• Title/Summary/Keyword: Binder volume

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Fabrication of Continuously Porous Alumina Bodies by Multi-Extrusion Process and their In-vitro and In-vivo Study for Biocompatibility (다중압출공정을 이용한 알루미나 연속다공질체 제조 및 그의 생체친화성 평가를 위한 In-vitro, In-vivo 실험)

  • 강인철;조순희;송호연;이병택
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.560-566
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    • 2004
  • To fabricate the continuously porous alumina bodies by multi-extrusion process, carbon powder and ethylene vinyl acetate were used as a pore forming agent and a binder, respectively. As the change of extrusion pass number, reduction ratio as well as the volume fraction of core and tube, the porous alumina bodies having various kind of pore size and porosity could be obtained. The porous bodies showed continuous pore shape, high specific surface as well as high bending strength, which were compared with those of commercial alumina bodies. In-vitro study was carried out using MG-63 osteoblast cells to investigate of their biocompatibility. As a result, the cells grew well on top and bottom as well as inside surface of pore. From the result of in-vivo study of 3-dimensional porous alumina bodies using rats, it was confirmed that any inflammatory response was not found in the subcutaneous tissue around porous body. Also the porous bodies removed from the rats were fully covered with well-developed fibrous tissues and showed the formation of new capillary blood vessels.

Workability and Mechanical Properties of Hybrid Fiber Reinforced Concrete Using Amorphous Steel Fiber and Polyamide Fiber

  • Kwon, Soon-Oh;Bae, Su-Ho;Lee, Hyun-Jin;Kim, Yo-Seb;Jun, Jin;Kim, Wha-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.470-476
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    • 2016
  • Many studies have been performed on hybrid fiber reinforced concrete for years, which is to improve some of the weak material properties of concrete. Studies on characteristics of hybrid fiber reinforced concrete using amorphous steel fiber and polyamide fiber, however, yet remain to be done. The purpose of this experimental research is to evaluate the workability and mechanical properties of hybrid fiber reinforced concrete using amorphous steel fiber and polyamide fiber. For this purpose, the hybrid fiber reinforced concrete containing amorphous steel fiber(ASF) and polyamide fiber(PAF) were made according to their total volume fraction of 0.5 % for water-binder ratio of 33 %, and then the mechanical properties such as the compressive strength, direct tensile strength, flexural strength, and flexural toughness of those were estimated. It was observed from the test results that the compressive strength was slightly decreased with increasing ASF and decreasing PAF and the effect of fiber combination on the flexural strength was not much but the flexural toughness was relatively largely increased with decreasing ASF and increasing PAF.

Flexural Behavior of Concrete-ECC Composite Beam Reinforced with Steel Rebar (철근 보강된 콘크리트-ECC 복합보의 휨 거동)

  • Hyun, Jung-Hwan;Bang, Jin-Wook;Lee, Bang-Yeon;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.104-111
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    • 2020
  • The purpose of this study is to investigate the flexural behavior and plastic hinge of reinforced concrete-ECC composite beams. Ordinary portland cement was used as a binder, and high volume fly ash was also used to improve the properties of ECC. An ECC designed in this study showed high tensile strain capacity of 3.0%. Three types of beams were manufactured according to the replacement length of concrete with ECC. From the bending tests, it was found that load-bearing capacity as well as ductility of beam increased with an increase in the replacement length of concrete with ECC. Curvature ductility and plastic hinge length of beam were also increased.

Studies on the Pore of Coating Layer and Printability (IV) -Effects of Blending Ratio of Pigments- (도공층의 공극과 인쇄적성에 관한 연구(제4보) -안료 배합 비율이 미치는 영향-)

  • 김창근;이용규
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.29-36
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    • 2001
  • This paper was made to evaluate the effect of the blending ration of GCC and No. 1 clay on the printability by investigating the structure of pore such as the pore rate, the number of pores, pore size and distribution of coated paper. The coated structure is mainly depended on the results of correlation between pigment and binder. It means that the structure of the pore occurred is chiefly affected by the blending ratio of GCC and No. 1 clay. This physical properties of the pore have a close relation with ink set-off associated with the drying rate and the penetration in ink into base paper and with printing gloss. Therefore it was needed to find out how the pore structure and the printability will be changed by modifying the blending ratio of GCC and No. 1 clay to vary the pore structure of coated paper. Below are the results of measurement: As the blending ratio of clay going up, water retention, sedimentation volume. smoothness, and paper gloss were increased, but relatively brightness and opacity were decreased. Pore rate was the highest at the blending ratio of No. 1 clay to GCC, 70:30. In this case, average pore radius was also increased. Ink receptivity and K&N ink receptivity were improved with the increase of the blending ratio of GCC, where was, ink setting was vice versa. No difference was observed in the weight of ink, but ink repellance decrease with the decrease of blending ratio of GCC.

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Evaluation of Characteristics of Tack Coat for Porous Pavement using Direct Shear Test (직접 전단 실험을 통한 배수성포장용 택코트 특성 평가)

  • Kim, Nak-Seok;Hong, Eun-Cheol;Jo, Shin-Haeng
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.27-32
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    • 2009
  • The main objective of this study is to develop a test for measuring the bond shear strength between pavement layers. The research is also conducted to evaluate tack coat materials and application rate in porous pavement. The experiment includes using two types of emulsions (RSC-4, Modified Emulsion) and a asphalt binder type (HM-1). HM-1 was developed to be applied in porous pavement. The bond shear strengths were measured by a direct shear type device under various test conditions. The shear strength may not be appropriate in the evaluation of the bond shear strength, while the toughness of the test may be useful. In case of the tack coat application rate in porous pavement, RSC-4 has to be used a minimum amount of $0.8l/m^2$ and modified emulsion asphalt has to be applied a volume of use $0.5{\sim}0.6l/m^2$. HM-1, asphalt cement type, is far stronger bond shear strength than emulsified asphalt tack coat and had showed the excellent trackless property.

Synthesis and electrochemical performance of transition metal-coated carbon nanofibers as anode materials for lithium secondary batteries

  • Choi, Jin-Yeong;Hyun, Yura;Park, Heai-Ku;Lee, Chang-Seop
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.161-167
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    • 2018
  • In this study, transition metal coated carbon nanofibers (CNFs) were synthesized and applied as anode materials of Li secondary batteries. CNFs/Ni foam was immersed into 0.01 M transition metal solutions after growing CNFs on Ni foam via chemical vapor deposition (CVD) method. Transition metal coated CNFs/Ni foam was dried in an oven at $80^{\circ}C$. Morphologies, compositions, and crystal quality of CNFs-transition metal composites were characterized by scanning electron microscopy (SEM), Raman spectroscopy (Raman), and X-ray photoelectron spectroscopy (XPS), respectively. Electrochemical characteristics of CNFs-transition metal composites as anodes of Li secondary batteries were investigated using a three-electrode cell. Transition metal/CNFs/Ni foam was directly employed as a working electrode without any binder. Lithium foil was used as both counter and reference electrodes while 1 M $LiClO_4$ was employed as the electrolyte after it was dissolved in a mixture of propylene carbonate:ethylene carbonate (PC:EC) at 1:1 volume ratio. Galvanostatic charge/discharge cycling and cyclic voltammetry measurements were taken at room temperature using a battery tester. In particular, the capacity of the synthesized CNFs-Fe was improved compared to that of CNFs. After 30 cycles, the capacity of CNFs-Fe was increased by 78%. Among four transition metals of Fe, Cu, Co and Ni coated on carbon nanofibers, the retention rate of CNFs-Fe was the highest at 41%. The initial capacity of CNFs-Fe with 670 mAh/g was reduced to 275 mAh/g after 30 cycles.

Evaluation of Reproducibility for Mechanical Properties of Lightweight Concrete using Bottom Ash Aggregates and Foam (바텀애시 골재와 기포를 이용한 경량 콘크리트의 역학적 특성에 대한 재현성 평가)

  • Ji, Gu-Bae;Mun, Ju-Hyun;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.202-209
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    • 2019
  • The objective of this study is to examine the reproducibility for compressive strength development and mechanical properties of lightweight concrete made using bottom ash aggregates and foam(LWC-BF). Based on the mix proportions conducted by Ji et al., six identical mixes were prepared with different actual foam volume ratios from 0% to 25% and water-to-binder ratios from 25% to 30%. The presently measured properties, including initial slump, slurry density, compressive strength gains at different ages, splitting tensile strength, and modulus of rupture, were very close to those determined in the previous tests by Ji et al. Thus, the developed LWC-BF has a good potential in obtaining a reproducibility for compressive strength development and mechanical properties even though the troubles of mixing control owing to the addition of preformed foam.

Optimum Combination of Thermoplastic Formability and Electrical Conductivity in Al-Ni-Y Metallic Glass

  • Na, Min Young;Park, Sung Hyun;Kim, Kang Cheol;Kim, Won Tae;Kim, Do Hyang
    • Metals and materials international
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    • v.24 no.6
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    • pp.1256-1261
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    • 2018
  • Both thermoplastic formability and electrical conductivity of Al-Ni-Y metallic glass with 12 different compositions have been investigated in the present study with an aim to apply as a functional material, i.e. as a binder of Ag powders in Ag paste for silicon solar cell. The thermoplastic formability is basically influenced by thermal stability and fragility of supercooled liquid which can be reflected by the temperature range for the supercooled liquid region (${\Delta}T_x$) and the difference in specific heat between the frozen glass state and the supercooled liquid state (${\Delta}C_p$). The measured ${\Delta}T_x$ and ${\Delta}C_p$ values show a strong composition dependence. However, the composition showing the highest ${\Delta}T_x$ and ${\Delta}C_p$ does not correspond to the composition with the highest amount of Ni and Y. It is considered that higher ${\Delta}T_x$ and ${\Delta}C_p$ may be related to enhancement of icosahedral SRO near $T_g$ during cooling. On the other hand, electrical resistivity varies with the change of Al contents as well as with the change of the volume fraction of each phase after crystallization. The composition range with the optimum combination of thermoplastic formability and electrical conductivity in Al-Ni-Y system located inside the composition triangle whose vertices compositions are $Al_{87}Ni_3Y_{10}$, $Al_{85}Ni_5Y_{10}$, and $Al_{86}Ni_5Y_9$.

Influence of Sulfate on Thermodynamic Modeling of Hydration of Alkali Activated Slag (알칼리 활성 슬래그의 열역학적 수화모델링에 대한 황산염의 영향)

  • Lee, Hyo Kyoung;Park, Sol-Moi;Kim, Hyeong-Ki
    • Resources Recycling
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    • v.28 no.1
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    • pp.32-39
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    • 2019
  • The present study investigated hydration of alkali activated slag incorporating sulfate as a form of anhydrite by employing thermodynamic modeling using the Gibbs free energy minimization approach. Various parameters were evaluated in the thermodynamic calculations, such as presence of sulfide, precipitation/dissolution of AFt/AFm phase, and the effect of oxic condition on the predicted reaction. The calculations suggested no significant difference in the void volume and chemical shrinkage, which might influence the performance of the mixtures, in spite of various changes of the parameters. Although the types of hydration products and their amount varied according to the input conditions, their variations were smaller range than that induced by water-to-binder ratio. Moreover, it did not affect the amount of C-(N-)A-S-H which was the most important hydration product.

Modified-stoichiometric Model for Describing Hydration of Alkali-Activated Slag (알칼리 활성 슬래그의 수화에 대한 개선된 화학양론적 모델)

  • Abate, Selamu Yihune;Park, Solmoi;Song, Keum-Il;Lee, Bang-Yeon;Kim, Hyeong-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.1-12
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    • 2021
  • The present study proposes the modified-stoichiometric model for describing hydration of sodium silicate-based alkaliactivated slag(AAS), and compares the results with the thermodynamic modelling-based calculations. The proposed model is based on Chen and Brouwers(2007a) model with updated database as reported in recent studies. In addition, the calculated results for AAS are compared to those for hydrated portland cement. The maximum difference between the proposed model and the thermodynamic calculation for AAS was at most 20%, and the effects of water-to-binder ratio and activator dosages were identically described by both approaches. In particular, the amount of non-evaporable water was within 10% difference, and was in excellent agreement with the experimental results. Nevertheless, notable deviation was observed for the chemical shrinkage, which is largely dependent on the volume of hydrates and pores.