• Title/Summary/Keyword: Binder dispersion

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Strength and conversion characteristics of DeNOx catalysts with the addition of dispersion agent (분산제 첨가에 따른 탈질촉매의 강도세기 및 전환특성)

  • Lee, Hyun Hee;Park, Kwang Hee;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6575-6580
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    • 2013
  • Various modified SCR catalysts were prepared and tested to improve the strength of catalysts for use under severe conditions. The SCR catalysts were modified with a binder and dispersion agent, and tested at the fixed bed reactor. FT-IR and $H_2$-TPR were used to analyze the degree of hydrogen use and ammonia adsorption by the modified catalysts. In the case of the SCR catalysts coated with 2.3g of the binder, 4.7g of ethanol, and 0.1g of dispersion agent, the strength of catalyst was increased by approximately 12%. On the other hand, despite the enhancement of strength, the activities of the SCR catalysts were decreased by 2-10%. When the mixed solution composed of binder, dispersion agent and $SiO_2$ solution was precipitated on the catalyst, the $NO_x$ conversion of the catalyst was decreased slightly. The Bronsted acid site and Lewis acid site worked as the activators for the SCR reaction, and were decreased by $SiO_2$.

Application of Compression Molding to Determination of Binder System for Low Pressure Injection Molding (열간압축성형에 의한 저압사출성형 결합제 시스템의 결정)

  • 김상우;이해원;송휴섭;김병호
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.823-828
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    • 1994
  • Dispersion condition of Si3N4 powder in molten wax was established by comparing relative viscosity of mixture with 20 vol% solids loading, while the evaluation of compression-molded sample was demonstrated as an effective method for developing a binder system for injection molding. The best dispersion of Si3N4 powder in molten wax was achieved when Si3N4 powder was treated with 5% stearic acid, and the critical powder volume fraction was determined to be about 0.51 from density measurement of compression-molded samples. Samples containing polar secondary binder showed markedly improved green strength, higher thermal expansion and increased wicking rate in the early stage.

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Dispersion and Rheological Characteristics of Alumina Slurries in Aqueous Tape-casting Using Acrylate Binder (Acrylate를 결합제로 사용한 수계 테이프 캐스팅에서 알루미나 슬러리의 분산 및 점성 특성)

  • Cho, Yu-Jeong;Park, Il-Seok;Moon, Joo-Ho;Kim, Dae-Joon
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.164-170
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    • 2002
  • Measurements of sedimentation, solid loading, zeta potential, and viscosity were employed to determine a proper dispersant and its amount for a well dispersed alumina powders in aqueous alumina tape casting using acrylate as a binder. Polycarboxylic acid was the most effective one among various dispersants considered in the present study and its amount was 0.23∼0.24 g per 100 g alumina for a dispersion. Better dispersion was obtained as an increase of dispersant addition. However, the dispersion was hindered as the amount of dispersant was higher than the optimum amount because of bridging or tangling of polymer chains. Excellent aqueous alumina tapes were prepared from the slurry containing the optimum amount of the polycarboxylic acid (0.2g), alumina powders(100 g), acrylate and Benzoflex as binder and plasticizer, respectively. The viscosity of the slurry was 570 cps and the alumina loading in the tape was 57 vol%.

Effect of $BaTiO_3$ Dispersion on the Properties of Cast Tapes in Processing of Multilayer Ceramic Capacitor(MLCC) (적층 세라믹콘덴서 제조공정에서 $BaTiO_3$의 분산이 테이프캐스팅 성형체의 물성에 미치는 영향)

  • 김봉호;김병관;김명호;백운규
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.214-222
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    • 1996
  • The effect of physicochemical properties of organic solvent and dispersant among organic solvent dispersant binder and plasticizer which are used as processing additives in MLCC fabrication process on the dispersion of BaTiO3 was studied. The steric and electrostatic stabilization mechanisms in dispersion of BaTiO3 in organic media were evaluated respectively. The sttability of BaTiO3 achieved bysteric stabilization was dependent on the fraction of surface coverage of dispersant adsorption on BaTiO3. The electrostatic repulsive forces of BaTiO3 particles dispersed in orgainc media was found to be appreciabley great and dependent mainly on the kinds of organic solvent used. The mechanism affecting the stability of BaTiO3 was studied by the method of rheologi-cal behaviors of BaTiO3 suspension.

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Effect of Organic Processing Parameters in Non-aqueous Tape-casting on Dispersion Stability of Barium Titanate-Borosilicate Glass Based Suspensions (비수계 테잎성형공정의 유기공정변수의 변화에 따른 티탄산바륨-붕규산염유리계 현탁액의 분산안정성)

  • Yeo, Jeong-Gu;Choi, Sung-Churl
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.725-731
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    • 2003
  • The effect of organic processing parameters on the dispersion stability of the BaTiO$_3$-based dielectric particles and borosilicate glass particulate suspensions was investigated in a system where organic solvents, dispersant, binder and modifier were used as processing additives in a low temperature cofired ceramic fabrication processes. Two- and three-component organic solvents were used to disperse ceramic particles and it was found the better stability in the particulate suspension prepared in a bi-solvent, which was consists of toluene and ethanol in a non-azeotropic composition. The addition amount of organic additives had a great impact on dispersion in the present investigation. The flow curves of the suspensions prepared with binder and modifier were fitted according to the power-law equation, which indicates that the internal structure of the suspension could be disturbed under the applied shear stress. Finally, the LTCC green tapes were successfully tape-cast based upon the optimum formulation of LTCC suspension and its microstructure was compared with that of the hard-agglomerates.

Evaluation of Physical Performance of High-Strength.High Waterproof Ready-mixed Shotcrete using Powdered Polymer Dispersion (분말형 폴리머 혼화제를 적용한 고강도.고차수성 레디믹스트 숏크리트의 물리적 성능 평가)

  • Ma, Sang-Joon;Choi, Hee-Sup;Lee, Heung-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.337-340
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    • 2008
  • As the Ready-mixed Shotcrete using Powdered Polymer Dispersion, Shotcrete Matrix as totally shotcrete gel that a part of second binder in Shotcrete materials is dense. Also, Ready-mixed Shotcrete is showed the decreasing Rebound and rising Durability. Therefore, it is possible that Ready-mixed Shotcrete for High-Strength and High-Waterproof can apply to the Powdered Polymer Dispersion.

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A Study on the Heat Resistance of Light-Weight Polymer Concrete Composites (경량 폴리머 콘크리트 복합체의 내열성능에 관한 연구)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.6
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    • pp.131-137
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    • 2008
  • In recent years, the light-weight aggregate has widely been used to reduce the weight of construction structures, and to achieve the thermal insulation of building structures. The purpose of this study is to evaluate the heat resistance of polymer concrete composites with light-weight aggregate made by binders as resin and cement with polymer dispersion. The light-weight polymer concrete composites are prepared with various conditions such as binder content, filler content, void-filling ratio, light-weight aggregate content and polymer-cement ratio, and tested for heat resistant test, and measured the weight reducing ratio, strengths and exhaustion content of gas such as CO, NO and $SO_2$. From the test results, the weight reducing ratio of light weight polymer concrete using UP binder after heat resistance test increase with an increase in the UP content irrespective of the filler content. The weight reducing ratio of polymer cement concrete is considerably smaller than that of UP concrete. In general, the strengths after heat resistance of polymer concrete composites are reduced about 40 to 65% compared with those before test. The exhausted quantity of CO, NO and $SO_2$ gases in polymer concrete composites is less than EPS(Expanded poly styrene). From the this study, it is confirmed that the many types gases discharge according to binder type of polymer concrete composites, its amount is controlled by selection of the binder type and mix proportions.

Dispersion of Carbon Black in Acrylic Resin Aqueous Solution (아크릴 수지 수용액에서의 Carbon black의 분산에 관한 연구)

  • 오지만;김성빈;권대환
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.16-27
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    • 2002
  • Recently, the attraction for water-based ink is increasing, Because Solvent ink, based on organic solvent, cause bad effect on environment and rise the cost. Instead of organic solvent that cause environment pollution as well as cost-rise by rise of petroleum price, Binder based on alkali-soluble resin is popular and studied by many other country. However, in domestic, research and development for alkali-soluble resin is not like, because of lack of understanding environmental pollution and safety, therefor alkali-soluble resin development and research for the properties of the water-based ink used by alkali-soluble resin is not study very well. In this paper, we studied dispersion of carbon black in acrylic resin solution and the properties of water-based ink used by carbon black and acrylic binder.

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Influence Dispersing Agent on the Modifiers in the High-Penetration Asphalt

  • Eun Kyoung Lee;You Kyoung Kim
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.215-221
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    • 2022
  • In this study, high-penetration asphalt with low greenhouse gas emissions was used in the asphalt mixing process to reduce the carbon emissions during the reaction due to its capacity to be produced even at low temperatures. In effect, cationic, anionic, and non-ionic dispersants were added and mixed in different feeding ratios, seeking an effective dispersion of the modifiers (SIS, PS, TPEE, and SEBS) into the high-penetration asphalt matrix and forming an asphalt binder with a melting point of 120 ℃. The compatibility of the modifiers and the high-penetration asphalt was examined using SEM and DSC techniques, and the role of NDP-1 as a dispersant was carefully investigated with respect to dissolution time. The analyses showed that: (1) the dispersibility of the asphalt binder is good when the non-ionic dispersant is used; (2) as the concentration of the non-ionic dispersant increases, the dissolution time decreases and the domain size contracts; (3) the ND70-PS has the shortest dissolution time, the lowest agglomeration rate, and a single Tg value.

The Effects of Ink Dispersion and Printing Conditions on Printed Mottle (잉크 분산 및 인쇄조건이 인쇄 모틀에 미치는 영향)

  • Ha, Young-Baeck;Lee, Yong-Kyu;Kim, Chang-Keun;Oh, Sung-Sang;Lim, Jong-Hag
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.41-46
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    • 2006
  • Printed mottle of coated paper is one of the most common but the most difficult problem in offset printing. Printed mottle is caused by an uneven penetration of Ink into the paper, binder migration, etc. For a high quality printing, development of new paper coating technologies to prevent print mottle is required. So for, the study of solving printed mottle is coated paper absorption controlled by base paper sizing and coating layer binder migration control. As a results, printed mottle has improved in coated paper. But printing is worked by interaction of printing ink, coated paper and printing pressure, then we need to understand of interaction printing work and coated paper. This research focused on a way of improving printed mottle by investigating various printing conditions such as ink dispersion, nip condition and amount of ink transfer using IGT printability tester.