• Title/Summary/Keyword: Binary properties

Search Result 518, Processing Time 0.024 seconds

Modelling the Hydrogen-Bonding Interactions in a Copolymer/Biodegradable Homopolymer Blend through Excess Functions

  • Garcia-Lopera, Rosa;Monzo, Isidro S.;Campos, Agustin;Abad, Concepcion
    • Macromolecular Research
    • /
    • v.16 no.5
    • /
    • pp.446-456
    • /
    • 2008
  • A recent theoretical approach based on the coupling of both the Flory-Huggins (FH) and the Association Equilibria thermodynamic (AET) theories was modified and adapted to study the miscibility properties of a multi-component system formed by two polymers (a proton-donor and a proton-acceptor) and a proton-acceptor solvent, named copolymer(A)/solvent(B)/polymer(C). Compatibility between polymers was mainly attained by hydrogen-bonding between the hydroxyl group on the phenol unit of the poly(styrene-co-vinyl phenol) (PSVPh) and the carbonyl group of the biodegradable and environmentally friendly poly(3-hydroxybutyrate) (PHB). However, the self-association of PSVPh and specific interactions between the PSVPh and the H-acceptor group (an ether oxygen atom) of the epichlorohydrin (ECH) solvent were also established in a lower extension, which competed with the polymer-polymer association. All the binary specific interactions and their dependence with the system composition as well as with the copolymer content were evaluated and quantified by means of two excess functions of the Gibbs tree energy, ${\Delta}g_{AB}$ and ${\Delta}g_{AC}$. Experimental results from fluorescence spectroscopy were consistent with the theoretical simulations derived with the model, which could also be applied and extended to predict the miscibility in solution of any polymer blend with specific interactions.

Synthesis and Mesomorphic Properties of New Achiral Liquid Crystals with 3-Alkoxy-2-(alkoxymethyl)-1-propoxy Swallow-Tails

  • Kang, Kyung-Tae;Kim, Jeong-Tak;Hwang, Ryeo-Yun;Park, Song-Ju;Lee, Seng-Kue;Lee, Jong-Gun;Kim, Yong-Bae
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.11
    • /
    • pp.1939-1944
    • /
    • 2007
  • New liquid crystalline (biphenylcarbonyloxy)benzoates with an achiral swallow-tail derived from 3-alkoxy-2- (alkoxymethyl)-1-propanol [(ROCH2)2CHCH2OH, R = Me, Et, Pr, Bu] were prepared. These liquid crystals exhibited the phase sequence (I-SmA-SmCalt-(SmCX)-Cr) and showed antiferroelectric-like Smectic C phase (SmCalt) at temperature lower, and temperature range broader than do the compounds containing a branched alkyl group as a swallow-tail. The temperature ranges of antiferroelectric phase were found to be 30-90 oC and crystallization temperatures were 4-60 oC. The binary mixture of an achiral swallow-tailed liquid crystal and a chiral antiferroelectric liquid crystal, (S)-MHPOBC showed antiferroelectric smectic C phase at temperature much lower than the single chiral antiferroelectric liquid crystal does.

Design of MuIti-Weight 2-Dimensional Optical Orthogonal Codes (다중 부호 무게를 가진 2차원 광 직교 부호의 설계)

  • Piao, Yong-Chun;Shin, Dong-Joon
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.33 no.1C
    • /
    • pp.1-5
    • /
    • 2008
  • Optical code division multiple access(OCDMA) systems make the active users to share the bandwidth by simply assigning distinct optical orthogonal codeword to each active user. An optical orthogonal code(OOC) is a collection of binary sequences with good correlation properties which are important factors of determining the capacity of OCDMA systems. Recently, 2-D OOC construction method is frequently researched which is able to support more users than 1-D OOC. In this paper, a combinatorial construction of simple multi-weight 2-D OOC with autocorrelation 0 and crosscorrelation 1 is proposed and the bound on the size of these codes is derived.

A Study on the Optimal Design Fuzzy Type Stabilizing Controller using Genetic Algorithm (유전 알고리즘을 이용한 퍼지형 안전화 제어기의 최적 설계에 관한 연구)

  • Lee, Heung-Jae;Lim, Chan-Ho;Yoon, Byong-Gyu;Lim, Hwa-Young;Song, Ja-Youn
    • The Transactions of the Korean Institute of Electrical Engineers A
    • /
    • v.48 no.11
    • /
    • pp.1382-1387
    • /
    • 1999
  • This paper presents an optimal fuzzy power system stabilizer to damp out low frequency oscillation. So far fuzzy controllers have been applied to power system stabilizing controllers due to its excellent properties on the nonlinear systems. But the design process of fuzzy logic power system stabilizer requires empirical and heuristic knowledge of human experts as well as many trial-and-errors in general. This paper presents and optimal design method of the fuzzy logic stabilizer using the genetic algorithm. Non-symmetric membership functions are optimally tuned over an evaluation function. The present inputs of fuzzy stabilizer are torque angle error and the change of torque angle error without loss of generality. The coding method used in this paper is concatenated binary mapping. Each linguistic fuzzy variable, defined as the peak of a membership function, is assigned by the mapping from a minimum value to a maximum value using eight bits. The tournament selection and the elitism are used to keep the worthy individuals in the next generation. The proposed system is applied to the one-machine infinite-bus model of a power system, and the results showed a promising possibility.

  • PDF

Imparting Disperse and Cationic Dyeability to Polypropylene through Melt Blending

  • Teli M. D.;Adivarekar R. V.;Ramani V.Y.;Sabale A.G.
    • Fibers and Polymers
    • /
    • v.5 no.4
    • /
    • pp.264-269
    • /
    • 2004
  • The present paper deals with improvement in disperse dyeablility as well as imparting of cationic dyeablility to difficultly dyeable polypropylene by a melt blending technique. Isotactic polypropylene (PP) was blended with fibre grade polybutylene terephthalate (PBT), cationic dyeable polyethylene terephthalate (CDPET) and polystyrene (PS), individually. The resulting binary blends were spun and drawn into fibres at draw ratio 2, 2.5, and 3. The compatibility of blends, structural changes of fibres in terms of X-ray crystallinity, relative crystallinity, sonic modulus, birefringence and thermal stability were examined. The blended fibres were found to be disperse dyeable by the conventional method of high temperature and high pressure dyeing. And this dye ability increased with increase in the level of substitution. PP/CDPET blend also exhibited dyeablility with cationic dyes in addition to that with disperse dyes. The optimum level of blending was predicted keeping in view of tenacity and thermal stability of melt blend fibres. The wash fastness properties of the dyed fibres were found to be of high rate.

Seabed Sediment Classification Algorithm using Continuous Wavelet Transform

  • Lee, Kibae;Bae, Jinho;Lee, Chong Hyun;Kim, Juho;Lee, Jaeil;Cho, Jung Hong
    • Journal of Advanced Research in Ocean Engineering
    • /
    • v.2 no.4
    • /
    • pp.202-208
    • /
    • 2016
  • In this paper, we propose novel seabed sediment classification algorithm using feature obtained by continuous wavelet transform (CWT). Contrast to previous researches using direct reflection coefficient of seabed which is function of frequency and is highly influenced by sediment types, we develop an algorithm using both direct reflection signal and backscattering signal. In order to obtain feature vector, we employ CWT of the signal and obtain histograms extracted from local binary patterns of the scalogram. The proposed algorithm also adopts principal component analysis (PCA) to reduce dimension of the feature vector so that it requires low computational cost to classify seabed sediment. For training and classification, we adopts K-means clustering algorithm which can be done with low computational cost and does not require prior information of the sediment. To verify the proposed algorithm, we obtain field data measured at near Jeju island and show that the proposed classification algorithm has reliable discrimination performance by comparing the classification results with actual physical properties of the sediments.

Structural, Optical, and Chemical Properties of Cadmium Phosphate Glasses

  • Chung, Jae-Yeop;Kim, Jong-Hwan;Choi, Su-Yeon;Park, Hyun-Joon;Hwang, Moon-Kyung;Jeong, Yoon-Ki;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
    • /
    • v.52 no.2
    • /
    • pp.128-132
    • /
    • 2015
  • In this study, we prepared cadmium phosphate glasses with various compositions, given by $xCdO-(100-x)P_2O_5$ (x = 10-55 mol%), and analyzed their Fourier transform infrared spectra, dissolution rate, thermal expansion coefficient, glass transition temperature, glass softening temperature, and optical band gap. We found that the thermal expansion coefficient and dissolution rate increased while the glass transition temperature and glass softening temperature decreased with increasing CdO content. These results suggest that CdO acts as a network modifier in binary phosphate glass and weakens its structure.

Binary Doping of N-B and N-P into Graphene: Structural and Electronic properties

  • Kim, Hyo seok;Kim, Seong Sik
    • Proceeding of EDISON Challenge
    • /
    • 2013.04a
    • /
    • pp.256-259
    • /
    • 2013
  • We investigate co-doping effects of conjugated P-N B-N with increasing of N concentration in the graphene sheets using a first principles based on the density functional theory. N doping sites of the graphene consider two possible sites (pyridinic and porphyrin-like). Energy calculation shows that additional doping of B atom in the porphyrin-like N doped graphene ($V+B-N_x$) is hard to form. At the low chemical potential of N, one N atom with additional doping in the graphene ($V+P-N_1$, $P/B-N_1$) has low formation energy on the other hand at high chemical potential of N, high concentration of N ($V+P-N_4$, $P/B-N_3$) in the graphene is governing conformation. From the results of electronic band structure calculation, it is found that $V+P-N_4$ and $P/B-N_3$ cases change the Fermi energy therefore type change is occurred. On the other hand, the cases of $V+P-N_1$ and N+B recover the electronic structure of pristine graphene.

  • PDF

Electrical Characteristics and Fabrication of NiCr/NiCrSi Alloy Film for High Precision Thin Film Resistors (고정밀급 박막저항을 위한 NiCr/NiCrSi박막의 제조 및 전기적 특성)

  • Lee, Boong-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.20 no.6
    • /
    • pp.520-526
    • /
    • 2007
  • In order to acquire fundamental informations to fabricate high precision thin film resistors, NiCr/NiCrSi alloy films were prepared using Ni and Cr targets. Effect of composition on the electrical properties of the NiCr/NiCrSi alloy film were then investigated. Considering the effect of Si doping on the electrical and material characteristics, the lower TCR (temperature coefficient of resistance) values could be achieved for samples with Ni/Cr ratio of $0.8{\sim}1.5$ (in a range of relative higher specific resistivity and Cr composition of $40\;wt%{\sim}55\;wt%$) and with Si doping. Consequently, the sample prepared using a DC power showed a good TCR of $-25\;ppm/^{\circ}C$, which implies that increase of specific resistivity and decrease of TCR would be achieved more efficiently not for Ni-Cr binary material but for Si doped Ni-Cr ternary material, and not using RF power but using DC power in the sputtering process.

An Effective Eye Location for Face Recognition (얼굴 인식을 위한 효과적인 눈 위치 추출)

  • Jung Jo Nam;Rhee Phill Kyu
    • The KIPS Transactions:PartB
    • /
    • v.12B no.2 s.98
    • /
    • pp.109-114
    • /
    • 2005
  • Many researchers have been interested in user authentication using biometric information, and face recognition is a lively field of study of ones in the latest biometric recognition field because of advantage that it can recognize who he/she is without touching machinery. This paper proposes method to extract eye location effectively at face detection step that is precedence work of face recognition. The iterative threshold selection was adopted to get a proper binary image and also the Gaussian filter was used to intensify the properties of eyes to extract an eye location. The correlation was adopted to verify if the eye location is correct or not. Extraction of an eye location that propose in paper as well as accuracy, considered so that may can apply to online system and showed satisfactory performance as result that apply to on line system.