• 제목/요약/키워드: Binary gas

검색결과 152건 처리시간 0.027초

평등전계에서 SF6/CF4 혼합가스의 AC절연내력 특성 (AC Breakdown Voltage Characteristics of SF6/CF4 in Uniform field)

  • 황청호;박신우;김남렬;허창수
    • 한국전기전자재료학회논문지
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    • 제20권4호
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    • pp.381-387
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    • 2007
  • The excellent dielectric properties of $SF_6$(sulfur hexafluoride) have lead to its wide range of application in the field of high voltage insulation. Because there has been some recent concern regarding the environmental impacts of $SF_6$ binary gas mixtures, with $SF_6$ as the main component, have been the subject of active research. Scientists have long been interested in the possible use of gaseous fluorocarbons, including $CF_4$ (Carton Tetrafluoride), in high voltage applications due to their inert character and high dielectric strength. This paper presents experimental results concerning the AC breakdown characteristics lot various mixtures of $SF_6/CF_4$ in a test chamber and 25.8 kV GIS (Gas Insulation Switchgear) at practical pressures (0.1-04 MPa) and gap lengths (0.5 mm, 1 mm) in a test chamber. In the result, it was observed that an increase in the dielectric strength is attained through the addition of $SF_6$ to $CF_4$. It is possible to make an environment friendly gas insulation material while maintaining the dielectric strength by combing $SF_6$ and $CF_4$ which generates a lower level of the "global warming" effect.

두 탑 PSA공정의 상세 동적모사 및 초기운전조건 결정 (Rigorous dynamic simulation and determination of initial operating conditions for two-bed PSA processes)

  • 황덕재;문일
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1997년도 한국자동제어학술회의논문집; 한국전력공사 서울연수원; 17-18 Oct. 1997
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    • pp.1520-1523
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    • 1997
  • A rigorous dynamic simulation was performed in binary gas mixture H$_{2}$/CO (70:30 vol.%) to determinate start-up operating conditions of PSA(Pressure Swing Adsorption) processes. The rigorous dynamic model for the PSA process contains an Ergun equation for expressing the pressure drop in a bed, and valve equations to compute the boundary pressure change of the bed. As the result of the continuous dynamic simulation of 100 operating cyles in various initial conditions, the unsteady-state appeared in the early period and the cyclic steady-state came out about 20th cycle in feed condition and vaccum condition, and 30th cycle in pure H$_{2}$ condition. As time goes by valve equations made change the pressure at each end of the bed in ressurization, countercurrunt-depressurization and pressure equalization steps. The H$_{2}$ purity and the recovery is 99.99% and 86.73% respectively, which is slightly higher than the experimental data. Main contributiion of this study includes supplying fundamental technologies of handling combined variables PSA processes by developing rigorous models.

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Measurement and Prediction of the Flash Points for Flammable Liquid Mixtures with Non-flammable Component

  • Ha, Dong-Myeong;Yu, Hyun-Sik;Kang, Gyeun-Hee;Ann, Jeong-Jin;Lee, Sung-Jin
    • International Journal of Safety
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    • 제7권2호
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    • pp.12-16
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    • 2008
  • Lower flash points for the binary systems, carbon tetrachloride+o-xylene and water+n-butanol were measured by Pensky-Martens closed cup tester. The Raoult's law and optimization method using van Laar equation were used to predict the lower flash points and were compared with experimental data. The calculated values based on the optimization method were found to be better than those based on the Raoult's law.

이성분계(3차 부틸-히드로과산화물 + 기체) 클러스레이트 하이드레이트의 구조적 특성과 열역학적 안정성에 관한 연구 (Phase equilibria and structure identification of tert-butylhydroperoxide + gaseous clathrate hydrates)

  • 윤여범;차민준;권민철;이흔
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.150.1-150.1
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    • 2011
  • Structure-II hydrate has been highlighted due to its higher gas storage capacity and favorable thermodynamic conditions. In this study, we introduce a new structure-II hydrate former, tert-butyl hydroperoxide (TBHP) and confirm the structural characteristics through High-Resolution Powder Diffraction (HRPD), $^{13}C$ solide-state NMR and Ramanspectroscopy. Here,we also investigated the thermodynamic stability of binary(TBHP+gaseous) clathrate hydrates. The experimental data were generated using an isochoric pressure-search method. The dissociation data for (TBHP +gaseous) clathrate hydrates are compared with the other hydrocarbon hydrate and pure gaseous hydrate.

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실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측 (Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction)

  • 강성필
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.477-480
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    • 2007
  • Hydrate phase equilibrium for the binary CO2+water and CH4+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal urn pore size were nealy identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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컴팩트 타입 실리카막 공정을 이용한 수소 분리 (Hydrogen Separation by Compact-type Silica Membrane Process)

  • 문종호;배지한;이상진;정종태;이창하
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.336-339
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    • 2006
  • With the steady depletion off fossil fuel reserves, hydrogen based energy sources become increasingly attractive. Therefore hydrogen production or separation technologies, such as Bas separation membrane based on adsorption technology, have received enormous attention in the industrial and academic fields. In this study, the transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using unary, binary and quaternary hydrogen gas mixtures permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical study, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust Bas model) were adapted to unsteady-state material balance

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UBV PHOTOMETRY AT THE OUTSIDE ECLIPSE PHASE OF AZ CASSIOPEIAE

  • Nha, Il-Seong
    • Journal of Astronomy and Space Sciences
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    • 제11권1호
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    • pp.21-30
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    • 1994
  • VV Cep-type long period spectroscopic-eclipsing binary AZ Cas has been observed for five years, 1985 Oct~1990 Feb, UBV at the Ilsan Station of Yonsei University Observatory. A total of 431 observations (U=129, B=142 and V=160) are made for 86 nights. Instrumental differential UBV and B-V light curves made with these observations cover phases nearly a half of one period. There is no appreciable light variation in V but in other two passbands a gradual decrease of the brightness is clearly noticed. The loss of light in B resulted in a reddening in $\Delta(B-V)$ by + 0.06 at phases between 0.4~0.5 as compared with that of at phase ~0.1. This intrinsic reddening arouses a question why at the orbital phase of the transit of a hot star in front of a cool M supergiant the heating of the facing hemisphere of M supergiant by the strong radiation from the B stat is absent. With regard to this unusual situation we propose a hypothesis that a large amount of gas stream of low temperature ejected from the surface of M supergiant component towards the B star dominates the brightness of B star and the reflection effect.

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실리카겔 공극에서의 이산화탄소 및 메탄 하이드레이트 상평형 측정 및 열역학적 예측 (Phase Equilibrium of the Carbon Dioxide and Methane Hydrate in Silica Gel Pores and Thermodynamic Prediction)

  • 강성필
    • 신재생에너지
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    • 제3권2호
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    • pp.47-52
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    • 2007
  • Hydrate phase equilibrium for the binary $CO_{2}$+water and $CH_{4}$+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal nm pore size were nearly identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

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저온 플라즈마 장치에서 $C_2H_4$의 첨가량이 NOx 저감에 미치는 영향에 대한 실험적 연구 (An Experimental Study on Effect of Adding $C_2H_4$ for Reduction of NOX using Low Temperature Plasma Apparatus)

  • 권준호;강우정;정태용
    • 한국자동차공학회논문집
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    • 제6권4호
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    • pp.211-218
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    • 1998
  • The purpose of this study is to investigate the reduction rate of NOX according to several parameters(NOX concentration, the flow rate of gas, the additional amount of C2H4, input voltage, input frequency and so in) when NOX is reduced by using PPCP(Pulse-induced Plasma Chemical Process). PPCP is based on the plasma-chemical technology, which induces narrow voltage pulses to binary electrode structure.

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Synthesis and Characteristics of FePt Nanopowder by Chemical Vapor Condensation Process

  • Yu, Ji-Hun;Lee, Dong-Won;Kim, Byoung-Kee;Jang, Tae-Suk
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1196-1197
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    • 2006
  • FePt binary-alloy nanopowder has been successfully synthesized by chemical vapor condensation process with two metal organic precursors, i.e., iron pentacarbonyl and platinum acetylacetonate. Average particle size of the powder was less than 50 nm with very narrow size distribution, revealing high dispersion capability. Characteristics of the powder could be controlled by changing process parameters such as reaction temperature, chamber pressure, as well as gas flow rate. Magnetic properties of the synthesized FePt nanopowder were investigated and analyzed in terms of the powder characteristics.

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