International Journal of Safety

한국안전학회 (The Korean Society of Safety)
권호 표지

Measurement and Prediction of the Flash Points for Flammable Liquid Mixtures with Non-flammable Component

  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University) ;
  • Yu, Hyun-Sik (Department of Occupational Health and Safety Engineering, Semyung University) ;
  • Kang, Gyeun-Hee (Department of Occupational Health and Safety Engineering, Semyung University) ;
  • Ann, Jeong-Jin (Korea Gas Safety Corporation) ;
  • Lee, Sung-Jin (Department of Clinical Laboratory Science, Semyung University)
  • 발행 : 2008.12.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Lower flash points for the binary systems, carbon tetrachloride+o-xylene and water+n-butanol were measured by Pensky-Martens closed cup tester. The Raoult's law and optimization method using van Laar equation were used to predict the lower flash points and were compared with experimental data. The calculated values based on the optimization method were found to be better than those based on the Raoult's law.

키워드

참고문헌

  1. D.A. Crowl and J.F. Louvar, "Chemical Process Safety: Fundamentals with Applications", Englewood Cliffs, New York, Prentice-Hall, 1990
  2. V. Babrauskas, "Ignition Handbook", Fire Science Publishers, SFPE, 2003
  3. D.M. Ha and S.J. Lee, "The Measurement and Estimation of Lower Flash Points for n-Propanol+Acetic acid and n-Propanol+n-Propionic acid Systems", Journal of the Korean Society of Safety, Vol. 22, No. 4, pp. 38-42, 2007
  4. D.M. Ha and S.J. Lee, "The Measurement and Prediction of the Flash Points for Water+2-Propanol System Using Open-Cup Apparatus", J. of Korean Institute of Fire Sci. & Eng., Vol. 21, No. 2, pp. 48-53, 2007
  5. C.R. Reid, J.M. Prausnitz and B.E. Poling, "The Properties of Gases and Liquids", 4nd ed., McGraw-Hill, New York, 1998
  6. J.M. Smith and H.C. Van Ness, "Introduction to Chemical Engineering Thermodynamics", 4nd ed., McGraw-Hill, 1987
  7. B.F. Hanley, "A Model for the Calculation and the Verification of Closed Cup Points Multicomponent Mixtures", Process Safety Progress, Vol. 17, No.2, pp.86-97, 1998 https://doi.org/10.1002/prs.680170204
  8. D.M. Ha, Y.C Choi and S.J. Lee, "Flash Points of Water+n-Propanol System Using Closed-Cup Measurement Apparatus", Journal of the Korean Society of Safety, Vol. 17, No. 4, pp. 140-145, 2002
  9. J.L. Kuester and J.H. Mize, "Optimization Techniques with Fortran", McGraw-Hill, New York, 1973
  10. ASTM, "Standard Test Method for Flash-Point by Pensky-Martens Closed Cup Tester(ASTM D93)", American Society for Testing Materials, Philadelpia, PA, 1994
  11. J.C. Park, D.M. Ha and M.G. Kim, "Modified Response Surface Methodology (MRSM) for Phase Equilibrium-Theoretical Background", Korean J. of Chemical Engineering, Vol. 13, pp. 115-122, 1996 https://doi.org/10.1007/BF02705897
  12. D.M. Ha, S.J. Lee and M.H. Back, "Measurement and Estimation of the Lower Flash Points for the Flammable Binary Systems Using a Tag Open Cup Tester", Korean J. of Chemical Engineering, Vol. 24, No. 4, pp. 551-555, 2007 https://doi.org/10.1007/s11814-007-0001-2