• Title/Summary/Keyword: Binary gas

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Binary Nature Revealed in Circumstellar Spiral-Shell Patterns

  • Kim, Hyosun;Hsieh, I-Ta;Liu, Sheng-Yuan;Taam, Ronald E.
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.56.1-56.1
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    • 2014
  • With the advent of high-resolution high-sensitivity observations, spiral patterns have been revealed around several asymptotic giant branch (AGB) stars. Such patterns can provide possible evidence for the existence of central binary stars embedded in outflowing circumstellar envelopes. It is, however, not generally recognized that the binary induced pattern, vertically extended from the orbital plane, exhibits a ring-like pattern with an inclined viewing angle. I will first review the binary-induced spiral-shell patterns on the AGB circumstellar envelopes with the effect of inclination angle with respect to the orbital plane, of which large inclination cases reveal incomplete ring-like patterns. I will describe a method of extracting such spiral-shell from the gas kinematics of an incomplete ring-like pattern to place constraints on the characteristics of the (unknown) central binary stars. This first success may open the possibility of connecting the ring-like patterns commonly found in the AGB circumstellar envelopes and in the outer parts of (pre-)planetary nebulae and pointing to the conceivable presence of central binary systems, which may give a clue for the onset of asymmetrical planetary nebulae.

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The Characteristics of Desulfurization for Dry-Type High Temperature in a Fluidized Bed Reactor (고온건식탈황을 위한 유동층반응기 특성연구)

  • 장현태
    • Journal of the Korean Society of Safety
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    • v.14 no.1
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    • pp.78-85
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    • 1999
  • The removal characteristics of H$_2$S from IGCC process over the natural manganese ore(NMO) containing several metal oxides($MnO_x$ : 51.85%, $FeO_y$ : 3.86%, CaO : 0.11%) were carried out in a batch type fluidized bed reactor(I.D.=40mm, height=0.8m). The $H_2S$ breakthrough curves were obtained as a function of temperature, initial gas velocity, initial gas concentration, and aspect ratio. The effect of particle size ratio and particle mixing fraction on $H_2S$ removal were investigated with binary system of different particle size. From this study, the adsorption capacity of $H_2S$ increased with temperature but decreased with excess gas velocity. The breakthrough time for $H_2S$ is reduced as the gas velocity is increased which leaded to gas by-passing and gas-solid contacting in a fluidized bed reactor. The results of the binary particle system with different size in batch experimental could predict to improve the behavior of continuous process of $H_2S$ removal efficiency. The natural manganese ore could be considered as potential sorbent in $H_2S$ removal.

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Separative Power of an Optimised Concurrent Gas Centrifuge

  • Bogovalov, Sergey;Borman, Vladimir
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.719-726
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    • 2016
  • The problem of separation of isotopes in a concurrent gas centrifuge is solved analytically for an arbitrary binary mixture of isotopes. The separative power of the optimised concurrent gas centrifuges for the uranium isotopes equals to ${\delta}U=12.7(V/700m/s)^2(300K/T)(L/1m)kg{\cdot}SWU/yr$, where L and V are the length and linear velocity of the rotor of the gas centrifuge and T is the temperature. This equation agrees well with the empirically determined separative power of optimised counter-current gas centrifuges.

Estimation of Density of Methane and Ethane and Vapor-Liquid Equilibrium Predictions for Methane-Ethane Binary System Using PR and PC-SAFT Equations of State (PR 및 PC-SAFT 상태방정식을 이용한 메탄과 에탄의 기상과 액상의 밀도 추산 및 이성분계의 기-액 상평형 계산)

  • Park, Jong-Kee;Choi, Kun-Hyung;Lee, Sang-Gyu;Yang, Young-Myung;Cho, Jung-Ho
    • Journal of the Korean Institute of Gas
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    • v.14 no.2
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    • pp.22-26
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    • 2010
  • In this study, experimental vapor pressures and densities of vapor and liquid phases versus temperature were estimated using PC-SAFT equation. The estimated results were compared with those using PR equation of state. For the vapor phase densities, both equations well predicted the literature data. However, PC-SAFT equation showed better prediction capability for liquid phase densities. In the comparison of vapor-liquid equilibrium prediction capability for the binary systems of methane and ethane, PC-SAFT equation was better than the PR equation.

The Study of Physical Properties for the Organic Compounds and their Binary Mixture according to Molecular Connectivity Method (Molecular Connectivity法을 이용한 有機化合物과 二成分 混合物에 對한 物理化學的 性質에 關한 硏究 (Ⅱ))

  • Ui-Rak Kim;Kyung-Sub Min;Myung-Jae Lee;Sang-Hae Kim;Bong-Jin Jeong
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.485-495
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    • 1992
  • The viscosities of organic compounds (alcohols, acetates, alkanes, acids, substituted $NH_2$) in liquid states, gas states and the binary mixtures of n-alkane / 1-chloroalkane were calculated by molecular modeling techniques. The molecular descriptors of molecular modeling technique are Molecular connectivity indices, Wiener indices and ad hoc descriptors, which can encode the information of compound properties about the effect of size, branching, cyclization, unsaturation, heteroatom content, polarizability, and so on. The successful results among method have been Molecular connectivity indices, binary mixtures of n-alkane / 1-chloroalkane, Wiener indices for gas state and ad hoc descriptor for liquid states. Also we obtained the regression equations for viscosities using molecular modeling indices for gas, liquid states and binary mixtures of n-alkane / 1-chloroalkane. The calculated viscosity values for organic compounds are in good agreement with experimental results.

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Estimation of Physical Properties of Natural Gas Using Cubic Equations of State (3차형 상태방정식을 이용한 천연가스의 물성 추산)

  • Cho, Jung-Ho;Cho, Kyu-Sang;Kim, Dong-Hyeok;Lee, Young-Chul;Hong, Sung-Ho
    • Journal of the Korean Institute of Gas
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    • v.10 no.4 s.33
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    • pp.6-10
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    • 2006
  • In this study, gross heating value(GHV), density, vapor pressure and heat capacity of natural gas were estimated and their experimental data were compared with calculated ones, SRK method. A new alpha function was used to predict the vapor pressures of pure component of the natural gas constituents well instead of calculating vapor pressures with acentric factors. And binary adjustable parameters were determined by regressing binary vapor-liquid equilibria data. Through this study, our results showed good agreements with experimental data.

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Growth and Properties of CrNx/TiNy/Al Based on N2 Gas Flow Rate for Solar Thermal Applications

  • Ju, Sang-Jun;Jang, Gun-Eik;Jang, Yeo-Won;Kim, Hyun-Hoo;Lee, Cheon
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.3
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    • pp.146-149
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    • 2016
  • The CrN/TiN/Al thin films for solar selective absorber were prepared by dc reactive magnetron sputtering with multi targets. The binary nitride CrN layer deposited with change in N2 gas flow rates. The gas mixture of Ar and N2 was an important parameter during sputtering deposition because the metal volume fraction (MVF) was controlled by the N2 gas flow rate. In this study, the crystallinity and surface properties of the CrN/TiN/Al thin films were estimated by X-ray diffraction (XRD), atomic force microscopy (AFM) and field emission scanning electron microscopy (FESEM). The composition and depth profile of thin films were investigated using Auger electron spectroscopy (AES). The absorptance and reflectance with wavelength spectrum were recorded by UV-Vis-NIR spectrophotometry at a range of 300~1,100 nm.

DOUBLE STARS AS TRACERS OF TINY STRUCTURES IN THE INTERSTELLAR MEDIUM

  • MORABBI, SOMAYEH;MIRTORABI, MOHAMMAD TAGHI
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.89-91
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    • 2015
  • Observed spectra of stars around the Sun have indicated that the Sun is located in a gas cavity, extending to 100pc. This gas cavity is called the "Local Bubble". The density of the interstellar medium (ISM) in the local bubble is about one tenth that of the average for the ISM in the Milky Way. Furthermore, some structures such as gas planes and strings in the local bubble are probably the result of supernovae. These, due to their low temperatures, can not be observed in the visible and infrared. The only way to do so is to measure the spectra of nearby stars so that the light of stars passing through the local bubble is absorbed by existing gas and the resulting spectral lines from absorption can be measured. In this study, we use binary stars to trace the local bubble structures through lines such as the Na I Doublet. First, we determined the observed spectral lines of stars by HARPS and FEROS echelle spectrographs. Then, we made synthetic spectra with the ATLAS9 code. Finally, the difference between the observational and synthetic spectra confirms the existence of the Na I Doublet in the local ISM.

Hydrogen Separation from Binary and Quaternary Gas Mixtures Using Organic Templating Silica Membrane (유기템플레이팅 실리카막을 이용한 이성분 및 사성분 수소 분리)

  • Moon, Jong-Ho;Bae, Ji-Han;Chung, Jong-Tae;Lee, Jae-Wook;Lee, Chang-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.9-12
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    • 2007
  • The transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using four binary and one quaternary hydrogen mixtures through permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical studies, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust gas model) were adapted to unsteady-state material balance.

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Comparison of sensitivity of gas sensors using sensing materials with mono and binary catalyst system (단원계 및 이원계 촉매 시스템의 감지 물질을 이용한 가스 센서의 감지 특성 비교)

  • Hong, Sung-Jei;Han, Jeong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.67-70
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    • 2003
  • 단원계 및 이원계 촉매를 이용하여 나노 감지 소자를 합성하였고, 이를 이용하여 가연성 후막 가스 센서를 제작, 촉매 시스템에 따른 가스 감지 특성을 비교하였다. 단원계의 경우 Pd 및 Pt를 각각 3wt%로, 이원계의 경우 Pd:Pt 농도를 1:2~2:1wt%로 각각 제어하여 평균 입도가 15 nm 인 $SnO_2$ 나노 분말에 도핑, 감지물질을 합성하였다. 그 후 감지물질을 paste로 만들어 인쇄, 가스센서 제작 후 $450{\sim}600^{\circ}C$의 온도로 열처리하였다. 그 결과 이원계 촉매 시스템을 가진 가스 센서는 시효 시간에 따라 감도 값이 변하는 불안정한 현상을 나타내었다, 그러나 단원계 촉매의 경우 시효 시간이 지나도 감도 값이 안정된 현상을 나타내었다. 특히 3wt% pt를 도핑하여 $500^{\circ}C$에서 열처리한 경우 5시간 시효 후에도 감도 값의 변화 폭이 3.5% 이하의 매우 안정된 특성을 나타내었고 반응 시간도 20초 이하로 매우 빠른 응답 특성을 나타내었다.

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