• Title/Summary/Keyword: Binary Systems

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Solubilization of Hydrocarbon Oils by C12E8 Nonionic Surfactant Solution (C12E8 비이온 계면활성제 수용액에 의한 탄화수소 오일의 가용화에 관한 연구)

  • Lim, JongChoo
    • Korean Chemical Engineering Research
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    • v.45 no.3
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    • pp.219-225
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    • 2007
  • The equilibrium solubilization capacity of pure hydrocarbon oils by 2.5 wt% $C_{12}E_8$ nonionic surfactant solution was measured at $30^{\circ}C$ by gas chromatography (GC) analysis. Experimental results indicated that the molar solubilization ratio (MSR) for pure alkanes was found to decrease almost linearly with the alkane carbon number (ACN) of the hydrocarbon oil. For the binary mixture systems of the hydrocarbon oils both selective and nonselective solubilization behaviors were observed depending on the difference in carbon number of the two hydrocarbon oils. Equilibrium solubilization tests for the two n-octane/n-nonane and n-nonane/n-decane mixture systems in $C_{12}E_8$ surfactant solutions suggest slightly selective solubilization in favor of n-octane, but the small difference in solubilization rates between two hydrocarbon oils does not allow ruling out non-selective solubilization for these particular systems. This is certainly not the case for the n-octane/n-decane mixture, for which selective solubilization was conclusively demonstrated by GC analysis data.

Valorization of bottom ash with geopolymer synthesis: Optimization of pastes and mortar

  • Froener, Muriel S.;Longhi, Marlon A.;de Souza, Fabiana;Rodriguez, Erich D.;Kirchheim, Ana Paula
    • Advances in concrete construction
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    • v.14 no.1
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    • pp.1-13
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    • 2022
  • Due to the physical-chemical characteristics of some bottom ash (BA), there are technical, economic and environmental limitations to find a destination that will add value to it. In Brazil, this residue is eventually used for filling coal extraction pits or remains in sedimentation ponds, creating a susceptible panorama to environmental issues. The geopolymers binders are one of the alternatives to the proper use high amounts of these materials. In this work, geopolymeric binder pastes were produced with BA mixed to activators with different alkali contents (expressed as %Na2O), as well as the incorporation of soluble silicates (Ms content). The production of binary geopolymeric pastes based on the use of two industrial wastes: fluid catalytic cracking (FCC) and aluminum anodizing sludge (AAS), was also assessed. The content in mass of BA/FCC and BA/AAS ranged from 100/0, 90/10; 80/20 and 70/30. Systems with soluble silicates as activator in a molar ratio SiO2/Na2O of 1.0 (Ms = 1.0) and Na2O content of 15%, showed the best results of mechanical strength (42 MPa at day 28th). The improvement is up to 5X when compared to NaOH based systems. For systems with partial replacement of BA of 10% of AAS and 20% of FCC (80/20), the presence of soluble silicates was also effective to increase compressive strength.

Design of a computationally efficient frame synchronization scheme for wireless LAN systems (무선랜 시스템을 위한 계산이 간단한 초기 동기부 설계)

  • Cho, Jun-Beom;Lee, Jong-Hyup;Han, Jin_Woo;You, Yeon-Sang;Oh, Hyok-Jun
    • Journal of the Institute of Electronics and Information Engineers
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    • v.49 no.12
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    • pp.64-72
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    • 2012
  • Synchronization including timing recovery, frequency offset compensation, and frame synchronization is most important signal processing block in all wireless/wired communication systems. In most communication systems, synchronization schemes based on training sequences or preambles are used. WLAN standards of 802.11a/g/n released by IEEE are based on OFDM systems. OFDM systems are known to be much more sensitive to frequency and timing synchronization errors than single carrier systems. A loss of orthogonality between the multiplexed subcarriers can result in severe performance degradations. The starting position of the frame and the beginning of the symbol and training symbol can be estimated using correlation methods. Correlation processing functionality is usually complex because of large number of multipliers in implementation especially when the reference signal is non-binary. In this paper, a simple correlation based synchronization scheme is proposed for IEEE 802.11a/g/n systems. Existing property of a periodicity in the training symbols are exploited. Simulation and implementation results show that the proposed method has much smaller complexity without any performance degradation than the existing schemes.

Morphological Properties of Binary Blends of Polyolefins Synthesized by Metallocene and Ziegler-Natta Catalysts (Ziegler-Natta와 메탈로센 촉매로 합성된 폴리올레핀 2원 블렌드의 상 형태학)

  • Kwag, Hanjin;Kim, Hak Lim;Choe, Soonja
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.944-948
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    • 1999
  • The morphological properties of four binary blends of polyethylene synthesized by metallocene catalyst(MCPE) and four polyolefins prepared by Ziegler-Natta catalyst have been investigated to interpret the effect of micro-molecular structure on the phase morphology and interfacial behavior; four binary blend systems studied are high density polyethylene(HDPE)-metallocene polyethylene (MCPE), polypropylene(PP)-MCPE, poly(propylene-co-ethylene) (CoPP)-MCPE, and poly(propylene-co-ethylene-co-1-butylene) (TerPP)-MCPE, and they are all phase separated. The HDPE-MCPE blend shows evenly growing homogeneous HDPE domain on the continuous MCPE phase, on the other hand, the rest of three blends show complex heterogeneous phase behavior. The PP-MCPE blend shows that PP and MCPE and completely phase separated and phase inversion takes place at 50% MCPE. The CoPP-MCPE and TerPP-MCPE show enhanced interface due to the same micro-molecular structure of ethylene, and phase inversion takes place at 40% MCPE. In particular, TerPP-MCPE blend shows improved phase morphology between interfaces, and this may be arisen from the comonomer contents in TerPP, which are 1-butene and ethylene having the same chemical structure as that of MCPE. The enhancement of the phase morphology in the TerPP-MCPE blend is correlated with the mechanical and morphological properties. Thus, although the four blend systems are phase separated, the phase morphology suggests that the order of interfacial adhesion strength be HDPE-MCPE > TerPP-MCPE > CoPP-MCPE > PP-MCPE and that micro-molecular structure between constituents be one of major factors giving enhanced interfacial adhesion.

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Melt Rheology of Ethylene 1-Octene Copolymer Blends Synthesized by Ziegler-Natta and Metallocene Catalysts

  • Kim, Hak-Lim;Dipak Rana;Hanjin Kwag;Soonja Choe
    • Macromolecular Research
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    • v.8 no.1
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    • pp.34-43
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    • 2000
  • The melt rheology of four binary blends of ethylene 1-octene copolymers (EOCs) which consist of one component by Ziegler-Natta and another by metallocene catalysts, was studied to elucidate miscibility in the melt by using torsion rheometer at 200$\^{C}$ and different shear rates. The four blend systems, designated into the FA+FM, SF+FM, RF+EN, and RF+PL blend, are divided and interpreted based on the melt index (MI), the density and the comonomer contents. The melt viscosity such asη', η", and η$\^$*/ is weight average value if the comonomer contents are similar, otherwise they show different manner. The experimental resole are analyzed based on the Cole-Cole plot of logη' uersus log η", the logarithmic plots of the dynamic storage modulus (G') versus the dynamic loss modulus (G") for various blend compositions, and the melt viscosity of 11', n", and f" as a function of blend compositions. As a cerise-quence, the FA+FM blend is miscible, but the SF+FM, RF+EN, and RF+PL blends are not in the melt. Thus miscibility of the blends studied in this communication is suggested to strongly influence by the comonomer contents rather than the density or the MI.

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New Non-uniformity Correction Approach for Infrared Focal Plane Arrays Imaging

  • Qu, Hui-Ming;Gong, Jing-Tan;Huang, Yuan;Chen, Qian
    • Journal of the Optical Society of Korea
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    • v.17 no.2
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    • pp.213-218
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    • 2013
  • Although infrared focal plane array (IRFPA) detectors have been commonly used, non-uniformity correction (NUC) remains an important problem in the infrared imaging realm. Non-uniformity severely degrades image quality and affects radiometric accuracy in infrared imaging applications. Residual non-uniformity (RNU) significantly affects the detection range of infrared surveillance and reconnaissance systems. More effort should be exerted to improve IRFPA uniformity. A novel NUC method that considers the surrounding temperature variation compensation is proposed based on the binary nonlinear non-uniformity theory model. The implementing procedure is described in detail. This approach simultaneously corrects response nonlinearity and compensates for the influence of surrounding temperature shift. Both qualitative evaluation and quantitative test comparison are performed among several correction technologies. The experimental result shows that the residual non-uniformity, which is corrected by the proposed method, is steady at approximately 0.02 percentage points within the target temperature range of 283 K to 373 K. Real-time imaging shows that the proposed method improves image quality better than traditional techniques.

A New Reference Pixel Prediction for Reversible Data Hiding with Reduced Location Map

  • Chen, Jeanne;Chen, Tung-Shou;Hong, Wien;Horng, Gwoboa;Wu, Han-Yan;Shiu, Chih-Wei
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.8 no.3
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    • pp.1105-1118
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    • 2014
  • In this paper, a new reversible data hiding method based on a dual binary tree of embedding levels is proposed. Four neighborhood pixels in the upper, below, left and right of each pixel are used as reference pixels to estimate local complexity for deciding embeddable and non-embeddable pixels. The proposed method does not need to record pixels that might cause underflow, overflow or unsuitable for embedment. This can reduce the size of location map and release more space for payload. Experimental results show that the proposed method is more effective in increasing payload and improving image quality than some recently proposed methods.

Classification of White Blood Cell Using Adaptive Active Contour

  • Theerapattanakul, J.;Plodpai, J.;Mooyen, S.;Pintavirooj, C.
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1889-1891
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    • 2004
  • The differential white blood cell count plays an important role in the diagnosis of different diseases. It is a tedious task to count these classes of cell manually. An automatic counter using computer vision helps to perform this medical test rapidly and accurately. Most commercial-available automatic white blood cell analysis composed mainly 3 steps including segmentation, feature extraction and classification. In this paper we concentrate on the first step in automatic white-blood-cell analysis by proposing a segmentation scheme that utilizes a benefit of active contour. Specifically, the binary image is obtained by thresolding of the input blood smear image. The initial shape of active is then placed roughly inside the white blood cell and allowed to grow to fit the shape of individual white blood cell. The white blood cell is then separated using the extracted contour. The force that drives the active contour is the combination of gradient vector flow force and balloon force. Our purposed technique can handle very promising to separate the remaining red blood cells.

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Programmable Ministep Drive

  • Thedmolee, Sunhapitch;Pongswatd, Sawai;Kummool, Sart;Ukakimapurn, Prapart
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.2274-2277
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    • 2003
  • A cylindrical permanent magnet inside the four-phase permanent magnet (PM) stepping motor is employed as the rotor. The stator has four teeth around, which its coils are wound. The mode of excitation can be classified into 3 modes: single-phase excitation, two-phase excitation and ministep excitation. The ministep drive is a method to subdivide one step into several small steps by means of electronics. The paper presents the programmable ministep technique drive. This technique decodes the results obtained from the counter to locate the data in Read Only Memory (ROM). The Sinusoidal Pulse Width Modulation (SPWM) is transformed to binary file and saved to the ROM. The experiment is performed with the four-phase PM stepping motor and drives from a two-phase programmable sinusoidal ministep signal, instead of square wave. The results show that the performances of the proposed programmable ministep technique drive have high efficiency, smooth step motion, and high speed response. Moreover, the resolution of sinusoidal ministep signal can be controlled by the input frequency (f command).

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Infant Retinal Images Optic Disk Detection Using Active Contours

  • Charmjuree, Thammanoon;Uyyanonvara, Bunyarit;Makhanov, Stanislav S.
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.312-316
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    • 2004
  • The paper presents a technique to identify the boundary of the optic disc in infant retinal digital images using an approach based on active contours (snakes). The technique can be used to be develop a automate system in order to help the ophthalmologist's diagnosis the retinopathy of prematurity (ROP) disease which may occurred on preterm infant,. The optic disc detection is one of the fundamental step which could help to create an automate diagnose system for the doctors we use a new kind of active contour (snake) method has been developed by Chenyang et. al. [1], based on a new type of external force field, called gradient vector flow, or GVF. GVF is computed as a diffusion of the gradient vectors of a gray-level or binary edge map derived from the image. The testing results on a set of infant retinal ROP images verify the effectiveness of the proposed methods. We show that GVF has a large capture range and it's able to move snakes into boundary concavities of optic disc and finally the optic disk boundary was determined.

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