• Analytical Science and Technology
• /
• v.19 no.5
• /
• pp.422-432
• /
• 2006

The volatile organic compounds(VOCs) have been recognized as a major contributor to air pollution. The catalytic oxidation is one of the most important processes for VOCs destruction due to getting high efficiency at low temperature. In this study, monometallic Pt and bimetallic Pt-Ru, Pt-Ir were supported to ${\gamma}-Al_2O_3$. Xylene, toluene and MEK were used as reactants. The monometallic or bimetallic catalysts were prepared by the excess wetness impregnation method and were characterized by XRD, XPS, TEM and BET analysis. As a result, Pt-Ru, Pt-Ir bimetallic catalysts showed higher conversion than Pt monometallic catalyst. Pt-Ir bimetallic catalyst showed the highest conversion on the ${\gamma}-Al_2O_3$ support. In the VOCs oxidation, Pt-Ru, Pt-Ir bimetallic catalyst had multipoint active sites, so it improved the range of Pt metal state. Therefore, bimetallic catalysts showed higher conversion of VOCs than monometallic ones. In this study, the use of small amount of Ru, Ir to Pt promoted oxidation conversion of VOCs.

• Journal of Powder Materials
• /
• v.18 no.6
• /
• pp.538-545
• /
• 2011

This study shows that catalytic activity of bimetallic RhPt nanoparticle arrays under CO oxidation can be tuned by varying the size and composition of nanoparticles. The tuning of size of RhPt nanoparticles was achieved by changing concentration of rhodium and platinum precursors in one-step polyol synthesis. Two-dimensional RhPt bimetallic nanoparticle arrays in different size and composition were prepared through Langmuir-Blodgett thin film technique. CO oxidation was carried out on these two-dimensional nanoparticle arrays, revealing higher activity on the smaller nanoparticles compared to the bigger nanoparticles. X-ray photoelectron spectroscopy (XPS) results indicate the preferential surface segregation of Rh compared to Pt on the smaller nanoparticles, which is consistent with the thermodynamic analysis. Because the catalytic activity is associated with differences in the rates of $O_2$ dissociative adsorption between Pt and Rh, this paper suppose that the surface segregation of Rh on the smaller bimetallic nanoparticles is responsible for the higher catalytic activity in CO oxidation. This result suggests a control mechanism of catalytic activity via synthetic approaches of colloid nanoparticles, with possible application in rational design of nanocatalysts.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2010.06a
• /
• pp.93-93
• /
• 2010

We developed friction welded bimetallic sleeve for 220kV aluminum conductor XLPE cable. Not only friction welded bimetallic sleeve for Termination(EB-A, EB-G) but also friction welded sleeve for Joint of Al to Cu conductor was developed regardless of this project. Generally, friction welded sleeve used to connect Al conductor cable to Cu conductor cable and used for improvement of mechanical property of terminal by offer the copper side of friction welded bimetallic sleeve at the Termination. Connection method for Al-Cu conductor has mainly used friction welding at the solid state, because it is difficult to connect by using conventional welding method. this investigation introduces development of friction welded bimetallic sleeve by friction welding and test result of 220kV Al conductor XLPE cable and accessories using friction welded sleeve.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.1
• /
• pp.120-124
• /
• 2010

Monometallic, bimetallic and trimetallic particles consisting of different weight compositions of Pt-Pd-Rh over pure alumina wash coats have been synthesized and their catalytic performance on methane conversion was studied from 150 to $600^{\circ}C$. Different catalyst formulations with variable Pt, Pd and Rh contents for bimetallic and trimetallic systems were tried and $Pt_{(1.5)}Rh_{(0.3)}/Al_2O_3$ and $Pt_{(1.0)}Pd_{(1.0)}Rh_{(0.3)}/Al_2O_3$ shows low $T_{50}$ and $T_{90}$ temperatures. Bimetallic and trimetallic particle synergism acts as three way catalysts and therefore, all the catalysts show 100% methane conversion. The effect of supports such as $ZrO_2$ and $TiO_2$ on methane combustion was investigated; from $T_{50}$ and $T_{90}$ results both $Al_2O_3$ and $ZrO_2$ are suitable supports for low temperature methane combustion.

• Korean Chemical Engineering Research
• /
• v.56 no.2
• /
• pp.269-274
• /
• 2018

All the $Ni-Co-Ce-ZrO_2$ mixed oxides are prepared by co-precipitations methods. Methanation of CO and $H_2$ reaction is screened tested over different fractions of cerium (2, 4, 7 and 12 wt.%) over $Ni-Co/ZrO_2$ bimetallic catalysts are investigated. The mixed oxides are characterized by XRD, CO-Chemisorption, TGA and screened methanation of CO and $H_2$ at $360^{\circ}C$ for 3000 min on stream at typical ratio $CO:H_2=1:1$. In $Ni-Co/CeZrO_2$ series 2 wt.% Ce loading catalyst shows most promising catalyst for $CH_4$ selectivity than $CO_2$, which directs more stability with less coke formation. The high activity is attributed to the better bimetallic synergy and the well-developed crystalline phases of NiO, $ZrO_2$ and $Ce-ZrO_2$. Other bimetallic mixed oxides NCoZ, $NCoC^{4-12}Z$ has faster deactivation with low methanation activity. Finally, 2 wt.% Ce loading catalyst was found to be optimal coke resistant catalyst.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.58 no.4
• /
• pp.795-800
• /
• 2009

Surface plasmon resonance (SPR) has been widely used for biological and chemical sensing applications. The present study investigates numerically the optical characteristics for the single Au film and bimetallic Ag/Au film SPR configurations by using the multiple beam interference matrix (MBIM) method. We use the prism coupling method, especially Kretschmann configuration for excitation of surface plasmon wave (SPW). The estimated results of reflectance, phase shift and magnetic field intensity enhancement factor are provided for finding out the optimum configuration with high sensitivity for SPR measurement. As a result, the optimum thicknesses are found to be 52 nm for a single Au film and 5 nm to 36 nm for bimetallic Ag-Au film. From the comparison of full width half maximum (FWHM) values for reflectance, phase shift, and enhancement of magnetic field intensity, it is concluded that the highest sensitivity can be obtained when using the phase shift for SPR sensor.

• Advances in Computational Design
• /
• v.4 no.1
• /
• pp.33-41
• /
• 2019

In this study, 2-mm Al/Cu bimetallic laminates were produced using asymmetric roll bonding (RB) process. The asymmetric RB process was carried out with thickness reduction ratios of 10%, 20% and 30% and mismatch rolling speeds 1:1, 1:1.1 and 1:1.2, separately. For various experimental conditions, finite element simulation was used to model the deformation of bimetallic Al/Cu laminates. Specific attention was focused on the bonding strength and bonding quality of the interface between Al and Cu layers in the simulation and experiment. The optimization of mismatch rolling speed ratios was obtained for the improvement of the bond strength of bimetallic laminates during the asymmetric RB process. During the finite element simulation, the plastic strain of samples was found to reach the maximum value with a high quality bond for the samples produced with mismatch rolling speed 1:1.2. Moreover, the peeling surfaces of samples around the interface of laminates after the peeling test were studied to investigate the bonding quality by scanning electron microscopy.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.6
• /
• pp.587-595
• /
• 2020

Nickel-based bimetallic catalysts were investigated for use in direct borohydride/hydrogen peroxide fuel cells. For anode and cathode, PdNi and AuNi catalysts were used, respectively. Nickel-based bimetallic catalysts have been investigated through various methods, such as inductively coupled plasma optical emission spectroscopy, transmission electron microscopy, scanning electron microscopy, and energy dispersive spectroscopy. The performance of the catalysts was evaluated through fuel cell tests. The maximum power density of the fuel cell with nickel-based bimetallic catalysts was found to be higher than that of the fuel cell with the monometallic catalysts. The nickel-based bimetallic catalysts also exhibited a stable performance up to 60 minutes.

• Analytical Science and Technology
• /
• v.18 no.2
• /
• pp.130-138
• /
• 2005

Volatile organic compounds (VOCs) have been recognized as major contributor to air pollution. Catalytic oxidation in VOCs can give high efficiency at low temperature. In this study, monometallic Pt, Ir and bimetallic Pt-Ir were supported to $TiO_2$. Xylene, toluene and methyl ethyl ketone (MEK) were used as reactants. The monometallic or bimetallic catalysts were prepared by the excess wetness impregnation method and characterized by XRD, XPS and TEM analysis. Result reveal that Pt catalyst has higher conversion than Ir catalyst and Pt-Ir bimetallic catalysts. The existence of multipoint actives in, Pt-Ir bimetallic catalysts gives improved performance for the Pt metalstate. Bimetallic catalysts have higher conversion for VOCs than monometallic ones. The addition, VOCs oxidation follows first order kinetics. The addition of small amount of Ir to Pt promotes oxidation conversion of VOCs.

• International Journal of Advanced Culture Technology
• /
• v.3 no.2
• /
• pp.110-117
• /
• 2015

10 wt% (Ni-Co) catalysts with different Ni and Co content : 10%Ni, 9%Ni1%Co, 7%Ni3%Co, 5%Ni5%Co, 3%Ni7%Co, and 10%Co; were prepared using sol-gel method followed by incipient wetness impregnation method. To investigate the catalytic activity including the stability, dry methane reforming were demonstrated over the pelletized catalysts at $620^{\circ}C$ under atmospheric pressure in a $CH_4:CO_2:N_2$ feedstock for 360 min. The results showed that bimetallic catalysts with the Co content equal to or greater than 3% were more stable than monometallic catalysts (10%Ni and 10%Co). The temperature programmed hydrogenation interpreted that the additional of Co into Ni catalyst improved the carbon resistance from methane cracking. Promoted this type of bimetallic catalyst using 1wt% K (trimetallic catalyst) prevented the carbon formation on the catalyst. The temperature programmed desorption of $CO_2$ indicated that this trimetallic catalyst has a greater number of strong basic sites. Moreover, the appearance of K lowered the number of weak basic sites and decreased the conversion of methane by 12 %.