• 제목/요약/키워드: BiM

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Determination of Cadmium(II) and Copper(II) by Flame Atomic Absorption Spectrometry after Preconcentration on Column with Pulverized Amberlite XAD-4 with Bismuthiol I

  • Park, Dong-Seok;Choi, Hee-Seon
    • Bulletin of the Korean Chemical Society
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    • 제28권8호
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    • pp.1375-1382
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    • 2007
  • A column preconcentration method with pulverized Amberlite XAD-4 loaded with bismuthiol I (BI) has been developed for the determination of trace Cd(II) and Cu(II) in various real samples by flame atomic absorption spectrophotometry. Various experimental conditions, such as the size of XAD-4, adsorption flow rate, amount of bismuthiol I, stirring time for adsorbing bismuthiol I on XAD-4, pH of sample solution, amount of XAD-4- BI, desorption solvent, and desorption flow rate, were optimized. Also, the adsorption capacity and the adsorption rate of Cd(II) and Cu(II) on XAD-4-BI were investigated. The interfering effects of various concomitant ions were investigated, Bi(III), Sn(II) and Fe(III) were found to affect the determination. But the interference by these ions was completely eliminated by adjusting the amount of XAD-4-BI resin to 0.70 g, although the adsorption flow rate was slower. For Cd(II) our proposed technique obtained a dynamic range of 0.5-40 ng mL-1, a correlation coefficient (R2) of 0.9913, and a detection limit of 0.3 ng mL-1. For Cu(II), the corresponding values were 2.0-120 ng mL-1, 0.9921 and 1.02 ng mL-1. To validate this proposed technique, the aqueous samples (stream water, reservoir water, tap water and wastewater), the diluted brass sample and the plastic sample, as real samples, were used. Recovery yields of 91-103% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. Our proposed method was also validated using rice flour CRM (normal, fortified) samples. From the results of our experiment, we found that the technique we present here can be applied to the determination of Cd(II) and Cu(II) in various real samples.

『상한론』에서 산제의 방촌비와 전비, 환제의 오동자대 크기 수정치 (Revision Volume of Square-inch-spoon, Jeon-bi and Firmiana-Seed-sized Pill Preparations in 『Treatise on Cold Damage Diseases』)

  • 김인락
    • 대한본초학회지
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    • 제37권5호
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    • pp.75-81
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    • 2022
  • Objectives : In 『Treatise on Cold Damage Diseases』, the volume of preparation dosage measured in Hap was 6.5mL. This study aimed to confirm that a square-inch-spoon, which measures powder preparation dosage, was 1/3 Hap, and that Jeon-bi was 1/8 square-inch-spoon. Based on these values, this study also aimed to adjust the diameter of Firmiana-Seed-sized pill preparation, currently known as 6.5mm, so that one square-inch-spoon of powder preparation creates 16 pills. Methods : Calculated the ratio between the floor areas of square-inch-spoon and Jeon-bi and measured the ratio of volume; assumed that powder preparations were stacked as much as possible in the shape of a square pyramid when scooped comfortably, then calculated the slopes of 1/3 Hap and 1/4 Hap; measured the volumes of powdered Oryeongsan and Lijungwhan in square-inch-spoon and Jeon-bi; created the powders into Firmiana-Seed-sized pill preparation; adjusted the diameter of Firmiana Seed so that 16 pills could be created. Results : Inferring from the floor areas, the volume of square-inch-spoon is 9.2 times that of Jeon-bi; one square-inch-spoon should be 1/3 Hap for the powder to reach its maximum slope of 47° and, according to actual measurement of powder preparations, reach its maximum volume; when created into Firmiana-Seed-sized pill preparations, one square-inch-spoon should be 1/3 Hap so that approximately 16 pills were created. Conclusions : One square-inch-spoon of powder preparation was 1/3 Hap(2.17mL), Jeon-bi was 1/8 square-inch-spoon(0.27mL), and the diameter of Firmiana-Seed-sized pill preparation was 5.5mm.

Bi-Sr-Ca-O계에서 초전도상의 형성에 관한 상평형 (Phase Equilibria for the Formation of Superconducting Phases in the Bi-Sr-Ca-O System)

  • 김철진
    • 한국재료학회지
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    • 제3권4호
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    • pp.410-421
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    • 1993
  • Bi-Sr-Ca-O 초전도성계에서 $Bi_2O_3-(Sr_2CaCu_2O_x$)의 pseude binary계를 선택하여 $Sr_2CaCu_2O_x$$Bi_2O_3$를 5%단위로 40 cation mole% Bi까지 첨가하면서 $850^{\circ}C$ 초전도상 및 공존하는 상들의 평형 및 반응 경로들을 XRD, SEM, EDS, DTA를 이용하여 분석하였다. Bi의 함량이 35 mole% Bi보다 클 때에는 $Bi_2Sr_2CaCu_2O_8$상과 공존하는 액상이 형성되며 2212상의 액상으로 존재하며 액상의 냉각시 제일 먼저 $Bi_2Sr_2CaCu_2O_8$상 주의에 석출된 것이 관찰되었다.

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Annealing Temperature Dependence of Magnetic and Optic Properties of Bi:YIG Films Deposited with Aerosol Deposition Method

  • Shin, Kwang-Ho;Mizoguchi, Masahiko;Inoue, Mitsuteru
    • Journal of Magnetics
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    • 제12권3호
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    • pp.129-132
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    • 2007
  • Bismuth-substituted yttrium iron garnet (Bi:YIG, $Bi_{0.5}Y_{2.5}Fe_5O_{12}$) films were deposited with aerosol deposition method and their magnetic and optical properties were investigated as a function of annealing temperature. Since the ceramic films deposited with aerosol deposition method have not a perfect crystal structure due to non-uniform internal stress occurred by mechanical collision during their deposition, the post annealing could be a key process to release its internal stress and to improve its micro structure for optimizing the magnetic and magneto-optic properties of films. The crystallinity of Bi: YIG film was improved with increase of annealing temperature, and the saturation magnetization increased up to 87 emu/cc at $800^{\circ}C$. The Faraday rotation increased up to $1.4deg/{\mu}m$ by annealing at $700^{\circ}C$ around the wavelength of $0.5{\mu}m$. The optical transmittance of the Bi:YIG film was also improved in visible region.

LARGE MAGNETORESISTANCE OF SPUTTERED BI THIN FILMS AND APPLICATION OF SPIN DEVICE

  • M. H. Jeun;Lee, K. I.;Kim, D. Y.;J. Y. Chang;K. H. Shin;S. H. Han;J. G. Ha;Lee, W. Y.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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    • pp.66-67
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    • 2003
  • Bismuth (Bi) has been an attractive materials for studying spin dependent transport properties because it shows very large magnetoresistance (MR) resulting from its highly anisotropic Fermi surface, low carrier concentrations, long carrier mean free path 1 and small effective carrier mass m*[1-3]. With all the intriguing properties, difficulty in fabrication of high quality Bi thin films may have prevented extensive application of Bi in magnetic field sensing and spin-injection devices. Previous works found that the surface roughness and small grain size in 100-200 nm of Bi thin film made by evaporation and sputtering are major causes of low MR. Although relatively higher MR in electrodeposited Bi followed by annealing was reported, it still suffers from rough sulfate roughness which is so severs that it is hardly able to make a field sensing and spin-injection device using conventional photolithography process.

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Billet 장입 방식을 이용 제조한 Bi(Pb)-Sr-Ca-Cu-O 초전도 선재의 특성 (Characteristics of Bi(Pb)-Sr-Ca-Cu-O Superconductor Wire Fabricated using the Billet Insertion Method)

  • 장건익;유재근;홍계원
    • 한국세라믹학회지
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    • 제33권4호
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    • pp.471-477
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    • 1996
  • During Bi(Pb)-Sr-Ca-Cu-O superconductor wire fabrication the effect of the initial packing density on the final characteristics of superconductor wire was systematically studied. To increase the powder packing density with uniform distribution of superconducting core a billet insertion method processed by CIP was applied instead of the commonly used vibration and ramming method of powder insertion into silver sheath. Compared with the vibration and ramming method the billent insertion technique processed by CIP cause the 30% incre-specimen with 130${\mu}{\textrm}{m}$(core thickness : 45 ${\mu}{\textrm}{m}$)and 5.24 mm width processed at 84$0^{\circ}C$for 200hrs. shows specimen with 130${\mu}{\textrm}{m}$ (core thickness ; 45${\mu}{\textrm}{m}$)and 5.24 mm width processed at 84$0^{\circ}C$ for 200 hrs. shows maximum 34A for Ic and 16, 700 A/cm2 for Ic measured at 77K and 0T. Also the sample rolled 3 times shows maximum 7, 2A for Ic and 11, 000 A/cm2 for 77K and 0T. Based on X-ray experimental results the formation of Bi-2223 and texture were significantly well developed at the interface between the superconducting core and silver sheath as compared with those of the interior area of superconducting core.

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임무 환경에 따른 무인항공기 가시선 분석 (An analysis of UAV line-of-sight according to mission environment)

  • 최준수;허창우
    • 한국정보통신학회논문지
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    • 제17권6호
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    • pp.1414-1418
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    • 2013
  • 본 논문은 무인항공기의 운용 고도 및 거리를 데이터링크 측면에서 분석하였다. 무인항공기의 운용 고도는 일반적으로 탑재되는 임무장비의 특성 및 운용 목적에 따라 결정된다. 무인항공기의 운용 고도를 결정하기 전에 데이터링크 장비의 가시선 조건을 반드시 고려해야 한다. 가시선 분석은 지상통신장비의 안테나 특성 및 설치고도, 지구의 곡률 반경을 사용하여 분석했다. 지상통신장비 설치고도가 0m 일 때, 32dBi 파라볼라 안테나를 사용할 경우 통신거리 300km에서 15,779m이고, 44dBi 파라볼라 안테나를 사용할 경우 7,927m에서 운용 가능하다. 또한 원거리 통신에서는 고 이득안테나가 운용 고도 측면에서 유리함을 확인하였다.

가시선 통신거리에 따른 무인항공기 운용 고도 분석 (An Analysis of UAV operation altitude according to Line-Of-Sight communication range.)

  • 최준수;허창우
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2013년도 춘계학술대회
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    • pp.783-785
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    • 2013
  • 본 논문은 무인항공기의 운용 고도 및 거리를 데이터링크 측면에서 분석하였다. 무인항공기의 운용 고도는 일반적으로 탑재되는 임무장비의 특성 및 운용 목적에 따라 결정된다. 무인항공기의 운용고도를 결정하기 전에 데이터링크 장비의 가시선 조건을 반드시 고려해야 한다. 가시선 분석은 지상통신장비의 안테나 특성 및 설치고도, 지구의 곡률 반경을 사용하여 분석했다. 지상통신장비 설치고도가 0m 일 때, 32dBi 파라볼라 안테나를 사용할 경우 통신거리 300km에서 13,724m이고, 44dBi 파라볼라 안테나를 사용할 경우 6,657m에서 운용 가능하다. 또한 원거리 통신에서는 고 이득안테나가 운용 고도 측면에서 유리함을 확인하였다.

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