• Title/Summary/Keyword: Bi-stability

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A Study on the Emulsion Polymerization of Methyl Methacrylate (Methyl Methacrylate의 Emulsion Polymerization에 關한 硏究)

  • Lee, Hyung-Kyoo;Min, Tae-Ik
    • Journal of the Korean Chemical Society
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    • v.12 no.1
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    • pp.4-11
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    • 1968
  • With the selected emulsifiers for the emulsion polymerization of methyl methacrylate, the HLB of the emulsifier in the reaction system has been studied on the effect of the ratio of tetra sodium-N-(1,2-dicarboxy ethyl)-N-octadecyl sulfosuccinamate(Aerosol 22) to polyethylene glycol nonyl phenyl ether (Noigen EA 160), and also sodium lauryl sulfate(Quolac EX-UB), Disodium-N-octadecyl sulfosuccinamate (Aerosol 18) and Aerosol 22 as emulsifiers having various hydrophilic groups in the molecules have been studied. Results are as follows; 1) The viscosity of the emulsions and the molecular weight of the polymers have maximum values at a constant HLB value of emulsifiers, but their stabilities show minimum point at the value with the titration with the three kinds of mono, bi, tri-valent electrolytes. These results are agreed on the theory of Greth & Wilson in which the properties of polymer emulsions depend upon the HLB system of emulsifiers. 2) The viscosity of the emulsions and the molecular weights of the produced polymers increase more in the case of blending of Aerosol 22 to Noigen EA-160 than of the separate using. 3) The coagulation effects of the divalent electrolytes($ex,\;Ca^{++},\;Zn^{++}$) are contrast to the effects of monovalent($ex,\;Na^+$) and trivalent($ex,\;Al^{+++}$) in the emulsions with Aerosol 18 or Aerosol 22 which have more than two hydrophilic groups. It seems that the stability of the O/W emulsions by electrolytes is directly related to the parameters of surface physical chemistry such as surface geometry of surface chemical constitution of polymer particles.

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Properties and Manufacturing of Low Melting Alloy Impregnated Wood Composites for using Domestic Thinned Logs of Juglans mandshurica (국산 가래나무 간벌재활용을 위한 금속주입목재의 제조 및 특성)

  • Park, Kye-Shin;Lee, Hwa-Hyoung
    • Korean Journal of Agricultural Science
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    • v.37 no.3
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    • pp.457-464
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    • 2010
  • The low melting alloy impregnated wood composites with natural grain of thinned Juglans mandshurica was made and evaluated in this study. And the proper manufacturing conditions was also investigated in this study. The low melting alloy with bismuth(Bi) and tin(Sn) which are harmless to humans, was applied for this novel composites, which showed not only no defects of discoloration, delamination, swelling, and cracking, because of high dimensional stability and low thickness swelling, but also much improved performance such as high bending strength, high hardness, low abrasion, high thermal conductivity as floor materials. This study also suggested the proper impregnating condition, such as 10 minutes of the preliminary vacuum time, $187^{\circ}C$ of the heating temperature and 10 minutes of the maintaining pressure time at the pressure of 30kgf/$cm^2$. The produced composites showed 9 times higher density for small specimen, 6.6 times for actual size sample and great increase in bending strength from 102.05N/$mm^2$ to 189.47N/$mm^2$ for small size sample and to 205.4N/$mm^2$ for actual size sample, also great increase in hardness from 15.1N/$mm^2$ to 73.38N/$mm^2$ for small size sample and 64.87N/$mm^2$ for actual size sample. And the composites demonstrated great decrease in abrasion depth and in water absorption.

Fabrication of Thin Solid Oxide Film Fuel Cells

  • Jee, Young-Seok;Chang, Ik-Whang;Son, Ji-Won;Lee, Jong-Ho;Kang, Sang-Kyun;Cha, Suk-Won
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.82-85
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    • 2010
  • Recently, thin film processes for oxides and metal deposition, such as physical vapor deposition (PVD) and chemical vapor deposition (CVD), have been widely adapted to fabricate solid oxide fuel cells (SOFCs). In this paper, we presented two research area of the use of such techniques. Gadolinium doped ceria (GDC) showed high ionic conductivity and could guarantee operation at low temperature. But the electron conductivity at low oxygen partial pressure and the weak mechanical property have been significant problems. To solve these issues, we coated GDC electrolyte with a nano scale yittria-doped stabilized zirconium (YSZ) layer via atomic layer deposition (ALD). We expected that the thin YSZ layer could have functions of electron blocking and preventing ceria from the reduction atmosphere. Yittria-doped barium zirconium (BYZ) has several orders higher proton conductivity than oxide ion conductor as YSZ and also has relatively high chemical stability. The fabrication processes of BYZ is very sophisticated, especially the synthesis of thin-film BYZ. We discussed the detailed fabrication processes of BYZ as well as the deposition of electrode. This paper discusses possible cell structure and process flow to accommodate such films.

Reliability Analysis of Stability of Berm Breakwaters (소단형 방파제의 안정성에 대한 신뢰성 해석)

  • Lee, Cheol-Eung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.19 no.5
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    • pp.399-407
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    • 2007
  • Two reliability models, AFDA(Approximate Full Distribution Approach) and Monte-Carlo simulation method, are directly developed to study on both hydraulic failure mode of berm recession and structural failure mode of armour breakage of berm breakwaters. By comparing the present results with the results of other researcher, it may be confirmed that two reliability models can be straightforwardly applicable to berm breakwaters. Relative influence of each random variable on hydraulic and structural failure probabilities could be properly analyzed. The upper bound and the lower bound of failure probability can be evaluated by using bi-modal bounds of the multiple failure mode analysis, from which it may be possible to investigate some kinds of dependence into between two failure modes. Finally, it may also be found that the structural failure mode of armour breakage could become a main failure mode of berm breakwaters in the condition of more than any allowable berm recession.

Studies on the Inulin hydrolyzing enzyme produced by Aspergillus sp. (C-74 strain) Part 1. Some properties of the Inulin hydrolyzing enzyme from selected strain (Aspergillus sp. (C-74 strain)가 생산하는 Inulin 분해효소에 관한 연구 (제 1보) 분리선별한 균주효소의 효소학적 성질)

  • 권태종;정호권;강효원;서정훈
    • Microbiology and Biotechnology Letters
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    • v.1 no.1
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    • pp.37-42
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    • 1973
  • C-74 belonging to the genus of Aspergillus species was selected from two hundred and seventy microorganisms stored at the lab, of microbiology. 1. Sample Inulase was precipitated mainly at pH 8 to 5 by isoelectric point fraction method. 2. The optimum pH of Inulase activity of the enzyme from C-74 strain was about 3.0 3. The optimum temperature of Inulase activity of the enzyme from C-74 strain was about $55^{\circ}C$ 4. The Inulase from C-74 strain was stable at $50^{\circ}C$ for 10mins. 5. The range of the pH stability of the Inulase from C-74 strain was about 2.5-4.5 6. Effect of metal ions on the Inulase activity of the enzyme from C-74 strain was activated by Mg$\^$++/, Sb$\^$+++/ and inhibited by Ag$\^$++/, Hg$\^$++/.

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Seismic Reliability Assessment of the Korean 345 kV Electric Power Network considering Parallel Operation of Transformers (변압기의 병렬 운전을 고려한 국내 345kV 초고압 전력망의 지진 재해 신뢰성 평가)

  • Park, Won-Suk;Park, Young-Jun;Cho, Ho-Hyun;Koh, Hyun-Moo
    • Journal of the Earthquake Engineering Society of Korea
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    • v.10 no.3 s.49
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    • pp.13-20
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    • 2006
  • Substations in electric power transmission network systems (EPTS) operate using several transformers in parallel to increase the efficiency in terms of stability of energy supply. We present a seismic reliability assessment method of EPTS considering the parallel operation of transformers. Two methods for damage state model are compared in this paper: bi-state and multi-damage model. Simulation results showed that both models yielded similar network reliability indices and the reliability indices of the demand nodes using hi-state model exhibited higher damage probability. Particularly, the corresponding EENS (Expected Energy Not Supplied) index was significantly larger than that of the multi-damage state.

Investigation of gamma radiation shielding capability of two clay materials

  • Olukotun, S.F.;Gbenu, S.T.;Ibitoye, F.I.;Oladejo, O.F.;Shittu, H.O.;Fasasi, M.K.;Balogun, F.A.
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.957-962
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    • 2018
  • The gamma radiation shielding capability (GRSC) of two clay-materials (Ball clay and Kaolin)of Southwestern Nigeria ($7.49^{\circ}N$, $4.55^{\circ}E$) have been investigated by determine theoretically and experimentally the mass attenuation coefficient, ${\mu}/{\rho}(cm^2g^{-1})$ of the clay materials at photon energies of 609.31, 1120.29, 1173.20, 1238.11, 1332.50 and 1764.49 keV emitted from $^{214}Bi$ ore and $^{60}Co$ point source. The mass attenuation coefficients were theoretically evaluated using the elemental compositions of the clay-materials obtained by Particle-Induced X-ray Emission (PIXE) elemental analysis technique as input data for WinXCom software. While gamma ray transmission experiment using Hyper Pure Germanium (HPGe) spectrometer detector to experimentally determine the mass attenuation coefficients, ${\mu}/{\rho}(cm^2g^{-1})$ of the samples. The experimental results are in good agreement with the theoretical calculations of WinXCom software. Linear attenuation coefficient (${\mu}$), half value layer (HVL) and mean free path (MFP) were also evaluated using the obtained ${\mu}/{\rho}$ values for the investigated samples. The GRSC of the selected clay-materials have been compared with other studied shielding materials. The cognizance of various factors such as availability, thermo-chemical stability and water retaining ability by the clay-samples can be analyzed for efficacy of the material for their GRSC.

SAL 10-6 and Cytotoxicity of Sanitary Aid Products Utilizing Gamma Sterilization Technology (감마선 멸균기술을 이용한 의약외품의 무균보증수준(SAL 10-6) 확보 및 세포독성 평가)

  • Kim, Kwang Hoon;Eom, Yong Woon;Lee, Hoo Chul;Park, Sung Hyun;Kim, Soo Jin;Kim, Kwan Soo;Park, Soon Youn;Jeong, Ill Yun
    • Journal of Radiation Industry
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    • v.8 no.2
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    • pp.133-140
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    • 2014
  • The sterilization of health care products is widely used to choose conventional Ethylene Oxide gas sterilization in South Korea. But the method has brought serious issues because of the toxic residual gas and global warming of $CO_2$ evacuation after the sterilization process. This study is carried out to confirm the application possibility of gamma sterilization instead of Ethylene Oxide in sanitary aid products. Four kinds of products (gauze, menstrual pad, bandage, menstrual tampon) were treated with gamma irradiation of 15 kGy, then analyzed the achievement of the sterility assurance level (SAL) $10^{-6}$ through BI test. The cytotoxicity of accelerated samples of 6 months elapse evaluated by means of colony forming rate at various concentration of the extracts. pH and UV measurements at extract concentrations were tested according to the MFDS (Ministry of food & drug safety) guideline to verify a stability & safety of product sterilized. The results revealed that the extracts did not show any significant changes in cytoxicity assay as well as pH and UV values by gamma sterilization. All extract concentration was observed high cell viability, pH and UV values were calculated within the acceptable range prescribed by the guideline. It indicates that gamma sterilization could effectively substitute for conventional sterilization such as Ethylene Oxide sterilization in the sanitary aid products.

Research Trend and Histories of Rocket Engines using Hydrogen Peroxide and Liquid Methane as Green Propellants (친환경 추진제인 과산화수소와 액체메탄의 활용 역사와 연구 동향)

  • Kim, Sun-Jin;Lee, Yang-Suk;Ko, Young-Sung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.14 no.4
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    • pp.46-58
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    • 2010
  • Hydrogen peroxide(HP) and liquid methane have deserved renewed considerations as green propellants in recent years, because main design concerns in the development of the new generation propulsion system for spacecrafts are concentrated on low operation cost and environmental cleanness. Although HP has a long history of application to aerospace propulsion systems due to high density, mono-propellant characteristics and low toxicity, it had been replaced by hydrazine and liquid oxygen due to extreme performance requirement during the cold war. But HP has received a renewed interest due to its increased stability and many researches have been conducted to develop high performance LREs(Liquid Rocket Engines) using HP. Liquid methane has also received a new interest in rocket propulsion system for the future space exploration according to its possibility of ISRU(In-Situ Resource Utilization).

ACOX1 destabilizes p73 to suppress intrinsic apoptosis pathway and regulates sensitivity to doxorubicin in lymphoma cells

  • Zheng, Fei-Meng;Chen, Wang-Bing;Qin, Tao;Lv, Li-Na;Feng, Bi;Lu, Yan-Ling;Li, Zuo-Quan;Wang, Xiao-Chao;Tao, Li-Ju;Li, Hong-Wen;Li, Shu-You
    • BMB Reports
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    • v.52 no.9
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    • pp.566-571
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    • 2019
  • Lymphoma is one of the most curable types of cancer. However, drug resistance is the main challenge faced in lymphoma treatment. Peroxisomal acyl-CoA oxidase 1 (ACOX1) is the rate-limiting enzyme in fatty acid ${\beta}$-oxidation. Deregulation of ACOX1 has been linked to peroxisomal disorders and carcinogenesis in the liver. Currently, there is no information about the function of ACOX1 in lymphoma. In this study, we found that upregulation of ACOX1 promoted proliferation in lymphoma cells, while downregulation of ACOX1 inhibited proliferation and induced apoptosis. Additionally, overexpression of ACOX1 increased resistance to doxorubicin, while suppression of ACOX1 expression markedly potentiated doxorubicin-induced apoptosis. Interestingly, downregulation of ACOX1 promoted mitochondrial location of Bad, reduced mitochondrial membrane potential and provoked apoptosis by activating caspase-9 and caspase-3 related apoptotic pathway. Overexpression of ACOX1 alleviated doxorubicin-induced activation of caspase-9 and caspase-3 and decrease of mitochondrial membrane potential. Importantly, downregulation of ACOX1 increased p73, but not p53, expression. p73 expression was critical for apoptosis induction induced by ACOX1 downregulation. Also, overexpression of ACOX1 significantly reduced stability of p73 protein thereby reducing p73 expression. Thus, our study indicated that suppression of ACOX1 could be a novel and effective approach for treatment of lymphoma.