• Title/Summary/Keyword: Bi-functionality

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Development of Micro-Tubular Perovskite Cathode Catalyst with Bi-Functionality on ORR/OER for Metal-Air Battery Applications

  • Jeon, Yukwon;Kwon, Ohchan;Ji, Yunseong;Jeon, Ok Sung;Lee, Chanmin;Shul, Yong-Gun
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.425-431
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    • 2019
  • As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

Numerical Study of a Novel Bi-focal Metallic Fresnel Zone Plate Having Shallow Depth-of-field Characteristics

  • Kim, Jinseob;Kim, Juhwan;Na, Jeongkyun;Jeong, Yoonchan
    • Current Optics and Photonics
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    • v.2 no.2
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    • pp.147-152
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    • 2018
  • We propose a novel bi-focal metallic Fresnel zone plate (MFZP) with shallow depth-of-field (DOF) characteristics. We design the specific annular slit patterns, exploiting the phase-selection-rule method along with the particle swarm optimization algorithm, which we have recently proposed. We numerically investigate the novel characteristics of the bi-focal MFZP in comparison with those of another bi-focal MFZP having equivalent functionality but designed by the conventional multi-zone method. We verify that whilst both bi-focal MFZPs can produce dual focal spots at $15{\mu}m$ and $25{\mu}m$ away from the MFZP plane, the former exhibits characteristics superior to those of the latter from the viewpoint of axial resolution, including the axial side lobe suppression and axial DOF shallowness. We expect the proposed bi-focal MFZP can readily be fabricated with electron-beam evaporation and focused-ion-beam processes and further be exploited for various applications, such as laser micro-machining, optical trapping, biochemical sensing, confocal sensing, etc.

CityDataHub-based Smart-Platform Design for Dissemination of Smart City Data Hub (스마트시티 데이터허브 보급을 위한 시티데이터허브 기반 스마트 플랫폼 설계)

  • Lee, Geum Bi;Kim, Ki Su;Kang, Seung Hag
    • The Journal of Information Systems
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    • v.31 no.4
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    • pp.101-121
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    • 2022
  • Purpose This study aims to introduce a Smart-Platform for solving numerous problems in urban cities and improving citizens' convenience. This Smart-Platform is achieved by studying the City Data Hub technology to build and spread a Smart City Data Hub . Design/methodology/approach In this study, we analyzed the functions in detail and interlocking flows specific to the published City Data Hub module and designed a Smart-Platform with additional UI-based functions to improve users' convenience based on our previous experience. Findings The City Data Hub will provide a modular data hub platform functionality for application by different stakeholders. However, further research on detailed functionality and experience in interworking legacy systems will be required to apply the platform realistically. Therefore, we judged that this Smart-Platform, which supplements the City Data Hub with additional functions, would be useful for utilizing the City Data Hub in the future. Through the demonstration of the platform designed, it is also necessary to explore the direction of continuous development for the future.

Wafer-Level Three-Dimensional Monolithic Integration for Intelligent Wireless Terminals

  • Gutmann, R.J.;Zeng, A.Y.;Devarajan, S.;Lu, J.Q.;Rose, K.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.4 no.3
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    • pp.196-203
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    • 2004
  • A three-dimensional (3D) IC technology platform is presented for high-performance, low-cost heterogeneous integration of silicon ICs. The platform uses dielectric adhesive bonding of fully-processed wafer-to-wafer aligned ICs, followed by a three-step thinning process and copper damascene patterning to form inter-wafer interconnects. Daisy-chain inter-wafer via test structures and compatibility of the process steps with 130 nm CMOS sal devices and circuits indicate the viability of the process flow. Such 3D integration with through-die vias enables high functionality in intelligent wireless terminals, as vertical integration of processor, large memory, image sensors and RF/microwave transceivers can be achieved with silicon-based ICs (Si CMOS and/or SiGe BiCMOS). Two examples of such capability are highlighted: memory-intensive Si CMOS digital processors with large L2 caches and SiGe BiCMOS pipelined A/D converters. A comparison of wafer-level 3D integration 'lith system-on-a-chip (SoC) and system-in-a-package (SiP) implementations is presented.

Synthesis and Characterization of Low Molecular Weight Poly(methyl acrylate)-b-Polystyrene by a Combination of ATRP and Click Coupling Method

  • Hasneen, Aleya;Kim, Su-Jeong;Paik, Hyun-Jong
    • Macromolecular Research
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    • v.15 no.6
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    • pp.541-546
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    • 2007
  • The combination of atom transfer radical polymerization (ATRP) and click chemistry was employed for the efficient preparation of well-defined block copolymers. Bromo terminated poly(methyl acrylate) (pMA-Br) was prepared by an ATRP initiator, ethyl-2-bromoisobutyrate (EBiB). Subsequently, the bromine chain end of pMA-Br was converted to an azide group by simple nucleophilic substitution reaction. ${\alpha}-Alkyn-{\omega}-bromo-functionalized$ polystyrene was also synthesized by ATRP using the alkyn-functionalized initiator, propargyl-2-bromoisobutyrate (PgBiB). In both cases, the conversion was limited to a low level to ensure a high degree of chain end functionality. Then the coupling reaction between the azide end group in $pMA-N_3$ and alkyn-functionalized PgBiB-pSt was performed by Cu(I)catalysis. This coupling reaction was monitored by gel permeation chromatography (GPC). The synthesized block copolymer was characterized by FT-IR, $^1H-NMR$ spectroscopy and $^1H-^1H$ COSY correlation spectroscopy.

Developing a prototype of bi-stretch pants for women in their 20s and 30s with overweight lower bodies (20~30대 하체비만형 여성을 위한 양방향 스트레치 팬츠 원형 개발)

  • Ha, Hee-Jung;Seong, Ok-Jin
    • The Research Journal of the Costume Culture
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    • v.21 no.2
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    • pp.246-260
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    • 2013
  • This research was carried out on women in their 20s and 30s who have overweight lower body. The subjects selected for this study were women a Rohrer index of 1.6 or higher, a waist circumference 78.5cm to 83.5cm, and a lower drop of at least 18cm. The aim is to propose a prototype of bi-stretch pants meeting demands for both functionality and aesthetic appeal. Various clothing patterns ease amount of the waist and hip circumferences and crotch depths and were developed. They had different crotch widths, and center back line angles. The results showed that the best pants patterns were ease 1cm to the total hip circumference. The front hip circumference was H/4-0.5cm, and the back hip circumference was H/4+1cm. The front crotch width was H/20+1cm, the back crotch width was H/10+3cm. No additional ease was given to the total waistline. The front waist circumference was W/4+0.5cm. The back waist circumference was W/4-0.5cm. The knee circumference was set at 44cm, the pant hem width was set at 36cm, and the pant length was set at 100cm-5cm. The findings of this research can be used as basic data for stretch pants that fit the abdomen, hips, and thighs for women in their 20s and 30s with overweight lower body.

A Storage Scheme for Logging and Indexing B2Bi XML Messages (기업간통합 XML 메시지의 기록과 색인을 위한 저장 방식)

  • Song Ha-Joo;Kim Chang-Su;Kwon Oh-Heum
    • Journal of KIISE:Computing Practices and Letters
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    • v.11 no.5
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    • pp.416-426
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    • 2005
  • A B2Bi system needs a message storage subsystem that efficiently logs and searches XML messages which have been sent from orreceived by it. XML database systems and XML enabled relational databases systems are not adequate as a message storage system because of their expensiveness and excessiveness in functionality. Storage schemes that split XML messages into database records are also unacceptable because of either low performance or implementation hardness. In this paper, we propose a storage scheme that can be applied to implement a message storage system based on a relational database system. In this scheme, messages are examined only through the index fields that have been registered for each message types. Therefore, the proposed storage scheme cannot support such a powerful search facility like XQL, but it provides high performance message legging and restricted search facility. There are three alternative database schemas to store the index fields. This paper compares the advantages and disadvantages of the three schemas through experimental tests.

HVEM is a TNF Receptor with Multiple Regulatory Roles in the Mucosal Immune System

  • Shui, Jr-Wen;Kronenberg, Mitchell
    • IMMUNE NETWORK
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    • v.14 no.2
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    • pp.67-72
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    • 2014
  • The herpes virus entry mediator (HVEM) is a member of the tumor necrosis factor receptor superfamily (TNFRSF), and therefore it is also known as TNFRSF14 or CD270 (1,2). In recent years, we have focused on understanding HVEM function in the mucosa of the intestine, particularly on the role of HVEM in colitis pathogenesis, host defense and regulation of the microbiota (2-4). HVEM is an unusual TNF receptor because of its high expression levels in the gut epithelium, its capacity to bind ligands that are not members of the TNF super family, including immunoglobulin (Ig) superfamily members BTLA and CD160, and its bi-directional functionality, acting as a signaling receptor or as a ligand for the receptor BTLA. Clinically, Hvem recently was reported as an inflammatory bowel disease (IBD) risk gene as a result of genome wide association studies (5,6). This suggests HVEM could have a regulatory role influencing the regulation of epithelial barrier, host defense and the microbiota. Consistent with this, using mouse models, we have revealed how HVEM is involved in colitis pathogenesis, mucosal host defense and epithelial immunity (3,7). Although further studies are needed, our results provide the fundamental basis for understanding why Hvem is an IBD risk gene, and they confirm that HVEM is a mucosal gatekeeper with multiple regulatory functions in the mucosa.

The Role of Garden Plants in Modern Culture - Focusing Japanese Garden Plants -

  • Koshio, Kaihei;Kim, Tae-Soon;Shin, Jeong-Hwa;Song, Won-Seob;Boo, Hee-Ock
    • Korean Journal of Plant Resources
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    • v.24 no.3
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    • pp.330-336
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    • 2011
  • The recent disaster of earthquake and tsunami on March 11, 2011 severely attacked East Japanese cities and people, and in addition, the accident of nuclear power station will inevitably damage the agricultural activities there. The economical depression influences on the horticulture and floriculture industry as well, through the reluctant consumption all over the country. Such a situation reflects a conventional perception that the garden plants or ornamental plants have been regarded as a symbol of capitalism, representing the success, luxury, beauty or other metaphors indicating the winners of business war. But as the word "culture" means "cultivation" originally, horti "culture" or flori "culture" should have played some roles in cultivating lands as well as cultivation of human minds, leading to develop a modern "culture" which may lay emphases on personality, originality, partnership, cooperation, diversity and so forth. In this article, a brief history of garden plants in Japan, as well as some current movements in Japanese horticulture and floriculture, is reviewed with some commodities which possess messages on creating a new humane culture.

Rapid Electric Vehicle Charging System with Enhanced V2G Performance

  • Kang, Taewon;Kim, Changwoo;Suh, Yongsug;Park, Hyeoncheol;Kang, Byungik;Kim, Simon
    • Proceedings of the KIPE Conference
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    • 2012.07a
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    • pp.201-202
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    • 2012
  • This paper presents a simple and cost-effective stand-alone rapid battery charging system of 30kW for electric vehicles. The proposed system mainly consists of active front-end rectifier of neutral point clamped 3-level type and non-isolated bi-directional dc-dc converter of multi-phase interleaved half-bridge topology. The charging system is designed to operate for both lithium-polymer and lithium-ion batteries. The complete charging sequence is made up of three sub-interval operating modes; pre-charging mode, constant-current mode, and constant-voltage mode. Each mode is operated according to battery states: voltage, current and State of Charging (SOC). The proposed system is able to reach the full-charge state within less than 16min for the battery capacity of 8kWh by supplying the charging current of 67A. The optimal discharging algorithm for Vehicle to the Grid (V2G) operation has been adopted to maintain the discharging current of 1C. Owing to the simple and compact power conversion scheme, the proposed solution has superior module-friendly mechanical structure which is absolutely required to realize flexible power expansion capability in a very high-current rapid charging system. Experiment waveforms confirm the proposed functionality of the charging system.

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