• 한국초전도학회:학술대회논문집
• /
• 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
• /
• pp.262-267
• /
• 2000

To tap the possibility of exploiting the precipitates as flux-pinning center in the Bi-2223 superconducting system, as-received Bi-2223/Ag tapes with the starting composition of Bi$_{1.8}$Pb$_{0.4}$Sr$_2$Ca$_{2.2}$Cu$_3$O$_8$ were post-annealed at various temperature, oxygen partial pressure, and annealing time. The 2$^{nd}$ phases in the annealed specimen were analysed with XRD, SEM, TEM, and EDS. The size and the distribution of the precipitates such as (Ca,Sr)$_2$(Pb,Bi)O$_4$ and Bi$_{0.5}$Pb$_3$Sr$_2$Ca$_2$CuO$_{12+{\delta}}$ (3221) in the Bi-2223 matrix was controllable by varying heat-treatment condition without breaking the connectivity of the 2223 grains. The nano-size precipitates within the 2223 grains are conjectured as working as flux-pinning sites, resulting in increased J$_c$ value.

• 한국초전도저온공학회:학술대회논문집
• /
• 한국초전도저온공학회 2002년도 학술대회 논문집
• /
• pp.249-252
• /
• 2002

The change of critical current with a crack formation in a Bi-2223/Ag tape was studied by experimental and numerical analyses. Critical current of Bi-2223/Ag tape was measured with a continuous DC-power supply. The current-voltage relation of a Bi-2223/Ag tape is measured by the four point method. Numerical method is used to solve two dimensional heat conduction equation. By comparing the experimental and numerical results, the validity of numerical method is verified.

• 한국초전도저온공학회:학술대회논문집
• /
• 한국초전도저온공학회 2001년도 학술대회 논문집
• /
• pp.65-67
• /
• 2001

Temperature and resistance of a Bi-2223 tape for fault currents up to 10 $I_{c}$ were measured in two types of samples taking into account real applications. The results indicate that the Bi-2223 tape is safe from burn-out for fault currents with a few cycles up to 10 I$_{c}$. For fault currents of over an order of magnitude higher than the nominal current, the temperature of the Bi-2223 tape depends strongly on fault durations.s.

• Progress in Superconductivity
• /
• 제6권2호
• /
• pp.138-141
• /
• 2005

Bi-2223/Ag tapes need to be safe, even it is under the over-critical current state for the protection of a superconducting power machine. However, it is not easy to identify the condition for the safe operation because of their broad S/N transition region. In this paper, for the study of the operation condition of Bi-2223/ Ag tapes, we investigated the V-I curves and the temperature variation of Bi-2223/ Ag tapes experimentally, applying alternating over-currents, and analyzed the relationship between resistance and temperature increase. For the experiments, a Bi-2223/Ag tape of 57 A $I_c$ was prepared, and the over-critical current characteristics under adiabatic state from $LN_2$ was measured. From the experiments, we confirmed that the Joule heating predicted by V-I curve corresponded with the increase of the measured temperature exactly. Using the results, a safe operation condition of Bi-2223 tape was discussed.

• 한국재료학회지
• /
• 제24권2호
• /
• pp.116-122
• /
• 2014

$Bi_2Sr_2CaCu_2O_x$(Bi-2212) and $Bi_2Sr_2Ca_2Cu_3O_y$(Bi-2223) high-Tc superconductors(HTS) have been manufactured by plasma spraying, partial melt process(PMP) and annealing treatment(AT). A Bi-2212/2223 HTS coating layer was synthesized through the peritectic reaction between a 0212 oxide coating layer and 2001 oxide coating layer by the PMP-AT process. The 2212 HTS layer consists of whiskers grown in the diffusion direction. The Bi-2223 phase and secondary phase in the Bi-2212 layer were observed. The secondary phase was distributed uniformly over the whole layer. As annealing time goes on, the Bi-2212 phase decreases with mis-orientation and irregular shape, but the Bi-2223 phase increases because a new Bi-2223 phase is formed inside the pre-existing Bi-2212 crystals, and because of the nucleation of a Bi-2223 phase at the edge of Bi-2212 crystals by diffusion of Ca and Cu-O bilayers. In this study the spray coated layer showed superconducting transitions with an onset Tc of about both 115 K, and 50 K. There were two steps. Step 1 at 115 K is due to the diamagnetism of the Bi-2223 phase and step 2 at 50 K is due to the diamagnetism of the Bi-2212 phase.

• 한국세라믹학회지
• /
• 제37권12호
• /
• pp.1212-1220
• /
• 2000

Bi-2223 초전도체계에서 석출물을 flux-pinning center로 이용할 수 있는지 가능성을 타진하기 위하여 $Bi_{1.8}$P $b_{0.4}$S $r_{2}$C $a_{2.2}$C $u_3$ $O_{8}$ 조성을 가진 Bi-2223/Ag 선재를 반응온도, 산소분압, 시간 등을 변화시키면서 열처리를 행하였다. 열처리 후 석출물들은 XRD, SEM, TEM, EDS로 분석하였다. Bi-2223 모상내의 (Ca, Sr)$_2$(Pb,Bi) $O_4$, B $i_{0.5}$ P $b_3$S $r_2$C $a_2$Cu $O_{12+}$$\delta$/ (3221)와 같은 2차상들의 크기와 분포는 2223 입자들의 연결성을 파괴하지 않고 열처리 조건에 의해서 조절할 수 있었다. 서냉 열처리가 된 시편은 임계전류밀도( $J_{c}$)값이 증가하였는데, 이는 2223 입자내 나노미터 크기로 형성된 석출물들이 flux-pinning sites로 작용한 것으로 추정된다.다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
• /
• pp.585-588
• /
• 2003

Bi-2223 superconducting wires were fabricated by stacking, drawing process with different precursor powders and different heat-treatment histories. The precursor powders were 2 kinds of Pb content. And a part of the tapes were experienced pre-annealing process which caused tetragonal structure of Bi-2212 phase to orthorhombic structure of it was during drawing process. We confirmed the transformation of Bi-2212 phase from tetragonal structure to orthorhombic structure and reduction of second phases. AC magnetization analysis were performed in order to investigate the fraction of Bi-2223 phase in Bi-2223/Ag HTS tape. The cross sections of 55 filaments and 61 filaments were investigated after rolled in order to understand deformation mechanism of superconducting cores. We could achieve best Ic of 70 A class at the Bi-2223/Ag tape using low Pb content of precursor powder and experienced pre-annealing process. AC magnetization analysis was useful to investigate the fraction of Bi-2223 phase in the Bi-2223/Ag tape.

• 한국초전도ㆍ저온공학회논문지
• /
• 제7권2호
• /
• pp.31-34
• /
• 2005

There are many kinds of high temperature superconducting (HTS) application using Bi-2223 tape which is the most commercialized HTS material. Also, resistive superconducting fault current limiters (SFCLs) have been developed using many kinds of superconducting material such as YBCO thin film, Bi-2212 bulk and so on. However, SFCL using Bi-2223 tape has never been developed. This paper deals with the feasibility study on SFCL using Bi-2223 wire. The over-current behaviors of Bi-2223 short-length sample were measured. To make the resistive SFCL, two small-scale bifilar winding modules using 7m Bi-2223 wire were fabricated; i.e. solenoid type bifilar coil and pancake type one. The short-circuit tests of the coils were successfully performed up to 16 V$_{rms}$ From these tests, the current limiting capabilities of Bi-2223 bifilar coils were confirmed and current limiting performances between two winding types were compared. In addition, the feasibility of resistive SFCL using another HTS wire, i.e. YBCO coated conductor, was also investigated.

• 한국초전도ㆍ저온공학회논문지
• /
• 제3권1호
• /
• pp.29-34
• /
• 2001

A Bi-2223 tape has been developed for low-field Power applications such as Power cables or transformers working at liquid nitrogen temperature For such applications it is required to understand fault current characteristics of the Bi-2223 tape. In this paper we report fault current characteristics using two types of samples, straight sample and pancake coil sample. It was found that the fault current characteristics of the Bi-2223 tape are independent of external fields and frequencies . However they depend on electrical insulations and fault durations strong1y Also it was shown that the fault current characteristics in the insulated straight sample are similar to those in the pancake sample with a conductor insulation. Finally. it was shown that the Pancake sample with a layer insulation has better characteristics than that with a conductor insulation fur fault currents.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2003년도 추계학술대회논문집
• /
• pp.273-276
• /
• 2003

High-temperature superconduction materials(Bi2223) possess electrical/electronic and magnetic properties. Because high-temperature superconduction materials is a ceramic powder, that can not be produced singlehandedly. So Ag sheathed Bi-2223 wire was produced by drawing process using powder-in-tube(PIT) method. This superconductor has many difficulties to produce. The main difficulty is that the mechanical properties of the ceramic powder are very different from those of the Ag sheath. Bi2223 high-temperature superconductivity have a single filament drawing process, and multi-filament drawing process. This study analysed multi-filament drawing process by FEM, a defects during multi-filament drawing was studied by FEM.