• Nuclear Engineering and Technology
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• v.53 no.3
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• pp.1041-1048
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• 2021

An engineered barrier system (EBS) for the disposal of high-level radioactive waste (HLW) is composed of a disposal canister with spent fuel, a buffer material, a gap-filling material, and a backfill material. As the buffer is located in the empty space between the disposal canisters and the surrounding rock mass, it prevents the inflow of groundwater and retards the spill of radionuclides from the disposal canister. Due to the fact that the buffer gradually becomes saturated over a long time period, it is especially important to investigate its thermal-hydro-mechanical-chemical (THMC) properties considering variations of saturated condition. Therefore, this paper suggests a new method of measuring thermal conductivity and water suction for single compacted bentonite at various levels of saturation. This paper also highlights a convenient method of saturating compacted bentonite. The proposed method was verified with a previous method by comparing thermal conductivity and water suction with respect to water content. The relative error between the thermal conductivity and water suction values obtained through the proposed method and the previous method was determined as within 5% for compacted bentonite with a given water content.

• Tunnel and Underground Space
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• v.32 no.1
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• pp.30-58
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• 2022

The deep geological repository for high-level radioactive waste disposal is a multi barrier system comprised of engineered barriers and a natural barrier. The long-term integrity of the deep geological repository is affected by the coupled interactions between the individual barrier components. Erosion and piping phenomena in the compacted bentonite buffer due to buffer-rock interactions results in the removal of bentonite particles via groundwater flow and can negatively impact the integrity and performance of the buffer. Rapid groundwater inflow at the early stages of disposal can lead to piping in the bentonite buffer due to the buildup of pore water pressure. The physiochemical processes between the bentonite buffer and groundwater lead to bentonite swelling and gelation, resulting in bentonite erosion from the buffer surface. Hence, the evaluation of erosion and piping occurrence and its effects on the integrity of the bentonite buffer is crucial in determining the long-term integrity of the deep geological repository. Previous studies on bentonite erosion and piping failed to consider the complex coupled thermo-hydro-mechanical-chemical behavior of bentonite-groundwater interactions and lacked a comprehensive model that can consider the complex phenomena observed from the experimental tests. In this technical note, previous studies on the mechanisms, lab-scale experiments and numerical modeling of bentonite buffer erosion and piping are introduced, and the future expected challenges in the investigation of bentonite buffer erosion and piping are summarized.

• Journal of the Korean Geotechnical Society
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• v.35 no.11
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• pp.7-14
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• 2019

The compacted bentonite buffer is one of the major components of an engineered barrier system (EBS) for the disposal of high-level radioactive waste (HLW), and it is considered the best candidate for the buffer material. The buffer is located between disposal canisters and near-field rock mass, and it interrupts the release of radionuclide from disposal canisters and protect them from the penetration of groundwater. At initial disposal condition, degree of saturation of the compacted bentonite buffer decreases because of high thermal quantities released from the disposal canisters. However, the degree of saturation of the compacted bentonite buffer gradually increases caused by inflow of groundwater. The saturated and unsaturated behavior of the buffer is a very important input data since it can determine the safety performance of EBS. Therefore, this paper investigated water retention capacity (WRC) for the Korean compacted bentonite buffer. The WRC of the compacted bentonite buffer was derived by measuring volumetric water content and water suction when temperature variation was between 24℃~125℃ considering decrease of degree of saturation with respect to temperature increase. The WRC was also derived with the same volumetric water content under the room temperature condition, and it showed 1~15% larger water suction than high temperature condition.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.15 no.3
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• pp.199-206
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• 2017

A geological repository for the disposal of high-level radioactive waste is generally constructed in host rock at depths of 500~1,000 meters below the ground surface. A geological repository system consists of a disposal canister with packed spent fuel, buffer material, backfill material, and intact rock. The buffer is indispensable to assure the disposal safety of high-level radioactive waste, and it can restrain the release of radionuclides and protect the canister from the inflow of groundwater. Since high temperature in a disposal canister is released to the surrounding buffer material, the thermal properties of the buffer material are very important in determining the entire disposal safety. Even though there have been many studies on thermal conductivity, there have been only few studies that have investigates the specific heat capacity of the bentonite buffer. Therefore, this paper presents a specific heat capacity prediction model for compacted Gyeongju bentonite buffer material, which is a Ca-bentonite produced in Korea. Specific heat capacity of the compacted bentonite buffer was measured using a dual probe method according to various degrees of saturation and dry density. A regression model to predict the specific heat capacity of the compacted bentonite buffer was suggested and fitted using 33 sets of data obtained by the dual probe method.

• Nuclear Engineering and Technology
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• v.34 no.1
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• pp.90-103
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• 2002

The thermal and mechanical properties of compacted bentonite and bentonite-sand mixture were collected from the literatures and compiled. The thermal conductivity of bentonite is found to increase almost linearly with increasing dry density and water content of the bentonite. The specific heat can also be expressed as a function of water ontent, and the coefficient of thermal expansion is almost independent on the dry density. The logarithm of unconfined compressive strength and Young’s modulus of elasticity increase linearly with increasing dry density, and in the case of constant dry density, it can be fitted to a second order polynomial of water content. Also the unconfined compressive strength and Young’s modulus of elasticity of the bentonite-sand mixture decreases with increasing sand content. The Poisson’s ratio remains constant at the dry density higher than 1.6 Mg/m$_3$, and the shear strength increases with increasing dry density.

• Nuclear Engineering and Technology
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• v.53 no.5
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• pp.1511-1518
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• 2021

In most countries, the thermal criteria for the engineered barrier system (EBS) is set to below 100 ℃ due to the possible illitization in the buffer, which will likely be detrimental to the performance and safety of the repository. On the other hand, if the thermal criteria for the EBS increases, the disposal density and the cost-effectiveness for the high-level radioactive wastes will dramatically increase. Thus, fundamentals on the thermal behavior of the buffer under the elevated temperatures is of crucial importance. Yet, the behaviors at the elevated temperatures of the bentonite under groundwater-saturated conditions have not been reported to-date. Here, we have developed an in-situ synchrotron-based method for the thermal behavior study of the buffer under the elevated temperatures (25-250 ℃), investigated dspacings of the montmorillonite in the Korean bentonite (i.e., Ca-type) at dry and KURT (KAERI Underground Research Tunnel) groundwater-saturated conditions (KJ-ii-dry and KJ-ii-wet), and compared the behaviors with that of MX-80 (i.e., Na-type, MX-80-wet). The hydration states analyzed show tri-, bi-, and mono-hydrated at 25, 120, and 250 ℃, respectively for KJ-ii-wet, whereas tri-, mono-, and de-hydrated at 25, 150, and 250 ℃, respectively for MX-80-wet. The Korean bentonite starts losing the interlayered water at lower temperatures; however, holds them better at higher temperatures as compared with MX-80.

• Journal of the Korean Geotechnical Society
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• v.38 no.12
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• pp.113-123
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• 2022

The required density relationship according to the press pressure of the floating die method and the homogeneity of the density distribution in the buffer block was evaluated to analyze the manufacturing characteristics of engineering scale bentonite-sand buffer blocks. In addition, the thermal conductivity was measured and compared with that of the pure bentonite buffer block to evaluate the level of thermal conductivity performance improvement of the bentonite-sand buffer material. As a result, it was confirmed that the standard deviation of dry density decreased to 0.011 and showed a homogeneous density distribution under the condition of press pressure greater than 400 kg/cm². Furthermore, as a result of the thermal conductivity test, the thermal conductivity of the buffer with optimum moisture content conditions was 1.345 and 1.261 W/(m·K) under the press pressure of 400 and 600 kg/cm², respectively. It increased by 16.1% and 11.0% compared to the pure bentonite buffer material. Based on the results of this study, it is judged that it can be used as fundamental data for manufacturing a homogeneous bentonite-sand buffer block on an engineering scale.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.2
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• pp.225-234
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• 2023

In the design of HLW repositories, it is important to confirm the performance and safety of buffer materials at high temperatures. Most existing models for predicting hydraulic conductivity of bentonite buffer materials have been derived using the results of tests conducted below 100℃. However, they cannot be applied to temperatures above 100℃. This study suggests a prediction model for the hydraulic conductivity of bentonite buffer materials, valid at temperatures between 100℃ and 125℃, based on different test results and values reported in literature. Among several factors, dry density and temperature were the most relevant to hydraulic conductivity and were used as important independent variables for the prediction model. The effect of temperature, which positively correlates with hydraulic conductivity, was greater than that of dry density, which negatively correlates with hydraulic conductivity. Finally, to enhance the prediction accuracy, a new parameter reflecting the effect of dry density and temperature was proposed and included in the final prediction model. Compared to the existing model, the predicted result of the final suggested model was closer to the measured values.

• Journal of the Korean Geotechnical Society
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• v.37 no.10
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• pp.5-11
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• 2021

The compacted bentonite buffer is one of the most important components in an engineered barrier system (EBS) to dispose of high-level radioactive waste (HLW) produced by nuclear power generation. The compacted bentonite buffer has a crucial role in protecting the disposal canister against the external impact and penetration of groundwater, so it has to satisfy the thermal-hydraulic-mechanical requirements. Even though there have been various researches on the investigation of thermal-hydraulic properties, few studies have been conducted to evaluate mechanical properties for the compacted bentonite buffer. For this reason, this paper conducted a series of unconfined compression tests and obtained mechanical properties such as unconfined compressive strength, elastic modulus, and void ratio of Korean compacted bentonite specimens with different water content and dry density values. The unconfined compressive strength and elastic modulus increased, and the Poisson's ratio decreased a little with increasing dry density. It showed that unconfined compressive strength and elastic modulus were proportional to dry density. However, there was not a remarkable correlation between mechanical properties and water content.

• Economic and Environmental Geology
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• v.55 no.3
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• pp.219-229
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• 2022

Bentonite is being considered as a candidate for buffer material in geological disposal systems for high-level radioactive wastes. In this study, the effect of cement-bentonite interactions on bentonite alteration was investigated by reviewing the literature on studies of cement-bentonite interactions. The major bentonite alteration by hyperalkaline fluids produced by the interaction of cementitious materials with groundwater includes cation exchange, montmorillonite dissolution, secondary mineral precipitation, and illitization. When the hyperalkaline leachate from the reaction of the cementitious material with the groundwater comes into contact with bentonite, montmorillonite, the main component of bentonite, is dissolved and a small amount of secondary minerals such as zeolite, calcium silicate hydrate, and calcite is produced. When montmorillonite is continuously dissolved, the physicochemical properties of bentonite may change, which may ultimately causes changes in bentonite performance as a buffer material such as adsorption capacity, swelling capacity, and hydraulic conductivity. In addition, the bentonite alteration is affected by various factors such as temperature, reaction period, pressure, composition of pore water, bentonite constituent minerals, chemical composition of montmorillonite, and types of interlayer cations. This study can be used as basic information for the long-term stability verification study of the buffer material in the geological disposal system for high-level radioactive wastes.