• Advances in environmental research
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• v.4 no.3
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• pp.197-210
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• 2015

Hexavalent chromium [Cr (VI)] adsorption on lateritic soil and lateritic soil blended with black cotton (BC) soil, marine clay and bentonite clay were studied in the laboratory using batch adsorption techniques. In the present investigation the natural laterite soil was blended with 10%, 20% and 30% BC soil, marine clay and bentonite clay separately. The interactions on test soils have been studied with respect to the linear, Freundlich and Langmuir isotherms. The linear isotherm parameter, Freundlich and Langmuir isotherm parameters were determined from the batch adsorption tests. The adsorption of Cr (VI) on natural laterite soil and blended laterite soil was determined using double beam spectrophotometer. The distribution coefficients obtained were 1.251, 1.359 and 2.622 L/kg for lateritic soil blended with 10%, 20% and 30% BC soil; 5.396, 12.973 and 48.641 L/kg for lateritic soil blended with marine clay and 5.093, 8.148 and 12.179 L/kg for lateritic soil blended with bentonite clay respectively. The experimental data fitted well to the Langmuir model as observed from the higher value of correlation coefficient. Soil pH and iron content in soil(s) has greater influence on Cr (VI) adsorption. From the study it is concluded that laterite soil can be blended with clayey soils for removing Cr (VI) by adsorption.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.03a
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• pp.1126-1131
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• 2006

This study is part of the project that develops the permeable preactive barrier to be applied in a landfill. The geotechnical applicability of the permeable preactive barrier that filters the leachate from the landfill was evaluated. Dry specimens were made using a mixture of sand, loess and bentonite. A series of experiments are performed to determine the unconfined compressive strength and permeability of various mixing ratio of bentonite, loess, and sand. The laboratory test indicate that the optimum-mixing ratio that satisfied the regulation of unconfined compressive strength(490kPa) and coefficient of permeability$(10^{-3}\sim10^{-4}cm/s)$ of the landfill was when the ratio of sand and loess was 8:2 with bentonite content of 2%. The permeable preactive barrier is different from an impermeable barrier in that it permits a limited diffusion of the leachate, which will be directly purified biologically and chemically in the landfill.

• Geomechanics and Engineering
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• v.34 no.4
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• pp.449-459
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• 2023

The design and development of underground nuclear waste repositories should cover the performance evaluation of the different components such as the construction materials because the long term stability will depend on their response to the surrounding conditions. In South Korea, Gyeonju bentonite has been proposed as a candidate to be used as buffer and backfilling material, especially in the form of blocks to speed up the construction process. In this study, various cylindrical samples were prepared with different dry density and water content, and their physical and mechanical properties were analyzed and correlated with X-ray CT observations. The main objective was to characterize the samples and establish correlations for non-destructive estimation of physical and mechanical properties through the utilization of X-ray CT images. The results showed that the Uniaxial Compression Strength and the P-wave velocity have an increasing relationship with the dry density. Also, a higher water content increased the values of the measure parameters, especially for the P-wave velocity. The X-ray CT analysis indicated a clear relation between the mean CT value and the dry density, Uniaxial Compression Strength, and P-wave velocity. The effect of the higher water content was also captured by the mean CT value. Also, the relationship between the mean CT value and the dry density was used to plot CT dry densities using CT images only. Moreover, the histograms also provided information about the samples heterogeneity through the histograms' full width at half maximum values. Finally, the particle size and heterogeneity were also analyzed using the Madogram function. This function identified small particles in uniform samples and large particles in some samples as a result of poor mixing during preparation. Also, the μ_max value correlated with the heterogeneity, and higher values represented samples with larger ranges of CT values or particle densities. These image-based tools have been shown to be useful on the non-destructive characterization of bentonite samples, and the establishment of correlations to obtain physical and mechanical parameters solely from CT images.

• Journal of the Korean Geotechnical Society
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• v.26 no.12
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• pp.19-30
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• 2010

Bentonite-based grout has been widely used to seal a borehole constructed for a closed-loop vertical ground heat exchanger in a geothermal heat pump system (GHP) because of its high swelling potential and low hydraulic conductivity. Three types of bentonites were compared one another in terms of viscosity and thermal conductivity in this paper. The viscosity and thermal conductivity of the grouts with bentonite contents of 5%, 10%, 15%, 20% and 25% by weight were examined to take into account a variable water content of bentonite grout depending on field conditions. To evaluate the effect of salinity (i.e., concentration of NaCl : 0.1M, 0.25M, and 0.5M) on swelling potential of the bentonite-based grouts, a series of volume reduction tests were performed. In addition, if the viscosity of bentonite-water mixture is relatively low, particle segregation can occur. To examine the segregation phenomenon, the degree of segregation has been evaluated for the bentonite grouts especially in case of relatively low viscosity. From the experimental results, it is found that (1) the viscosity of the bentonite mixture increased with time and/or with increasing the mixing ratio. However, the thermal conductivity of the bentonite mixture did not increase with time but increased with increasing the mixing ratio; (2) If bentonite grout has a relatively high swelling index, the volume reduction ratio in the saline condition will be low; (3) The additive, such as a silica sand, can settle down on the bottom of the borehole if the bentonite has a very low viscosity. Consequently, the thermal conductivity of the upper portion of the ground heat exchanger will be much smaller than that of the lower portion.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.395-398
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• 2003

Geosynthetic Clay Liners(GCLs) have been widely used as hydraulic barrier in landfills and remediation projects of contaminated sites. The aim of this research is to modify GCLs for effective removal of contaminants. We perform the free swell test, hydraulic conductivity test, and contaminants (TCE, hexavalent chromium, and nitrate) removal test on the bentonite-ZVI mixture with various ZVI content. As the ZVI content increased, contaminants removal efficiencies and swell volume increased, and hydraulic conductivity decreased.

• Journal of the Korean GEO-environmental Society
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• v.4 no.4
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• pp.25-34
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• 2003

This paper is focused on an experimental study in order to investigate the utilization of sewage sludge ash as the cover and liner materials for the waste disposal landfill or as construction materials. A series of tests were performed to evaluate the basic properties, compaction, compressive strength, consolidation, permeability, and CBR of sewage ash. Specially, clay bricks were made as increasing replacement ratio of sewage ash (such as 5, 10, 15, 20, 25, 30%). And tests were fulfilled for its quality. Bentonite and lime were used as the additives to improve permeability properties of sewage sludge ash. As a result of tests, it was shown that the permeability coefficient decreases as increasing bentonite content and the percentage of bentonite was roughly needed 20% to keep the permeability coefficient below $1{\times}10^{-7}cm/sec$. The results of unconfined compression tests show that sewage ash meets the criteria of the unconfined compression strength for cover material. It was shown that the compressive strength decreases as increasing the replacement ratio of sewage sludge ash and the maximum replacement ratio of sewage sludge ash to satisfy the quality standards of the third degree bricks was about 15%.

• Journal of the Korean Geosynthetics Society
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• v.11 no.1
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• pp.35-45
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• 2012

Dynamic characteristics of decomposed granite soil mixed with stone sludge and bentonite were investigated to figure out adequate applications of stone sludge, A total of 16 specimens with different stone sludge contents of 0%, 5%, 10%, 15% and bentonite with 0%, 5%, 10%, 15% were prepared. Resonant column tests were carried out on each specimen at different confining pressure. The results showed that the optimum mixing ratio which can satisfy the maximum shear modulus and the minimum damping ratio of the decomposed granite soils ranges from 5% to 10% respectively.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.5
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• pp.430-437
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• 2004

This paper is intended as an investigation of study on the thermal and electrical characteristics of the carbon heating element. In this experimentation, the electric material used is the crystalline graphite a kind of natural graphite. The bentonite is used to solidify the heating element and the vacuum furnace is used for sintering it. It is noted that the natural drying time should be at least 58 hours. The plating of the electric pole with the electroless nickel showed the lowest contact resistance among others. The resistance shows linear variation with regard to length. For the insulation and resolution, the glaze coating is best with 80% of water content. The temperature rising characteristic of the heating element is better than sheath heater saving 43% of rising time. The correlation equation for temperature was obtained with the electric power.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.7 no.1
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• pp.10-16
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• 2011

Performance of ground-source heat pumps (GSHPs) is mainly affected by ground heat exchangers which makes up more than 40% of construction cost. Exact construction and grout as backfill are important, because it is difficult to repair after being installed. As grout materials, bentonite grout material and cement material are used In this paper, thermal conductivity according to mix proportion of cement grout has been experimentally studied. Some variables were set to evaluate thermal conductivities according to change in cement content, unit water ratio, mass per volume of fresh mortar, and aggregate types. From the experimental analysis, high performance cement grout has been proposed.

• Journal of the Korean GEO-environmental Society
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• v.13 no.1
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• pp.31-36
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• 2012

Recently, industrial by-products are exponentially growing because energy consumption is increasing due to rapid industrial development and improved living standards. The purpose of this study is to determine the proper mixing ratio to meet the liner conditions(must be less than $1{\times}10^{-7}$cm/sec), using pond ash and bentonite as liner. As the result of the compaction test, depending on the increase mixing ratio of bentonite, the maximum dry unit weight was decreased but the optimum moisture content was tended to be increased at the compaction curve. As the result of the permeability test, depending on the increase mixing ratio of bentonite, the coefficient of permeability showed tendency to be decreased in the form of index and the tendency was caused by the hydration reactions filling the void of the pond ash. When the mixing ratio of bentonite was approximately over 15%, it was satisfied with the land fill liner conditions. In other words, it is necessary to consider other mixtures containing the cement or another material in the economical aspect for application of the pond ash.