• Title/Summary/Keyword: Behavior of fluoride

Search Result 106, Processing Time 0.023 seconds

Mechanical Properties and Ionic Conductivities of Plasticized Gel Polymer Electrolyte Based on P(VdF-co-HFP) (가소화된 P(VdF-co-HFP)계 고분자 전해질의 기계적 성질 및 이온전도도)

  • 최종국;김성훈
    • Polymer(Korea)
    • /
    • v.24 no.2
    • /
    • pp.259-267
    • /
    • 2000
  • Gel polymer electrolytes were prepared from poly(vinylidene fluoride-co-hexafluoro propylene)[P(VdF-co-HFP)] that had higher mechanical properties as well as higher dielectric constant ($\varepsilon$=8~13) than other polymeric matrix. Mechanical properties and ionic conductivities have been investigated as a function of blend ratio of electrolyte solution and polymer matrix. Ethylene carbonate (EC)/${\gamma}$-butyrolactone (${\gamma}$-BL) and lithium triflate (LiCF$_3$SO$_3$) were used as solvent and salt, respectively. The mechanical properties such as tensile strength, tensile modulus, compression modulus, and dynamic shear modulus were evaluated. The highest ionic conductivity was 1.09$\times$10$^{-3}$ S/cm for PVH40 containing 28.6 wt% of P(VdF-co-HFP) at $25^{\circ}C$. Tensile strength, tensile modulus and compression modulus were increased with P(VdF-co-HFP) content and abruptly changed between PVH70 and PVH80. Dynamic shear moduli showed a typical gel behavior and changed with shear strain.

  • PDF

A STUDY ON PIEZOELECTRIC PROPERTIES OF PVDF AND ITS COPOLYMERS

  • Ansari, Mohd.Zahid;Cho, Chong-Du
    • Proceedings of the KSME Conference
    • /
    • 2007.05a
    • /
    • pp.584-589
    • /
    • 2007
  • Polyvinylidene fluoride (PVDF) is a type of electroactive polymer which shows significant shape change when exposed to electric field. PVDF is generally used as a film sensor in non-destructive evaluation (NDE) of materials. In this study, however, its properties relevant to film actuator are considered. Since most of the electromechanical applications that use PVDF and its copolymers as actuators use their piezoelectric properties, only the piezoelectric properties of PVDF are discussed here. These properties depend mainly on the degree of crystallinity of PVDF. Available data from recent research publications are used to simulate the response of a PVDF bimorph beam on the application of electric field, by a commercial finite element analysis package ANSYS. Finally, the factors that affect mechanical behavior of PVDF bimorph beam are discussed.

  • PDF

ENHANCEMENT OF PHOTOVOLTAIC PERFORMANCE IN COPPER PHTHALOCYNINE THICK FILM SOLAR CELLS

  • Ruiono, Yo Tomota;Momose, Yoshihiro;Takeuchi, Manabu
    • Journal of the Korean institute of surface engineering
    • /
    • v.29 no.6
    • /
    • pp.673-677
    • /
    • 1996
  • Copper phthalocyanine(CuPc) thick film solar cells were fabgricated byspin coating and their photovoltaic behavior was studied. Polyvinylidene fluoride (PVdF) was used for the binder. Aluminum and indium were employed as electrode metals to form Schottky contact to CuPc layer. The cells showed rectifying J-V characteristics in the dark and photovoltaic effect associated with white light irradiation. The photovoltaic performance of the cells strongly depended on contact metals, in which the formation of oxide layer between binder layer and electrode interface affected the solar cell. Influnce of the CuPc layer thickness, CuPc/PVdF ratio on the photovoltaic performance of the cells were also examined.

  • PDF

Low Dimensional Electro-optic Properties of Ferroelectric Polymer Films (강유전 고분자 박막의 저차원 전기광학 특성)

  • Park, Chul-Woo;Jung, Chi-Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.27 no.3
    • /
    • pp.184-188
    • /
    • 2014
  • The electro-optic properties in Langmuir Blodgett films of poly (vinylidene fluoride trifluoroethylene) are investigated in the crossover region between two and three dimensions. The absence of finite size effect is observed in the films thinner than 20 nm, which confirms that these films are two dimensional ferroelectrics. The copolymer LB film of P(VDF-TrFE) exhibits the largest electro-optic response(26 pm/V) at 10 layer thickness. The cross-over behavior of electro-optic effect around the 10 layer thickness was discussed with the formation of nanomesa after thermal annealing.

Characteristics of ERF Polishing using Chemical-oil (케미컬오일을 이용한 ERF 연마 특성)

  • 윤종호;이재종;이응숙;이동주;김영호
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
    • /
    • 2004.04a
    • /
    • pp.27-33
    • /
    • 2004
  • Electro-theological fluid is recently used for the micro polishing of 3-dimensional micro-aspherical lens. It's also used for polishing small area defects on the wide flat wafer. Since ER fluid shows a behavior of viscosity changing under certain electric fields. micro polishing efficiency may be enhanced for certain cases. In this paper, a perfluorinated carbonyl fluoride oil based ER fluids was used to improve surface polishing rate and submicron-scale accuracy. As the polishing electrodes, micro size cylindrical tools had been used for maximizing the electric field. An experimental device, which was applied for micro polishing a number of wafers of 4inches in size and other workpiece. was made on a precision polishing system. It consisted of a steel electrode. a wafer fixture. l0㎃ current and DC 5㎸ power supply unit, and a controller unit. From the Experiments. the ER fluid is applicable for micro polishing of small parts.

  • PDF

Corrosion Protection Performance of PVDF/PMMA-Blended Coatings by Electrochemical Impedance Method

  • Kim, Yun Hwan;Kwon, Yong Sung;Shon, Min Young;Moon, Myung Jun
    • Journal of Electrochemical Science and Technology
    • /
    • v.9 no.1
    • /
    • pp.1-8
    • /
    • 2018
  • The effect of mixing ratio on the corrosion protection of carbon steel coated by a film composed of poly(vinylidene) fluoride (PVDF) and poly(methyl methacrylate) (PMMA) was examined using electrochemical impedance spectroscopy. Surface crystallization behavior and thermal properties of the PVDF/PMMA coated carbon steel were evaluated using polarized optical microscopy and differential scanning calorimetry, respectively. A Maltese cross-pattern spherulite crystal was observed in the PVDF/PMMA coating film, which became more apparent with increasing PVDF content. The highest corrosion protection performance was achieved with 60 wt.% PVDF-coated carbon steel, and delamination and corrosion reactions were observed for 20 wt.% PVDF-coated carbon steel. Further, corrosion protection performance with an amorphous/crystal mixture (PVDF/PMMA, 60/40 (w/w)) was better than those observed in the amorphous domain and the perfect-crystal domain of the PVDF/PMMA blended coating system.

Thermal Stability of Lithiated Silicon Anodes with Electrolyte

  • Park, Yoon-Soo;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.1
    • /
    • pp.145-148
    • /
    • 2011
  • The thermal behavior of lithiated Si anodes has been investigated using differential scanning calorimetry (DSC). In particular, the effect of Si particle size on the thermal stability of a fully lithiated Si electrode was investigated. For DSC measurements, a lithiated Si anode was heated in a hermetically sealed high-pressure pan with a polyvinylidene fluoride (PVDF) binder and a 1 M $LiPF_6$ solution in an ethylene carbonate (EC)-diethyl carbonate (DEC) mixture. The thermal evolution around $140^{\circ}C$ increases with lithiation and with decreasing particle size; this phenomenon is attributed to the thermal decomposition of the solid electrolyte interface (SEI) film. Exothermic peaks, following a broad peak at around $140^{\circ}C$, shift to a lower temperature with a decrease in particle size, indicating that the thermal stability of the lithiated Si electrode strongly depends on the Si particle size.

Development of Rollable Smartpad for Management of the Sitting Behavior (착좌 행동 관리를 위한 롤러블 스마트패드 개발)

  • Kang, Seongtak;Lee, Jaegeun;Park, Sooji;Shin, Hangsik
    • Proceedings of the Korea Information Processing Society Conference
    • /
    • 2017.04a
    • /
    • pp.1129-1130
    • /
    • 2017
  • 본 연구에서는 현대인들의 하루 중 많은 시간을 차지하는 착좌 생활을 관리하기 위한 롤러블(rollable) 스마트패드를 개발하였다. 이를 위해 PVDF(polyvinylidene fluoride) 필름을 이용한 압전센서(piezoelectric sensor)를 제작하였으며, 센서에서 데이터를 획득하고 및 햅틱 피드백(haptic feedback)을 주기 위한 측정시스템을 개발하였다. 또한, 스마트폰 어플리케이션을 통해 착좌 자세에 대한 정보를 실시간으로 제공하도록 하였다. 제작된 시스템의 착좌 자세 구분 정확도는 10명의 피험자를 대상으로 평가되었으며, 4가지 자세(상체를 좌, 우, 앞, 뒤로 기울인 앉은 자세)에 대한 실험결과 제작된 시스템은 92.5%의 정확도로 제시한 4가지의 자세를 구분하였다.

Oral health behavior according to oral health education experience in the elementary school teachers (일부 초등학교 담임교사의 구강보건교육경험유무에 따른 구강건강행태)

  • Lee, Jung-Hwa;Ryu, Hae-Gyum
    • Journal of Korean society of Dental Hygiene
    • /
    • v.15 no.2
    • /
    • pp.253-259
    • /
    • 2015
  • Objectives: The purpose of this study was to investigate the oral health behavior according to oral health education experience in the elementary school teachers and to provide the basic data for the development of oral health education program. Methods: A self-reported questionnaire was filled out by 239 elementary school teachers in Busan and Ulsan from May 7 to 31, 2013. The questionnaire consisted of general characteristics of the subjects, use of oral health devices, dental clinic visit within a year, purpose of dental clinic visit, subjective oral health condition, place and contents of oral health education, future contents of oral health education, purpose of tooth brushing, recognition of sealant, recognition of dental caries prevention effect of fluoride, and method and frequency of tooth brushing. Data were analyzed by Predictive Analysis Software(PASW) Statistics $19.0^{(R)}$(SPSS Inc., Chicago IL, USA). Results: Of the 239 teachers, 187 teachers had oral health education experience and 52 did not. Those who had oral health education experience reported higher scores in tooth brushing than those who did not. 59.4% of the respondents answered the experience of oral health education in dental clinics. Conclusions: Oral health behavior was different from the experience of oral health education in the elementary school teachers. The teachers are the most important persons influencing on the right tooth brushing habit in the students. So the teachers must take the continuing and systematic oral health education.

Dry etching of ZnO thin film using a $CF_4$ mixed by Ar

  • Kim, Do-Young;Kim, Hyung-Jun
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2009.10a
    • /
    • pp.1504-1507
    • /
    • 2009
  • In this paper, the etching behavior of ZnO in $CF_4$ plasma mixed Ar was investigated. Previously, the etch rate in $CF_4$/Ar plasma was reported that it is slower than that in Cl containing plasma. But, plasma included Cl atom can produce the by-product such as $ZnCl_2$. In order to solve this film contamination, no Cl containing etching gas is required. We controlled the etching parameter such as source power, substrate bias power, and $CF_4$/Ar gas ratio to acquire the fast etch rate using a ICP etcher. We accomplished the etching rate of 144.85 nm/min with the substrate bias power of 200W. As the energetic fluorine atoms were bonded with Zinc atoms, the fluoride zinc crystal ($ZnF_2$) was observed by X-ray photoelectron spectroscopy (XPS).

  • PDF