• Title/Summary/Keyword: Beer's Law

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ETIR and Raman Spectroscopic Studies of Crystallization and Polymorphism of Syndiotactic Polystyrene (FTIR과 라만 분광 실험을 이용한 신디오탁틱 폴리스티렌의 구조 및 결정화 연구)

  • ;;;;;Kohji Tashiro
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.603-608
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    • 2003
  • Syndiotactic polystyrene (s-PS) presents a very complex polymorphic behavior depending on the sample preparation history and exhibits a solid-solid phase transition. Each different polymorphic structures of the s-PS sample were prepared by annealing the samples from room temperature to 220 $^{\circ}C$. The structural changes induced by annealing were investigated using FTIR and FT-Raman spectroscopy. Although the crystallization kinetics of s-PS are difficult to investigate with DSC due to its fast crystallization rate, it was possible to determine crystallinity changes in the s-PS sample using infrared characteristic peaks with Beer-Lambert's law.

The Study on image correction of geometric distortion in digital radiography image (방사선투과영상의 기하학적 왜곡 보정에 관한 연구)

  • Park, S.K.;Ahn, Y.S.;Gil, D.S.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.25-30
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    • 2011
  • This study is made to provide with a method for correcting the geometric distortion of the digital radiography image by analytical approach based upon the inverse square law and Beer's law. This study is aimed to find out and improve a mathematic model of nonlinear type. Variations in the alignment of the X-ray source, the object, and imaging plate affect digital radiography images. A model which is expressed in parameter values; e.g, angle, position, absorption coefficient, length, width and pixel account of radiography source, is developed so as to match the sample image. For the best correction of the digital image that is the most similar to the model image, a correction technique based upon tangent is developed; then applied to the digital radiography images of steel tubes. As a result, the image correction is confirmed to be made successfully.

Feedback stabilization of linear systems with delay in control by receding horizon (지연요소를 갖는 시스템의 안정화 방법)

  • 권욱현
    • 전기의세계
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    • v.28 no.5
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    • pp.44-48
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    • 1979
  • For ordinary systems the receding horizon method has beer proved by the author as a very useful and easy tool to find stable feedback controls. In this paper an open-loop optimal control which minimizes the control energy with a suitable upper limit and terminal control and state constraints is derived and then transformed to the closed-loop control. The stable feedback control law is obtained from the closed-loop control. The stable feedback control law is obtained from the closed-loop control by the receding horizon concept. It is shown by the Lyapunov method that the control law derived from the receding, horizon concept is asymtotically stable under the complete controllability condition. The stable feedback control which is similar to but more general than the receding horizon control is presented in this paper To the author's knowledge the control laws in this paper are easiest to stabilize systems with delay in control.

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A Study on Structural-Thermal-Optical Performance through Laser Heat Source Profile Modeling Using Beer-Lambert's Law and Thermal Deformation Analysis of the Mirror for Laser Weapon System (Beer-Lambert 법칙을 적용한 레이저 열원 프로파일 모델링 및 레이저무기용 반사경의 열변형 해석을 통한 구조-열-광학 성능 연구)

  • Hong Dae Gi
    • Journal of Aerospace System Engineering
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    • v.17 no.4
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    • pp.18-27
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    • 2023
  • In this paper, the structural-thermal-optical performance analysis of the mirror was performed by setting the laser heat source as the boundary condition of the thermal analysis. For the laser heat source model, the Beer-Lambert model considering semi-transparent optical material based on Gaussian beam was selected as the boundary condition, and the mechanical part was not considered, to analyze the performance of only the mirror. As a result of the thermal analysis, thermal stress and thermal deformation data due to temperature change on the surface of the mirror were obtained. The displacement data of the surface due to thermal deformation was fitted to a Zernike polynomial to calculate the optical performance, through which the performance of the mirror when a high-energy laser was incident on the mirror could be predicted.

Spectrophotometric Determination of Co (Ⅱ) with 7-Nitroso-8-Hydroxyquinoline-5-Sulfon (7-Nitroso-8-Hydroxyquinoline-5-Sulfonate 에 依한 Co (Ⅱ) 의 吸光光度定量)

  • Lee, Dong-Hyung
    • Journal of the Korean Chemical Society
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    • v.9 no.2
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    • pp.101-105
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    • 1965
  • Spectrophotometric method for the determination of Co(Ⅱ) is developed based on the fact that Co(Ⅱ) forms a stable red complex with 7-nitroso-8-hydroxyquinoline-5-sulfonate at pH 4. 5. The absorbance is measured at 528$m{\mu}$, $25^{\circ}C$. Beer's law is followed in the concentration range of 0. 3 to 6. 0 p.p.m. of Co(Ⅱ) and molar extinction coefficient of the complex was $1.1{\times}10^4$. Of the diverse ions checked, Fe(Ⅱ), Fe(Ⅲ), Cu(Ⅱ), Mn(Ⅱ), Hg(Ⅰ), CN-, EDTA interfere. The composition of the complex is found to be 3:1 ligand to metal species by mole ratio and continuous variation methods.

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Determination of Microquantities of Nicotine (니코틴의 미량 정량법)

  • 김찬호;김신일
    • Journal of the Korean Society of Tobacco Science
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    • v.3 no.2
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    • pp.77-81
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    • 1981
  • A flew spectroscopic method was developed to determine microquantities of nicotine with cyanogen chloride and pyrazolon. Absorption maximum of tile derivative solution appeared at 520nm. The color formed in the proposed method was stable for at least 30 min. at pH 7.5, and followed the Lambert-Beer's law between tile limits of 1 and 5 micrograms of nicotine. The relative errors in burley and flue-cured tobacco leaves were $\pm5%$ in comparison with the Griffith method.

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Simulation of Rear Lamp using Spectral-Based Ray Tracing (분광분포기반의 광선추적을 이용한 리어램프의 시뮬레이션)

  • 이명영;이철희;이호근;하영호
    • Proceedings of the IEEK Conference
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    • 2002.06d
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    • pp.327-330
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    • 2002
  • This paper proposes the simulation algorithm of rear lamp of car using a ray tracing method that models transmission and refraction of light frequently used in computer graphics At first. To reproduce an image accurately. incident on a sight of viewer, we propose the backward ray tracing method based on spectral distribution representing physical characteristics of illuminant and object used in real. We implement the reproduction algorithm of rear lamp image applying the Bouguer-Beer's law to an optical absorptive phenomenon. As the result, more realistic image can be reproduced.

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Studies on the Micro-determination of Metals by Spetrophotometry (II) Micro-determination of pb by Dithizone Method (Spectrophotometer에 의한 금속의 최상정량법에 관한 연구 (제 2 보) Dithizone에 의한 Pb의 미량정량법)

  • 노일협
    • YAKHAK HOEJI
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    • v.5 no.1
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    • pp.24-26
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    • 1960
  • Micro-determination of Lead by Dithizone Method was studied as follows: 1) Max. absorption wave length of Dithizone-pb complex in CC $l_{4}$ soln. is 510m.mu., 2) at the range of 5.gamma.-120.gamma. pb content, Bourguer-Beer's law hold good, 3) co-existence of F $e^{++}$ Z $n^{++}$, and C $u^{++}$ interfere.rfere.

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Spectrophotometric Determination of Iron with 2-Hydroxybenzaldehyde-5-nitro-pyridylhydrazone after Separation with Amberlite XAD-7 Nonionic Resin (Amberlite XAD-7 비이온성 수지로 분리 후 2-Hydroxybenzaldehyde-5-nitro-pyridylhydrazone을 이용한 철의 분광학적 정량)

  • Park, Chan Il;Chung, Byung Doo;Jung, Duck Chae;Cha, Ki Won
    • Journal of the Korean Chemical Society
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    • v.43 no.5
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    • pp.522-526
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    • 1999
  • 2-Hydroxybenzaldehyde-5-nitro-pyridylhydrazone (2HB-5NPH) was synthesized and its application to the spectrophotometric determination of iron was studied. The reagent reacts with iron in the pH range 6.0-7.5 to form a yellow coIored 1:2 chelate which is very stable in methanol solution. Beer's law is obeyed in the concentration range 0.05∼2.0 ${\mu}gmL^{-1}$ iron and separation procedure using a short column filled with Amberlite XAD-7 nonionic chelating resin is proposed for the spectrophotometric determination of traces of iron. The influence of several ions as interference was discussed. The separation of Fe(III) ion from the mix-ture solution were carried out with the buffer solution (pH 5.0) and 0.25M HCl as eluents.

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Synthesis and Analytical Application of Piperidine Dithiocarbamate Complex of Copper(II) (피페리딘 디티오카바메이트의 구리(II)의 착물합성과 분석적 응용)

  • Kim, Chan-Woo;Kim, Chang-Su
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.1-6
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    • 1999
  • Copper(II) complex of piperidine dithiocarbamate (Pipdtc) was synthesized from the reaction of Cu(II) and piperidine dithiocarbamate. The possible structure of the complex was proposed on the basis of elemental analysis, molar conductivity, infrared spectroscopy, electronic absorption spectroscopy, and $^{13}C-NMR$ studies. The extraction of copper(II)-Pipdtc complex by carbon tetrachloride can be achieved in the pH range of 6.0~10. The solution of copper(II) with piperidine dithiocarbamate was bey Beer's law in the concentration up to ${\sim}8.0{\times}10^{-5}M$ at pH 9.0.

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