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Nitrogen Removal from Milking Center Wastewater via Simultaneous Nitrification and Denitrification Using a Biofilm Filtration Reactor

  • Won, Seung-Gun;Jeon, Dae-Yong;Kwag, Jung-Hoon;Kim, Jeong-Dae;Ra, Chang-Six
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.6
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    • pp.896-902
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    • 2015
  • Milking center wastewater (MCW) has a relatively low ratio of carbon to nitrogen (C/N ratio), which should be separately managed from livestock manure due to the negative impacts of manure nutrients and harmful effects on down-stream in the livestock manure process with respect to the microbial growth. Simultaneous nitrification and denitrification (SND) is linked to inhibition of the second nitrification and reduces around 40% of the carbonaceous energy available for denitrification. Thus, this study was conducted to find the optimal operational conditions for the treatment of MCW using an attached-growth biofilm reactor; i.e., nitrogen loading rate (NLR) of 0.14, 0.28, 0.43, and $0.58kg\;m^{-3}\;d^{-1}$ and aeration rate of 0.06, 0.12, and $0.24\;m^3\;h^{-1}$ were evaluated and the comparison of air-diffuser position between one-third and bottom of the reactor was conducted. Four sand packed-bed reactors with the effective volume of 2.5 L were prepared and initially an air-diffuser was placed at one third from the bottom of the reactor. After the adaptation period of 2 weeks, SND was observed at all four reactors and the optimal NLR of $0.45kg\;m^{-3}\;d^{-1}$ was found as a threshold value to obtain higher nitrogen removal efficiency. Dissolved oxygen (DO) as one of key operational conditions was measured during the experiment and the reactor with an aeration rate of $0.12\;m^3\;h^{-1}$ showed the best performance of $NH_4-N$ removal and the higher total nitrogen removal efficiency through SND with appropriate DO level of ${\sim}0.5\;mg\;DO\;L^{-1}$. The air-diffuser position at one third from the bottom of the reactor resulted in better nitrogen removal than at the bottom position. Consequently, nitrogen in MCW with a low C/N ratio of 2.15 was successfully removed without the addition of external carbon sources.

Patterns of recurrence after radiation therapy for high-risk neuroblastoma

  • Jo, Ji Hwan;Ahn, Seung Do;Koh, Minji;Kim, Jong Hoon;Lee, Sang-wook;Song, Si Yeol;Yoon, Sang Min;Kim, Young Seok;Kim, Su Ssan;Park, Jin-hong;Jung, Jinhong;Choi, Eun Kyung
    • Radiation Oncology Journal
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    • v.37 no.3
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    • pp.224-231
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    • 2019
  • Purpose: To investigate the patterns of recurrence in patients with neuroblastoma treated with radiation therapy to the primary tumor site. Materials and Methods: We retrospectively analyzed patients with high-risk neuroblastoma managed with definitive treatment with radiation therapy to the primary tumor site between January 2003 and June 2017. These patients underwent three-dimensional conformal radiation therapy or intensity-modulated radiation therapy. A total of 14-36 Gy was delivered to the planning target volume, which included the primary tumor bed and the selected metastatic site. The disease stage was determined according to the International Neuroblastoma Staging System (INSS). We evaluated the recurrence pattern (i.e., local or systemic), progression-free survival, and overall survival. Results: A total of 40 patients with high-risk neuroblastoma were included in this study. The median patient age was 4 years (range, 1 to 11 years). Thirty patients (75%) had INSS stage 4 neuroblastoma. At the median follow-up of 58 months, there were 6 cases of local recurrence and 10 cases of systemic recurrence. Among the 6 local failure cases, 4 relapsed adjacent to the radiation field. The other 2 relapsed in the radiation field (i.e., para-aortic and retroperitoneal areas). The main sites of distant metastasis were the bone, lymph nodes, and bone marrow. The 5-year progression-free survival was 70.9% and the 5-year overall survival was 74.3%. Conclusion: Radiation therapy directed at the primary tumor site provides good local control. It seems to be adequate for disease control in patients with high-risk neuroblastoma after chemotherapy and surgical resection.

Synthesis of Porous Cu-ZnO Composite Sphere and CO Oxidation Property (기공성 Cu-ZnO 복합 구형 산화물의 합성 및 CO 산화반응 특성)

  • Park, Jung-Nam;Hwang, Seong-Hee;Jin, Mingshi;Shon, Jeong-Kuk;Kwon, Sun-Sang;Boo, Jin-Hyo;Kim, Ji-Man
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.328-332
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    • 2010
  • In this study, porous ZnO sphere and Cu-ZnO composite were synthesized by coprecipitation method in diethylene glycol solvent. The physicochemical properties of as-prepared composite materials were characterized by SEM, XRD, $N_2$-sorption and $H_2$-TPR. A series of porous Cu-ZnO with different Cu contents (0, 6.6, 21.3, 36.4, 54.6, 77.8 wt%) was investigated for CO oxidation activity in a fixed bed reactor system. With increasing Cu content in Cu-ZnO the surface area and micropore volume of Cu-ZnO are decreased and Cu (36.4 wt%)-ZnO shows higher activity for CO oxidation compared to the others.

Chemical Effects on Head Loss across Containment Sump Strainer under Post-LOCA Environment (LOCA이후 환경에서 원자로건물집수조 여과기의 수두손실에 대한 화학적 영향)

  • Ku, Hee-Kwon;Jung, Bum-Young;Hong, Kwang;Jeong, Eun-Sun;Jung, Hyun-Jun;Park, Byung-Gi;Rhee, In-Hyoung;Park, Jong-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3260-3268
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    • 2009
  • A test apparatus has been fabricated to simulate chemical effect on head loss through a strainer in a pressurized water reactor (PWR) containment water pool after a loss of coolant accident (LOCA). Tests were conducted under condition of same ratio of strainer surface area to water volume between the test appratus and the containment sump. A series of tests have been performed to investigate the effects of spray, existence of calcium-silicate with tri-sodium phosphate (TSP), and composition of materials. The results showed that head loss across the chemical bed with even a small amount of calcium-silicate insulation instantaneously increased as soon as TSP was added to the test solution. Also, the head loss across the test screen is strongly affected by spray duration and is increased rapidly at the early stage, because of high dissolution and precipitation of aluminum and zinc. After passivation of aluminum and zinc by corrosion, the head loss increase is much slowed down and is mainly induced by materials such as calcium, silicon, and magnesium leached from NUKONTM and concrete. Furthermore, it is newly found that the spay buffer agent, tri-sodium phosphate, to form protective coating on the aluminum surface and reduce aluminum leaching is not effective for a large amount of aluminum and a long spray.

A Proposed Analytical Model for the Debris Flow with Erosion and Entrainment of Soil Layer (지반의 침식 및 연행작용을 고려한 토석류 해석 모델 제안)

  • Lee, Kwang-Woo;Park, Hyun-Do;Jeong, Sang-Seom
    • Journal of the Korean Geotechnical Society
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    • v.32 no.10
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    • pp.17-29
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    • 2016
  • A debris flow analysis model has been developed to simulate the erosion and entrainment of soil layer. Special attention is given to the model which represents strength softening behaviour of soil layer due to velocity of deformation. The 3D FE analysis by Coupled Eulerian-Lagrangian (CEL) model is conducted to simulate the debris flow. The model is validated using published data on laboratory experiment (Mangeny et al., 2010). It has been definitely shown that proposed model is in good agreement with the results of laboratory data. Futhermore, the FE analysis is conducted to ensure capability of simulating the real scale debris flow. The result of Ramian watershed, Korea shows that the debris flow has increased the volume and speed and it is in good agreement with field investigation. Based on this, it is confirmed that proposed model shows good agreement of the behavior of the actual and analytical debris flow.

Distribution of Pyroclastic Density Currents Determined by Numerical Model at Mt. Baekdu Volcano (백두산 화산에서 수치모형 분석에 의한 화쇄류의 영향 범위)

  • Yun, Sung-Hyo;Chang, Cheolwoo;Kim, Sunkyeong
    • The Journal of the Petrological Society of Korea
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    • v.23 no.4
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    • pp.351-366
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    • 2014
  • We assumed the situation where an eruption column had been formed by the explosive Plinian eruption from Mt. Baekdu and that the collapse of eruption column had caused pyroclastic density currents to occur. Based on this assumption, we simulated by using a Titan2D model. To find out about the range of the impacts of pyroclastic density currents by volcanic eruption scenarios, we studied the distance for the range of the impacts by VEIs. To compare the results by each volcanic eruption scenario, we set the location of the vent on the 8-direction flank of the outer rim and on the center of the caldera, the internal friction angle of the pyroclastic density currents as $35^{\circ}$, the bed friction angle as $16^{\circ}$. We set the pile height of column collapse and the vent diameter with various VEIs. We properly assumed the height of the column collapse, the diameter of the vent, the initial rates of the column collapse and the simulation period, based on the VEIs, gravity and the volume of the collapsed volcanic ash. According to the comparative analysis of the simulation results based on the increase of the eruption, the higher VEI by the increase of eruption products, the farther the pyroclastic density currents disperse. To the northwest from the vent on the northeast slope of the outer rim of the caldera, the impact range was 3.3 km, 4.6 km, 13.2 km, 24.0 km, 50.2 km, 83.4 km or more from VEI=2 to VEI=7, respectively. Once the database has been fully constructed, it can be used as a very important material in terms of disaster prevention and emergency management, which aim to minimize human and material damages in the vicinity of Mt. Baekdu when its eruption causes the pyroclastic density currents to occur.

A Study on the Risk Assessment of River Crossing Pipeline in Urban Area (도심지 하천매설배관의 위험성 평가에 관한 연구)

  • Park, Woo-Il;Yoo, Chul-Hee;Shin, Dong-Il;Kim, Tae-Ok;Lee, Hyo-Ryeol
    • Journal of the Korean Institute of Gas
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    • v.24 no.2
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    • pp.22-28
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    • 2020
  • In this study, quantitative risk assessment was carried out for city gas high-pressure pipelines crossing through urban rivers. The risk assessment was performed based on actual city gas properties, traffic volume and population and weather data in the worst case scenario conditions. The results confirmed that the social and individual risks were located in conditionally acceptable areas. This can be judged to be safer considering that the risk mitigation effect of protecting the pipes or installing them in the protective structure at the time of the construction of the river buried pipe is not reflected in the result of the risk assessment. Also, SAFETI v8.22 was used to analyze the effects of wind speed and pasquil stability on the accident damage and dispersion distances caused by radiation. As a result of the risk assessment, the safety of the pipelines has been secured to date, but suggests ways to improve safety by preventing unexpected accidents including river bed changes through periodic inspections and monitoring.

Adsorption characteristics of Amitrol, Nonylphenol, Bisphenol-A with GACs (흡착특성이 다른 내분비계 장애물질 3종, Amitrol, Nonylphenol, Bisphenol-A의 GACs에서의 흡착 특성)

  • Choi, Keun-Joo;Kim, Sang-Goo;Kwon, Ki-Won;Ji, Yong-dae;Kim, Seung-Hyun;Kim, Chang-Won
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.256-264
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    • 2004
  • Adsorption characteristics of three endocrine disruptors, amitrol, nonylphenol, and bisphenol-A, were evaluated depending on the type and service duration of activated carbon (AC). Bituminous coal-, wood-, and coconut-based coals were tested. Bituminous coal-based AC (BCAC) had the greatest sorption capacity for the three chemicals tested, followed by wood-based AC (WAC) for nonylphenol and coconut palm-based AC (CAC) for bisphenol-A. During the column test, amitrol removal efficiency increased over time, indicating that hydrophilic endocrine disruptors are biodegraded in the AC column. Removal efficiencies of hydrophobic compounds such as nonylphenol and bisphenol-A decreased over time since the main removal mechanism was adsorption. The order of the amitrol removal was: BCAC-5.9 yr, CAC-3.l yr > BCAC-2.2 yr > BCAC-virgin > CAC-virgin > WAC-virgin > WAC-3.l yr. In general, used AC had greater removals than virgin AC. The order of the bisphenol-A removal was: CAC-virgin > BCAC-2.2 yr > CAC-3.l yr > WAC-virgin > BCAC-5.9 yr > WAC-3.l yr. The order of the nonylphenol removal was: BCAC-virgin > WAC-virgin > CAC-3.1 yr, WAC-3.1yr> BCAC-2.2 yr > BCAC-5.9 yr > CAC-3.1 yr. Bituminous coal AC performed the best over time. Endocrine disruptors such as these three compounds appear to be removed effectively by activated carbon through biodegradation and adsorption. Wood and coal based among the virgin ACs and 3.1 years used wood base among the used ACs appeared the lowest carbon usage rate(CUR) for nonylphenol removal by prediction model. Virgin and used coconut base ACs except BCAC had the lowest CUR for removal Bisphenol-A. Biodegradation of nonylphenol and Bisphenol-A did not occurred during the 9,800 bed volume experiment period. BCAC had the highest biodegradation capacity of 46% for amitrol among virgin ACs and the used coal based ACs had 33-44% higher biodegradation capacity than virgin's for amitrol so biodegradation is the effective removal technology for hydrophilic material such as amitrol.

The Fundamental Properties of Foamed Concrete as the Eco-friendly Ground Repair System for Cast in Site Using the CSA (CSA를 사용한 친환경 지반보수용 현장 기포콘크리트의 기초 특성 검토)

  • Woo, Yang-Yi;Park, Keun-Bae;Ma, Young;Song, Hun-Young
    • Resources Recycling
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    • v.29 no.1
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    • pp.53-61
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    • 2020
  • This study aimed to develop a foam concrete material for a ground repair system that has low strength and low fluidity by using an eco-friendly binder, which substitutes industrial by-products for more than 90% of cement. Basic properties were evaluated after substituting a small amount of calcium sulfo aluminate (CSA) for the binder to improve the sinking depth rate and volume change, commonly found when it had a large amount of industrial by-products. The substitution rates of CSA for the eco-friendly binder used for the foam concrete were 2.5, 5, and 10%. Fresh properties, hardened properties, pore structure, and hydrates were analyzed. Experimental results showed that using only 2.5% of CSA could improve the deep sinking depth which occurred when using an eco-friendly binder. As a result, the weight difference between the upper, middle, and lower parts of cast specimens was improved even after being hardened. The addition of CSA also contributed to the formation of small, uniformly sized closed pores and improved initial strength. However, when the proportion of CSA increased, the long-term strength decreased. However, it satisfied the target strength when 5% or less of CSA was used. The results of this study revealed that it was possible to manufacture foam concrete with low strength and high fluidity for repairing ground satisfying target qualities by adding 2.5% of CSA to the eco-friendly binder containing a large amount of industrial by-products.

Analysis on the Water Circulation and Water Quality Improvement Effect of Low Impact Development Techniques by Test-Bed Monitoring (시범 단지 운영을 통한 LID 기법별 물순환 및 수질개선 효과 분석)

  • Ko, Hyugbae;Choi, Hanna;Lee, Yunkyu;Lee, Chaeyoung
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.5
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    • pp.27-36
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    • 2016
  • Low Impact Development (LID) techniques are eco-friendly storm water management process for water circulation restoration and non-point pollutant reduction. In this study, four LID techniques (Small constructed wetland, Infiltration trench box, Infiltration trench, Vegetated swale) were selected and installed as a real size at the real site. All facilities were evaluated as monitoring under the real environmental climate situation and an artificial rain with exceeding design rainfall. In various rainfall, runoff reduction efficiency and non-point pollutant removal efficiency are increased to the bigger Surface Area of LID (SA)/Catchment Area (CA) ratio and the bigger Storage Volume of LID (SV)/Catchment Area (CA) ratio. Runoff did not occur at all rainfall event (max. 17.2 mm) in infiltration trench and vegetated swale. But Small constructed wetland was more efficient at less than 10 mm, a efficiency of infiltration trench box was similar at different rainfall. Although different conditions (such as structural material of LID, rainfall flow rate, antecedent dry periods), LID techniques are good effects not only water circulation improvement but also water quality improvement.