• 제목/요약/키워드: BeO

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졸-겔 법에 의한 $\gamma-LiAlO_2$ 화이버의 제조 및 특성 (Preparation and Characteristics of $\gamma-LiAlO_2$ Fibers by the Sol-Gel Method)

  • 현상훈;홍성안;신현철
    • 한국세라믹학회지
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    • 제32권2호
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    • pp.197-208
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    • 1995
  • ${\gamma}$-LiAlO2 fibers for fiber reinforced molten carbonate fuel cell (MCFC) matrix have been produced from LiAlO2 complex polymeric sols using the sol-gel process. The stable and spinnable LiAlO2 sols could be synthesized by mixing LiNO3 alcohol solutions in aluminum complex polymeric sols prepared through the condensationpolymerization reaction of 1 more of aluminum tri-sec-butoxide with 0.55 mole of mixed chelates (mole ratio of acetylaceton/triethanolamine=0.25/0.3). It was found that the viscosity range for fiber-spinning should be higher than 30 poise. The defect-free flexible ${\gamma}$-LiAlO2 fibers with the average tensile strength of 350 MPa could be obtained when the spinned fibers were heat-treated to 120$0^{\circ}C$ on the specified heating schedule after dried at room temperature.

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Synthesis and Characterization of CNT/TiO2 Composites Thermally Derived from MWCNT and Titanium(IV) n-Butoxide

  • Oh, Won-Chun;Chen, Ming-Liang
    • Bulletin of the Korean Chemical Society
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    • 제29권1호
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    • pp.159-164
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    • 2008
  • Two kinds of CNT/TiO2 composite photocatalysts were synthesized with multi-walled carbon nanotubes (MWCNTs) and titanium(IV) n-butoxide (TNB) by a MCPBA oxidation method. Since MWCNTs had charge transfer and semiconducting, the CNT/TiO2 composite shows a good photo-degradation activity. The XRD patterns reveal that only anatase phase can be identified for MCT composite, but the HMCT composite synthesized with HCl treatment was observed the mixed phase of anatase and rutile. The EDX spectra were shown the presence as major elements of Ti with strong peaks. From the SEM results, the sample MCT and HMCT synthesized by the thermal decomposition with TNB show a homogenous sample with only individual MWCNTs covered with TiO2 without any jam-like aggregates between CNTs and TiO2. From the photocatalytic results, we could be suggested that the excellent activity of the CNT/TiO2 composites for organic dye and UV irradiation time could be attributed to combination effects between TiO2 and MWCNTs with plausible photodegradation mechanism.

Preparation of Porous $Al_2O_3$-AIN-Mullite and $Al_2O_3$-AIN-SiC

  • Kim, Byung-Hoon;Na, Yong-Han
    • The Korean Journal of Ceramics
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    • 제1권3호
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    • pp.147-151
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    • 1995
  • Porous composite of $Al_2O_3$ and AIN based mullite and SiC can be prepared by alumium reaction synthesis and atmosphere controllied sintering in order to improve the durability of a gas filter body. The porous $Al_2O_3$-AIN-mullite, which has a strength of 168 kg/$\textrm{cm}^2$ and porosity of 51.59%, could be obtained by stmospheric firing at $1600^{\circ}C$ and the porous $Al_2O_3$-AIN-SiC with a porosity of 33% and strength of 977 kg/$\textrm{cm}^2$, could also be prepared. The average pore size has been changed from 0.2$\mu\textrm{m}$ in a reduction atmosphere and to 2$\mu\textrm{m}$ in an air atmosphere, respectively.

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SiO IN THE SGR B2 REGION

  • Minh, Y.C.
    • 천문학회지
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    • 제40권3호
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    • pp.61-65
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    • 2007
  • The 2-1 and 5-4 transitions of SiO have been observed toward the Sgr B2 region, including the Principal Cloud(the GMC containing Sgr B2(M)) and its surroundings. The morphology and velocity structure of the SiO emission show a close resemblance with the HNCO Ring feature, identified by Minh & Irvine(2006), of about 10 pc in diameter, which may be expanding and colliding with the Principal Cloud. Three SiO clumps have been found around the Ring, with total column densities $N_{SiO}{\sim}1{\times}10^{14}cm^{-2}$ at the peak positions of these clumps. The fractional SiO abundance relative to $H_2$ has been estimated to be ${\sim}(0.5-1){\times}10^{-9}$, which is about two orders of magnitude larger than the quiet dense cloud values. Our SiO observational result supports the existence of an expanding ring, which may be triggering active star formations in the Principal Cloud.

고체 산화물 연료전지 공기극 물질인 $(Pr_{1-x}Sr_{x})CoO_{3}$ (x=0.5 및 0.7)의 표면분석 (Surface analysis of $(Pr_{1-x}Sr_{x})CoO_{3}$ (x=0.5 and 0.7) as a cathode material for Solid Oxide Fuel Cell)

  • 김정현;이창보;백승욱;박광진;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.196-199
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    • 2007
  • The chemical states of oxygen on the surfaces of $Pr_{1-x}Sr_{x}CoO_{3}$ (x=0.5 and 0.7) oxide systems were investigated by X-ray photoelectron spectroscopy. Merged oxygen peaks of $Pr_{1-x}Sr_{x}CoO_{3}$ (x=0.5 and 0.7) oxides could be divided as five sub-peaks. These five sub-peaks could be defined as lattice oxygen ($O_{L}$). chemisorbed oxygen peaks ($O_{C}$) and hydroxyl condition oxygen peak ($O_{H}$). In case of the $Pr_{0.5}Sr_{0.5}CoO_{3}$ and $Pr_{0.3}Sr_{0.7}CoO_{3}$, the binding energy (BE) of oxygen lattice were located at same BE. However, the BE of chemisorbed oxygen peaks including oxygen vacancy shows different BE. Especially, it was found that BE of chemisorbed oxygen peaks was increased when more Sr were substituted. Comparing atomic percentages of oxygens of $Pr_{0.5}Sr_{0.5}CoO_{3}$ and $Pr_{0.3}Sr_{0.7}CoO_{3}$, the ratio of $Pr_{0.3}Sr_{0.7}CoO_{3}$ was higher than that of $Pr_{0.5}Sr_{0.5}CoO_{3}$. It showed more chemically adsorbed site including oxygen vacancies were existed in $Pr_{0.3}Sr_{0.7}CoO_{3}$.

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A Study on the User Acceptance of O2O Services : Mediating Effect of Customer Attitude

  • CHUNG, Ji Bok;NAM, Sung Jip
    • 동아시아경상학회지
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    • 제8권3호
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    • pp.15-24
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    • 2020
  • Purpose - New technologies allow service providers to integrate all the customer information within and between contact channels so that they can offer individualized services. The availability of new mobile devices enables retailers to interact with customers through countless channels (Rigby, 2011). The objective of this research is to examine customers' attitudes toward O2O (on-line to off-line) services and their intention to use based on the Technology Acceptance Model (TAM). Research design, data, and methodology - Utilizing the TAM model, the mediating effect of the users' attitudes toward O2O services on the relationship among perceived ease of use, perceived usefulness, perceived risks and intention to use are to be investigated. Results - The result shows that the perceived ease of use, perceived usefulness, perceived risks have a significant effect on customers' attitudes toward O2O services. It is also revealed that the attitude toward O2O services has a mediating effect among perceived ease of use, perceived usefulness, perceived risks and intention to use. Conclusions - The boundary between on-line and off-line is eroding and various services based on the O2O platform are growing. The results of this study and managerial implications can be applied to O2O platform operators or enterprises planning to sharp on their competitiveness edge through offering variations of service channels.

ZnO Buffer Layer에 의한 ZnO 박막의 결정학적 특성에 관한 연구 (A Study of the Crystallographic Characteristic of ZnO Thin Film Grown on ZnO Buffer Layer)

  • 금민종;손인환;이정석;신성권;김경환
    • 한국진공학회지
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    • 제12권4호
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    • pp.214-217
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    • 2003
  • 본 연구에서는 박막 증착시 발생되는 $\gamma$-전자와 같은 고에너지 입자들의 막 충돌에 의한 손상이 적은 대향타겟식 스퍼터링 장치를 이용하여 $SiO_2$/Si 기판강에 ZnO 박막을 제작하였으며, 막의 결정성에 악 영향을 미치는 초기 성장층을 제어 할 수 있는 ZnO buffer-layer를 도입하여 박막의 결정학적 특성을 알아보았다. 제작된 박막의 결정성 및 c-축 우선배향성은 XRD를 사용하여 측정하였다. 측정 결과 ZnO buffer layer의 두께 10, 20 nm와 가스압력 1 mTorr일 때 ZnO 박막의 결정성이 가장 우수함을 알 수 있었다.

산화알루미늄 세라믹 보트 기판을 이용한 탄소마이크로 코일의 대량 합성 (Large scale synthesis of the geometrically controlled carbon coils using $Al_2O_3$ ceramic boat for the supporting substrate)

  • 김성훈
    • 한국응용과학기술학회지
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    • 제30권3호
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    • pp.423-430
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    • 2013
  • Carbon coils could be synthesized using $C_2H_2/H_2$ as source gases and $SF_6$ as an incorporated additive gas under thermal chemical vapor deposition (CVD) system. Prior to the carbon coils deposition reaction, two kinds of samples having different combination of Ni catalyst and substrate were employed, namely, a commercially-made $Al_2O_3$ ceramic boat with Ni powders and a commercially-made $Al_2O_3$ substrate with Ni layer. By using a commercially-made $Al_2O_3$ ceramic boat, the synthesis of carbon coils could be enhanced as much as 10 times higher than that of $Al_2O_3$ substrate. Furthermore, the dominant formation of the microsized carbon coils could be obtained by using $Al_2O_3$ ceramic boat. The surface roughness of the supporting substrate of $Al_2O_3$ ceramic boat was understood to be associated with the large scale synthesis of carbon coils as well as the dominant formation of the larger-sized, namely the microsized carbon coils.

(Ba,Sr,Mg)$TiO_3$를 이용한 입계층 캐패시터의 제작 및 유전특성에 관한 연구 (The preparation and characteristics of (Ba,Sr,Mg) $TiO_3$ ceramic for BL capacitor)

  • 오재유;오의균;강도원;김범진;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.251-254
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    • 1998
  • The ($0.8BaTiO_3-0.1SrTiO_3-0.1MgTiO_3$)+$0.006Nb_2O_5$ ceramics were fabricated by conventional ceramic process. The dielectric property of specimen was investigated that the specimen was sintering temperature at 1,300C for 3hours and then annealed at $1,100^{\circ}C$ for 3hours in a atmosphere (air) to be painted on the surface with CuO paste. The results of the temperature and frequency are varied, the dielectric constant and loss tangent are unsuitable for BL capacitor. The dielectric constants were varied to be negative temperature coefficient(2.000-3,000) in the temperature range between -10 and $140^{\circ}C$, the dissipation factors (tan $\delta$) were some high(0.1-0.3). It was not grain insulation, in cause of the some difficult to be annealed temperature with CuO paste and fired atmosphere. But, we have some different annealing temperature and fired atmosphere, it will be suitable BL(Boundary Layer)capacitor.

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산소 결함형 $TiO_2$ 분말의 가시광에 대한 광촉매 활성 (Photocatalytic Activity of $TiO_2$ Powder with an Oxygen Deficiency in the Visible-Light Region)

  • 양천회
    • 한국응용과학기술학회지
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    • 제24권1호
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    • pp.1-9
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    • 2007
  • It prepared the $TiO_2$ powder which has photo-catalytic activity in the visible-light by the wet process with titanium oxysulfate. The titanium $dioxide(TiO_2)$ by the wet process creates a new absorption band in the visible light region, and is expected to create photocatalytic activity in this region. Anatase $TiO_2$ powder which has photocatalytic activity in the visible light region, is treated using microwave and radio-frequency(RF) plasma. But, the $TiO_2$ powder for the visible light region, which also can be easily produced by wet process. The wet process $TiO_2$ absorbed visible light between 400nm and 600nm, and showed a high activity in this region, as measured by the oxidation removal of aceton from the gas phase. The AH-380 sample appears the yellow color to be strong, the catalytic activity in the visible ray was excellent in comparison with the plasma-treated $TiO_2$. The AH-380 $TiO_2$ powder, which can be easily produced on a large scale, is expected to have higher efficiency in utilizing solar energy than the plasma-treated $TiO_2$ powder.