• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.2
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• pp.789-793
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• 2021

A lithium secondary battery is the most promising candidate for future energy storage devices. On the other hand, the battery capacity decreases gradually due to the small amount of water and decomposition of the salts during the charging and discharging process, which deteriorates at high temperatures. Many researchers focused on increasing the cycling performance, but there have been few studies on the fundamental problem that removes water and HF molecules. In this study, silane molecules that are capable of absorbing water and HF molecules are introduced to the separator. Firstly, silica-coated amino-silane (APTES, 3-aminopropyltriethoxysilane) was synthesized, then the silica reacted with epoxy-silane, GPTMS ((3-glycidyloxypropyl)trimethoxysilane). A ceramic-coated separator was fabricated using the silane-coated silica, which is coated on porous polyethylene substrates. FT-IR spectroscopy and TEM analysis were performed to examine the chemical composition and the shape of the silane-coated silica. SEM was performed to confirm the ceramic layers. LMO half cells were fabricated to evaluate the cycling performance at 60 ℃. The cells equipped with a GPTMS-silica separator showed stable cycling performance, suggesting that it would be a solution for improving the cycling performance of the Li-ion batteries at high temperatures.

• Journal of the Institute of Electronics and Information Engineers
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• v.51 no.10
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• pp.197-203
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• 2014

The safety and arming device(SAD), one of the components of the fuzes, shall provide safety that is consistent with handling, storage, transportation, use, and disposal. In this paper, we describes the design of the SAD which includes the solenoid assembly and the solenoid driving circuit to improve the safety of the fuzes. The solenoid assembly consists of a coil assembly, a restoring spring, and a core. The solenoid assembly is added in the SAD as an additional safety device. In case of the normal circumstances, the core of the solenoid assembly restrains the $1^{st}$ and $2^{nd}$ safety devices of the SAD for those devices not to operate at all, so that the SAD can secure safety for storage, transportation, and use. In contrast, when the battery power is provided to the solenoid driving circuit just before the flight, the core confirms the power level and starts removing the restraint from the $1^{st}$ and $2^{nd}$ safety devices of the SAD, and then the SAD is able to change its mode from safety mode to armed mode. After firing, once the SAD's operations complete, the turned-on arming switch stops providing the power to the solenoid assembly automatically. It can reduce the power consumption at solenoid assembly. Therefore, the proposed solenoid driving circuit for the solenoid assembly not only unlocks the restrained solenoid assembly from the safety devices, but also saves the power consumption during the flight.

• Journal of KIISE:Computer Systems and Theory
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• v.34 no.3
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• pp.101-112
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• 2007

Hard disks have been the most prevalent secondary storage devices and these days their usage is becoming more important in mobile computing systems due to I/O intensive applications such as multimedia applications and games. However, significant power consumption in the disk drives still limits battery lifetimes of mobile systems critically. In this paper, we show that using several smaller disks (instead of one large disk) can be an energy-efficient secondary storage solution on typical mobile platforms without a significant performance delay. Also, we propose a novel energy-efficient technique, which clusters related data into groups and migrates the correlated groups to the same disk. We compare this method with the existing data concentration scheme, and also combine them. The experiments show that our technique saves the energy consumption up to 34% when a pair of 1.8' disks is used instead of a single 2.5' disk with a negligible increase in the average response time. The results also show that our method also saves up to 14.8% of disk energy consumption and improve the average I/O response time by up to 10 times over the existing scheme.

• Journal of Hydrogen and New Energy
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• v.12 no.1
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• pp.29-38
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• 2001

The alloys $ZrMn_2Ni_x$ (x=0.0, 0.3, 0.6, 0.9 and 1.2) as the alloys of Zr-Mn-Ni three component system were prepared and their hydrogen-storage properties and their electrochemical properties were investigated. The C14 Laves phase formed in all the alloys $ZrMn_2Ni_x$. Among these alloys $ZrMn_2Ni_{0.6}$ was activated relatively easily(after about 11 charge-discharge cycles), and had the largest discharge capacity(max. 45mAh/g). For all the alloys Zr was dissolved most easily into the 6M KOH solution. More Mn and Ni were dissolved from the $ZrMn_2Ni_{0.6}$ alloy than from the other alloys. Due to the active charge and discharge of the $ZrMn_2Ni_{0.6}$ alloys, related to the easier activation and the larger discharge capacity, Zr, Mn and Ni in this alloy were considered to be dissolved more easily into the 6M KOH solution, compared with the other alloys.

• Journal of the Korean Electrochemical Society
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• v.7 no.4
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• pp.183-188
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• 2004

In order to develop polymer electrolyte for lithium/sulfur batteries, highly microporous P(VdF-HFP) membranes were prepared by phase inversion method. Porous structure was controlled by extracting NMP with mixture of deionized water and methanol. Porous structure of the membranes was observed with SEM. Polymer electrolytes were prepared by soaking the porous membranes in 1M $LiCF_3SO_3-TEGDME/EC$. The ionic conductivity of polymer electrolyte was found to be at high as $2\times10^{-3}S/cm$ when the polymer membrane extracted by $80\%$ methanol was used. The microporous polymer electrolyte optimized in this work displayed high ionic conductivity, uniform pore size, low interfacial resistance and stable ionic conductivity with storage time. The ionic conductivity of polymer electrolytes was measured with various lithium salts, and the conductivity showed $3.3\times10^{-3}S/cm$ at room temperature when $LiPF_6$ was used as a lithium salt.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.162-168
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• 2013

$Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) nano-composite is a promising cathode material for xEV application due to its high theoretic capacity. However high voltage operating system of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) has worked as a hurdle in its application because of the inherent demerits, such as cycle life degradation and gas evolution. In order to enhance cell performance of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn)/graphite cell, we examined electrolyte mainly composed of FEC, fluroalkyl ether and $LiPF_6$ (F-based EL). F-based EL showed much better discharging retention ratio than 1.3 M $LiPF_6$ EC/EMC/DMC (3/4/3, v/v/v) (STD). Furthermore gas evolution, especially CO and $CO_2$ during $60^{\circ}C$ storage for 30 days was dramatically reduced owing to thermal stable SEI formation effect of F-based EL.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.4
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• pp.164-168
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• 2014

The sodium-sulfur batteries which operate at $350^{\circ}C$ have been mainly used in the field of energy storage system. This batteries consist of liquid sodium anode, sulfur cathode and ${\beta}^{{\prime}{\prime}}$-alumina solid electrolyte. The conditioning process for stabilization of the batteries is essential since the cells show considerable fluctuation of discharge voltage at the beginning of discharge/charge cycles. It is found that one of the reasons of the fluctuation is the gradual change of contact area between molten sodium and solid electrolyte.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.2
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• pp.199-208
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• 2012

This paper proposes a quasi Z-source DVR(Dynamic Voltage Restorer) system with a series connection of the output terminals, to compensate the voltage variations in the 6.6[kV]/60[Hz] power distribution system. The conventional DVR using one quasi Z-source AC-AC converter has the advantage which it can compensate the voltage variations without the need for the additional energy storage device such as a battery, but it is impossible to compensate for the 50[%] under voltage sags. To solve this problem, a DVR system using two quasi Z-source AC-AC converters with the series connection of the output terminals is proposed. By controlling the duty ratio D in the buck-boost mode, the proposed system can control the compensation voltage. For case verification of the proposed system, PSIM simulation is achieved. As a result, in case that the voltage sags-swells occur 10[%], 20[%], 60[%] in power distribution system, and, in case that the 50[%] under voltage sags-swells continuously occur, all case could compensate by the proposed system. Especially, the compensated voltage THD was examined under the condition of the 10[%]~50[%] voltage sags and the 20[${\Omega}$]~100[${\Omega}$] load changes. The compensated voltage THD was worse for the higher load resistances and more severe voltage sags. Finally, In case of the voltage swells compensation, the compensation factor has approached nearly 1 regardless of the load resistance changes, while the compensation factor of voltage sags was related to the load variations.

• IEIE Transactions on Smart Processing and Computing
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• v.5 no.1
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• pp.35-42
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• 2016

Developments in power electronics have enabled the widespread application of Pulse Width Modulation (PWM) inverters, notably for connecting renewable systems to the grid. This study demonstrates that a high-quality power can be achieved using a stand-alone inverter, whereby the comparison between the power quality of the stand-alone inverter with battery storage (off-grid) and the power quality of the utility network is presented. Multi-loop control techniques for a single phase stand-alone inverter are used. A capacitor current control is used to give active damping and enhance the transient and steady state inverter performance. A capacitor current control is cheaper than the inductor current control, where a small current sensing resistor is used. The output voltage control is used to improve the system performance and also control the output voltage. The inner control loop uses a proportional gain current controller and the outer loop is implemented using internal model control proportional-integral-derivative to ensure stability. The optimal controls are achieved by using the Sisotool tool in MATLAB/Simulink. The outcome of the control scheme of the numerical model of the stand-alone inverter has a smooth and good dynamic performance, but also a strong robustness to load variations. The numerical model of the stand-alone inverter and its power quality are presented, and the power quality is shown to meet the IEEE 519-2014. Furthermore, the power quality of the off-grid system is measured experimentally and compared with the grid power, showing power quality of off-grid system to be better than that of the utility network.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.7
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• pp.467-472
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• 2015

Thermal batteries are primary power sources for military applications requiring high reliability, robustness and long storage life. Conventional electrodes for thermal batteries are prepared by compacting powder mixtures into pellets. Separator is composed of halide mixture, such as LiCl-KCl eutectic salt, blended with MgO to immobilize the molten salt. In order to increase the power density and energy density, the resistance of electrolyte should be reduced because the resistance of electrolyte is predominant in thermal batteries. In this study, wetting behaviors and impregnation weight of molten salts as well as the micro structures of ceramic felt were investigated to be applicable to thin electrolyte. Discharge performances of single cell with the ceramic separator impregnated by molten salt were evaluated also. Zirconia felt with high porosity and large pore outperformed alumina felt in wetting characteristics and molten salt impregnation as well as discharge performances. Based on the results of this study, ceramic felt separator impregnated with molten salt have revealed as an alternative of conventional thick MgO based separator with no conspicuous sign of thermal runaway by short circuit.