• Journal of Industrial Technology
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• v.42 no.1
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• pp.19-27
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• 2022

This review will discuss the effort to understand the interfacial reactions at the anode and cathode sides of all-solid-state batteries. Antiperovskite solid electrolytes have received increasing attention due to their low melting points and anion tunability which allow controlling microstructure and crystallographic structures of this material system. Antiperovskite solid electrolytes pave the way for the understanding relationship between critical current density and mechanical properties of solid electrolytes. Microstructure engineering of cathode materials has been introduced to mitigate the volume change of cathode materials in solid-state batteries. The hollow microstructure coupled with a robust outer oxide layer effectively mitigates both volume change and stress level of cathode materials induced by lithium insertion and extraction, thus improving the structural stability of the cathode and outer oxide layer, which results in stable cycling performance of all-solid-state batteries.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2021.10a
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• pp.570-571
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• 2021

The research on waste power batteries in China in the past ten years reveals that the power battery recycling industry is enormous but marred with several challenges. A study of China's current power battery closed-loop supply chain revealed some issues in the power battery recycling industry, such as imperfect supply chain, small recycling scale, asymmetric information, and imperfect profit distribution mechanism. This paper uses the theory of corporate social responsibility and consumer choice to propose a closed-loop network of power batteries based on block chain technology and analyzes the existing closed-loop supply chain of power batteries. Consequently, this study provides a new idea for developing the power battery closed-loop supply chain by proposing the closed-loop network of power batteries based on blockchain technology

• Journal of the Korean Electrochemical Society
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• v.16 no.1
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• pp.9-18
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• 2013

Components of zinc-air battery and their problems are explained. Energy density of zinc air battery is superior to other commercial ones including Li-ion batteries. Cycle life of the zinc air batteries is poor because of irreversible redox reactions on both electrodes. In order to improve the performance of the zinc air battery, catalysts, passivation, and the new structure of electrodes should be developed to optimize several reactions in an electrode. Multidisciplinary efforts, such as mechanics, corrosion science, composite materials are necessary from the beginning of the research to obtain a meaningful product.

• Bulletin of the Korean Chemical Society
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• v.23 no.1
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• pp.75-80
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• 2002

Cycle life tests have been carried out to evaluate the influence of safety valve pressure on valve regulated lead/acid batteries under deep cycling applications. Batteries were cycled at 5 hour rates at 100% DOD, and safety valve pressure was set to 1.08 and 2.00 bar, respectively. The batteries lost 248.3 g and 235.3 g of water for each case after about 1,200 cycles, but the cyclic performances of the batteries were comparable. Most of the gas of the battery during discharging was hydrogen, and the oxygen concentration increased to 18% after 3 hours of charging. The micro structure of the positive active materials was completely changed and the corrosion layer of the positive grid was less than $50{\mu}m$, regardless of the pressure of the safety valve after cycle life tests. The cause of discharge capacity decrease was found to be water loss and the shedding of the positive active materials. The pressure of safety valve does not give little effect to the cyclic performances and the failure modes of the gelled electrolyte valve-regulated lead acid batteries.

• Proceedings of the KIPE Conference
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• 2016.07a
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• pp.345-346
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• 2016

The grid-connected energy storage systems, which could increase the reliability, efficiency, and cleanliness of the grid is presently restricted by the high cost of batteries. This problems could be solved by batteries retired from automotive services. These batteries can provide a low-cost system for energy storage and other applications such as residential applications and renewable energy integration. This paper gives an overview of technical requirements for the re-use of the electric vehicle batteries in energy storage systems.Firstly, the motivation of research is introduced. Secondly, the technologies needed for the re-use of the battery are introduced such asidentification of the battery characteristics, grading of the aged batteries, identification of the state-of-charge and state-of-health of the battery and suitable power electronic converter topologies. In addition the control strategy to maximize the battery lifespan and bypass the faulty batteries is presented and one-stop solution to implement the above mentioned technologies are also given.

• International Journal of Reliability and Applications
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• v.1 no.1
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• pp.89-104
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• 2000

Accelerated testing consists of a variety of test methods for shortening the life of products or hastening the degradation of their performance. This paper presents practical, modern statistical methods for evaluating the reliability of Nickel-Cadmium batteries at their design temperature of 2$0^{\circ}C$ by accelerated life test. Batteries have been life tested at three high temperature conditions, 50, 60, 7$0^{\circ}C$, respectively to yield failures quickly. The failures have been observed and judged by means of charge and discharge current integration. Analyses of life data from those conditions resulted in the Weibull distribution, which has been verified on the ground of the Kolmogorov-smirnov test and the pairwise t-test. Life data are modeled according to the Arrhenius life-temperature relationship. The mean life of tested batteries is assessed at about 590 cycles, and the activation energy of this chemical reaction is concluded to be 0.39eV as results. This study provides procedures for estimating the reliability of batteries in a short period, which has little been possible in domestic industries. The results can be applied in many fields such as proof testing, acceptance testing, and estimating assurance periods.

• IEMEK Journal of Embedded Systems and Applications
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• v.11 no.5
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• pp.305-312
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• 2016

Modern embedded systems are typically operated by the rechargeable batteries in our daily life. Since charge of batteries is considered as an time consuming task, there have been extensive efforts to manage the charge time from the perspective of materials, circuits, and systems. Estimation of battery charge time is one of the essential information to design the charge circuitry. A compact macro model for the constant-current and constant-voltage charge protocol was recently introduced, which gives us a quick estimation of charge time with similar shape to the famous Peukert's law for discharge time estimation. The CC-CV charging protocol is widely used for Lithium-based batteries and Lead-acid batteries. In this paper, we characterize the lead-acid battery by measurement to extract the model coefficients, which was not covered by the previous studies. By our proposed model, the key coefficient Kcc results in 1.18-1.31, which is little bit higher than that of Lithium batteries. The accuracy of our model is within the range of ${\pm}10%$ error, which is compatible with the other studies such as Peukert's law.

• Journal of Electrochemical Science and Technology
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• v.7 no.2
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• pp.97-114
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• 2016

Lithium batteries based on elemental sulfur as the cathode-active material capture great attraction due to the high theoretical capacity, easy availability, low cost and non-toxicity of sulfur. Although lithium/sulfur (Li/S) primary cells were known much earlier, the interest in developing Li/S secondary batteries that can deliver high energy and high power was actively pursued since early 1990’s. A lot of technical challenges including the low conductivity of sulfur, dissolution of sulfur-reduction products in the electrolyte leading to their migration away from the cathode, and deposition of solid reaction products on cathode matrix had to be tackled to realize a high and stable performance from rechargeable Li/S cells. This article presents briefly an overview of the studies pertaining to the different aspects of Li/S batteries including those that deal with the sulfur electrode, electrolytes, lithium anode and configuration of the batteries.

• Journal of the Korea Institute of Military Science and Technology
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• v.15 no.4
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• pp.527-534
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• 2012

Thermal batteries are primary batteries that use molten salts as an electrolyte and employ an internal pyrotechnic source to heat the battery stack to operating temperatures, typically between 450 and $550^{\circ}C$. The unit cell of thermal batteries consists of an anode, an electrolyte, a cathode, a heat pellet and a current collector. The heat source for such batteries is typically heat pellets based on $Fe/KClO_4$. The elevated temperature by combustion of heat pellet is supposed to cause a flatness non-uniformity, buckling, with a lateral extension diameter of current collector. This paper mainly focused on the combustion and buckling model of current collector to simulate the effect of heat source. Mechanical stresses in the current collector caused by thermal stress is a critical design consideration of thermal batteries because the internal short circuit could be occurred.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.124-128
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• 2018

Titanium doping is employed to enhance the structural strength of a high-Ni layered cathode material in lithium ion batteries during high temperature cycling. After Ti-doping, the external morphology remains similar, but the lattice parameters of the layered structure are slightly shifted toward larger values. With application of the prepared materials as cathodes in lithium-ion batteries, the initial capacities are similar but the cycling performance at $25^{\circ}C$ is enhanced by Ti-doping. During high temperature cycling at $60^{\circ}C$, furthermore, highly improved capacity retention is achieved with the Ti-doped material (95% of initial capacity at 50th cycles), while cycle fading is accelerated with the bare electrode. This enhancement is attributed to better retention of the compressive strength of the particles and retarded crack formation within the particles. In addition, impedance increase is reduced in the Ti-doped electrode, which is attributed to an improvement in the structural strength of the high-Ni cathode material with Ti-doping.