• Bulletin of the Korean Chemical Society
• /
• v.35 no.3
• /
• pp.828-832
• /
• 2014

The spectroscopic properties of quercetin (QCT) were studied in the AOT reverse micelle by fluorescence spectroscopy. Because the molecular structure of QCT is completely planar, excited state intramolecular proton transfer (ESIPT) occurs between the -OH at C(5) and carbonyl oxygen via intramolecular hydrogen bonding. This ESIPT happens at the $S_1$ state but not at the $S_2$ state. Because QCT is a good donor-acceptor-conjugated molecule at the excited state, this molecule can emit strong fluorescence but shows no $S_1{\rightarrow}S_o$ emission due to this ESIPT. Since the $S_2{\rightarrow}S_1$ internal conversion was very slow due to the small Franck-Condon factors, $S_2{\rightarrow}S_o$ fluorescence emission was observed. All of the experimental results indicated that the QCT resided at the bound water interface and that the position of solute did not change significantly in the micelle at various water concentrations.

• Journal of the Korean Magnetic Resonance Society
• /
• v.12 no.2
• /
• pp.96-102
• /
• 2008

Direct quantification of methanol in polymer electrolyte membrane (PEM) by solid-state nuclear magnetic resonance (NMR) spectroscopy was studied and the methanol concentrations in PEM produced by crossover and diffusion were compared. The error range of the quantification was not smaller than ${\pm}15%$ and the amount of the methanol crossed over in our direct methanol fuel cells (DMFCs) was less than the methanol diffused to PEM. The methanol concentration in the PEM of the DMFC operated at different current densities were equivalent.

• Journal of applied mathematics & informatics
• /
• v.4 no.1
• /
• pp.117-134
• /
• 1997

In this paper we introduce the notions of TL-subsystems strong TL-subsystems and discuss their basic properties.

• Proceedings of the Earthquake Engineering Society of Korea Conference
• /
• 2000.04a
• /
• pp.375-382
• /
• 2000

This paper briefly summarizes the basic concepts and main characteristics of seismic design of New Zealand Standards(NZS) with regard to reinforced concrete(RC) structures. NZS used the concept of the capacity design and the limit state design to satisfy the requirements of serviceability and safety. Plastic mechanisms and details with respect to the limit state of safety are briefly presented in this paper. The understanding of this advanced seismic design concept will enable us to implement the basic theory of capacity design and contribute to the development of Korean seismic code in new generation,

• Journal of the Korean Magnetic Resonance Society
• /
• v.7 no.2
• /
• pp.68-73
• /
• 2003

Proton magic angle spinning spectra and thermogravimetric analysis data of poly(vinyl butylal) with water in it indicate water contents in the poly(vinyl butylal) samples were reduced during magic angle spinning. Our observation implies that the centrifugal force on the samples due to magic angle spinning cannot be neglected, especially on inhomogeneous and soft samples like poly(vinyl butylal) we tested in this work.

• Journal of the Korean Mathematical Society
• /
• v.26 no.2
• /
• pp.223-229
• /
• 1989

• Proceedings of the Korean Magnetic Resonance Society Conference
• /
• 2002.08a
• /
• pp.20-20
• /
• 2002

• Analytical Science and Technology
• /
• v.8 no.4
• /
• pp.623-630
• /
• 1995

Silicone rubber-based sodium-selective membranes are developed for solid-state ion sensors. It was shown that the potetiometric performance of SR-based membranes are greatly dependent on the type of neutral carriers employed; among the three ionophores, N,N,N',N'-tetracyclohexyl-1,2-phenylenedioxydiacetamide (ETH 2120), bis[(12-crown-4)methyl]dodecylmethylmalonate (D12C4DMM) and monensin methyl ester (MME), examined, only ETH 2120 was compatible with the SR-based matrix. Addition of about 20 wt% plasticizer to the SR-based matrix provided the resulting membranes with potentiometric properties essentially equivalent to those of the corresponding PVC-based membranes. Owing to the strong adhesive strength of SR-based membranes, the CWEs coated \vith those membranes exhibited long lifetime with conventional electrode-like performance. Blending of PU into the SR matrix increased the lifetime of CWEs from two weeks to one month.

• Structural Engineering and Mechanics
• /
• v.61 no.5
• /
• pp.675-684
• /
• 2017

In this paper, a hybrid seismic response control (HSRC) system was developed to control bridge behavior caused by the seismic load. It was aimed at optimum vibration control, composed of a rubber bearing of passive type and MR-damper of semi-active type. Its mathematical modeling was driven and applied to a bridge model so as to prove its validity. The bridge model was built for the experiment, a two-span bridge of 8.3 meters in length with the HSRC system put up on it. Then, inflicting the EI Centro seismic load on it, shaking table tests were carried out to confirm the system's validity. The experiments were conducted under the basic structure state (without an MR-damper applied) first, and then under the state with an MR-damper applied. It was also done under the basic structure state with a reinforced rubber bearing applied, then the passive on/off state of the HSRC system, and finally the semi-active state where the control algorithm was applied to the system. From the experiments, it was observed that pounding rather increased when the MR-damper alone was applied, and also that the application of the HSRC system effectively prevented it from occurring. That is, the experiments showed that the system successfully mitigated structural behavior by 70% against the basic structure state, and, further, when control algorithm is applied for the operation of the MR-damper, relative displacement was found to be effectively mitigated by 80%. As a result, the HSRC system was proven to be effective in mitigating responses of the two-span bridge under seismic load.

• BMB Reports
• /
• v.47 no.4
• /
• pp.233-238
• /
• 2014

Polypyrimidine tract-binding protein 1 (PTBP1) and its brain-specific homologue, PTBP2, are associated with pre-mRNAs and influence pre-mRNA processing, as well as mRNA metabolism and transport. They play important roles in neural differentiation and glioma development. In our study, we detected the expression of the two proteins in glioma cells and predicted that they may be sumoylated using SUMOplot analyses. We confirmed that PTBP1 and PTBP2 can be modified by SUMO1 with co-immunoprecipitation experiments using 293ET cells transiently co-expressing SUMO1 and either PTBP1 or PTBP2. We also found that SUMO1 modification of PTBP2 was enhanced by Ubc9 (E2). The mutation of the sumoylation site (Lys137) of PTBP2 markedly inhibited its modification by SUMO1. Interestingly, in T98G glioma cells, the level of sumoylated PTBP2 was reduced compared to that of normal brain cells. Overall, this study shows that PTBP2 is posttranslationally modified by SUMO1.