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Polymeric Lead(II)-selective Electrode Based on N,N'-Bis-thiophen-2-ylmethylene-pyridine-2,6-diamine as an Ion Carrier

  • Kim, Hee-Cheol;Lee, Hyo-Kyoung;Choi, A-Young;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.538-542
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    • 2007
  • Polymeric electrodes for lead ion based on N,N'-bis-thiophen-2-ylmethylene-pyridine-2,6-diamine as an ion carrier were prepared. The membrane electrode (m-3) containing o-NPOE as a plasticizer and 50 mol% additive of ionophore gives an excellent Nernstian response (29.59 mV/decade) and the limit of detection of ?log a (M) = 5.74 to Pb2+ in Pb(NO3)2 solution at room temperature. The prepared electrode provided good sensitivity and outstanding selectivity and response for Pb2+ over a wide variety of other metal ions in pH 7.0 buffer solutions. The good sensitivity and selectivity towards lead ion are attributed to the strong complexation of lead ion to N,N'-bis-thiophen-2-ylmethylene-pyridine-2,6-diamine which has geometrically the proper cavity to coordinate to the ligand.

Lead(II)-selective Polymeric Electrode Using a Schiff Base Complex of N,N'-Bis-thiophene-2-ylmethylene-ethane-1,2-diamine as an Ion Carrier

  • Jeong, Tae-Jun;Jeong, Dae-Cheol;Lee, Hyo-Kyoung;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • v.26 no.8
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    • pp.1219-1224
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    • 2005
  • We prepared lead ion-selective PVC membranes that were based on N,N'-bis-thiophene-2-ylmethylene-ethane-1,2-diamine as a membrane carrier. The membrane electrode has a linear dynamic range between 1.0 ${\times}$ $10^{-5}$ and 1.0 ${\times}$ $10^{-1}$ M with a Nernstian slope of 29.79 mV per decade, and its detection limit was 2.04 ${\times}$ $10^{-6}$ M at room temperature. The potentiometric response is independent of the pH of the solution in the pH range of 5-7. The proposed electrode revealed good selectivity and response for $Pb^{2+}$ over a wide variety of other metal ions in pH 5.0 buffer solutions, and there was good reproducibility of the base line on the subsequent measurements. The membrane electrode has a relatively fast response time, satisfactory reproducibility and a relatively long life time.

Development of the Railroad Geotechnical Information Management System Using Web GIS (웹 GIS 기반 철도 지반정보 관리프로그램의 개발)

  • 황선근;이성혁;김현기;김정무
    • Journal of the Korean Society for Railway
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    • v.7 no.1
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    • pp.20-25
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    • 2004
  • Railroad geotechnical information management system was developed by using Web GIS and DB in this study. The standardization of railroad geotechnical information is progressed by classifying three groups as like basic informations, vibration informations along railway lines and design drawings. The basic informations consisted of basic and dynamic properties of soils, geophysical exploration and seismic survey/exploration. And the specification for 'human exposure to whole-body vibration' was adopted to construct the vibration informations along railway lines. The informations as like drawings and photographs were saved by changing to graphic files in the standardization of design drawings. In the case of standardization of geographical information, the topographical maps(NGIS, 1:5000) were primarily used as digital maps. Another digital maps(KRRI, 1:5000) and their geographical DB based on NGI code system were added on this maps. The standardized informations were used to construct their database. And railroad information management system was developed using Entity-Relation(ER) model which had a good feasibility for expansion and transition to other system in designing stage of database. This system consisted of layer selection, search and analysis of geotechnical informations and Zeus DB was adopted for GIS operating and user interface. This system could be a good tool for saving, searching and analyzing the geotechnical and geophysical informations. These DB systems would offered the basic informations to plans, design and construction of railroad lines etc. in practical use.

Fabrication of 40 Gb/s Front-End Optical Receivers Using Spot-Size Converter Integrated Waveguide Photodiodes

  • Kwon, Yong-Hwan;Choe, Joong-Seon;Kim, Je-Ha;Kim, Ki-Soo;Choi, Kwang-Seong;Choi, Byung-Seok;Yun, Ho-Gyeong
    • ETRI Journal
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    • v.27 no.5
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    • pp.484-490
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    • 2005
  • We fabricated 40 Gb/s front-end optical receivers using spot-size converter integrated waveguide photodiodes (SSC-WGPDs). The fabricated SSC-WGPD chips showed a high responsivity of approximately 0.8 A/W and a 3 dB bandwidth of approximately 40 GHz. A selective wet-etching method was first adopted to realize the required width and depth of a tapered waveguide. Two types of electrical pre-amplifier chips were used in our study. One has higher gain and the other has a broader bandwidth. The 3 dB bandwidths of the higher gain and broader bandwidth modules were about 32 and 42 GHz, respectively. Clear 40 Gb/s non-return-to-zero (NRZ) eye diagrams showed good system applicability of these modules.

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Basic Principles of the Validation for Good Laboratory Practice Institutes

  • Cho, Kyu-Hyuk;Kim, Jin-Sung;Jeon, Man-Soo;Lee, Kyu-Hong;Chung, Moon-Koo;Song, Chang-Woo
    • Toxicological Research
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    • v.25 no.1
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    • pp.1-8
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    • 2009
  • Validation specifies and coordinates all relevant activities to ensure compliance with good laboratory practices (GLP) according to suitable international standards. This includes validation activities of past, present and future for the best possible actions to ensure the integrity of non-clinical laboratory data. Recently, validation has become increasingly important, not only in good manufacturing practice (GMP) institutions but also in GLP facilities. In accordance with the guideline for GLP regulations, all equipments used to generate, measure, or assess data should undergo validation to ensure that this equipment is of appropriate design and capacity and that it will consistently function as intended. Therefore, the implantation of validation processes is considered to be an essential step in a global institution. This review describes the procedures and documentations required for validation of GLP. It introduces basic elements such as the validation master plan, risk assessment, gap analysis, design qualification, installation qualification, operational qualification, performance qualification, calibration, traceability, and revalidation.

Automatic Analysis of Volatile Basic Nitrogen of Pork with an On-line Flow Injection Analysis System (온-라인 FIA시스템에 의한 돈육의 휘발성염기질소의 자동분석 -연구노트-)

  • 이형춘
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.5
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    • pp.965-967
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    • 2000
  • An on-line FIA system in place of traditional Conway method was used for quicker and simpler analysis of volatile basic nitrogen of pork. The on-line system was developed by connecting an FIA apparatus with an ammonia electrode as a detector to a personal computer. The data from Conway method and from the on-line FIA system were in good agreement and the correlation coefficient was 0.981. One sample could be analyzed in about 4 min.

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The Kinematical Characteristics of the Basic Ballet Position (발레에서 팔 기본 동작의 운동학적 특성)

  • Kim, Eun-Hee
    • Korean Journal of Applied Biomechanics
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    • v.16 no.1
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    • pp.151-158
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    • 2006
  • The purpose of this study was to find out the kinematical characteristics of arm's basic position in ballet. In order to achieve the purpose of the study, 3D cinematographic analysis was conducted with a ballerina who might performed the perfect arm's basic position. According to the results of this study, it was appeared that the shoulder kept about 78%-82%, the elbow kept about 62%-96%, the wrist kept 52%-109%, and finger kept 48%-110% with the height. Also, movement was formed with $21^{\circ}-77^{\circ}$ of the upper arm angle, $106^{\circ}-164^{\circ}$ of the elbow, $125^{\circ}-140^{\circ}$ of the wrist, and $83^{\circ}-160^{\circ}$ of the shoulder. The left-right ratio of the total arm angle was 98% in the first, second, and third position, and 100% in the forth position. The angle of arm gradient was remained $-68^{\circ}$ in the first position, $-27^{\circ}$ in the second position, $73^{\circ}$ in the third position, and $-11^{\circ}$ in the forth position. Based on the results mentioned above, balance and symmetry of both arms was an important factor in those four positions. Although it is impossible to maintain the position like robot, it may be a good performance if a certain level of extent was remained With respect to this point of view, it may be a good position if the difference between right and left arm in each joint can be remained within 2%. Angle also was an important factor that if the difference in total angle can be remained within 2% it may be an excellent position, there was difference of right and left based on the joint though. Therefore, practice and instruction to make a perfect symmetry as much as possible were needed Also, it would be a good movement if position and angle of joint within 2% difference of right and left arm can be remained In turn, because ballet is movement with expression of the body, beauty of the body and balance of the movement have to be harmonized for beautiful performance. Therefore, it would be a meaningful future study considering the body condition and movement of ballerina to define the beauty.

Potentiometric Characteristics of Nitroso.R-Salt-Metal Complex Based Basic Drug Selective Electrodes (금속 니트로소 R염 착물을 이용한 염기성 의약품 선택성 전극의 특성)

  • 이미나;안문규
    • YAKHAK HOEJI
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    • v.47 no.6
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    • pp.356-360
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    • 2003
  • Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt (NRS) was used as an organic ligand to prepare basic drug-selective polymeric membrane electrode. The sensing membrane of the electrode consited of basic drug-meta1(II)-NRS as an ion-exchanger site in a poly(vinyl chloride) matrix plasticized with 2-nitrophenyl octyl ether (NPOE). The metal ions used were Fe$^{2+}$, Co$^{2+}$, Ni$^{2+}$ and Cu$^{2+}$. The electrodes exhibited fast and wide linear response in the basic drug concentration of 10$^{-5}$ ∼10$^{-3}$ mol/l with a response slope of 50∼60 mV/decade in a buffer solution of pH 4∼8. The electrodes exhibited good selectivity for many basic compounds.mpounds.

Adolescent Girls' Bodice Pattern Fit Using the 3-Dimensional Virtual Clothing System (3차원 가상 착의 시스템을 이용한 여자 청소년용 길 원형 맞음새 연구)

  • Kim, Dohkyung;Chun, Jongsuk
    • Human Ecology Research
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    • v.54 no.3
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    • pp.279-292
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    • 2016
  • This research predicted the fit of the basic bodice patterns worn on adolescent girls' 3-dimensional scanned bodies. Six 3-dimensional scanned bodies were selected from the sixth Size Korea data. Each of them had good body posture and represented one of the three garment sizes: 79-160, 82-160, and 85-160. Experimental basic bodice patterns were drafted by three basic bodice pattern making methods. The fit of the basic bodice pattern was analyzed by the CLO 3D virtual clothing system. The results showed that the experimental basic bodice patterns did not fit well at the neck, shoulder, and back for adolescent girls. The fit of the basic bodice patterns varied by pattern making method or size. The basic bodice pattern A with the waist darts ending above the breast line showed the best fit among the three different types of experimental pattern. Among the three sizes 79-160, 82-160, and 85-120, size 79-160 basic bodice pattern showed the worst fit for adolescent girls. The results show that the placement and size of the bodice darts affect the basic bodice pattern fit. The basic bodice pattern making method of size 79-160 for adolescent girls should be studied in a future study.

A Novel Mobile Antenna for Ku-Band Satellite Communications

  • Park, Ung-Hee;Noh, Haeng-Sook;Son, Seong-Ho;Lee, Kyong-Hee;Jeon, Soon-Ik
    • ETRI Journal
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    • v.27 no.3
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    • pp.243-249
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    • 2005
  • A mobile antenna for multimedia communications with Ku-band geostationary satellite KOREASAT-3 and JSAT-2A is presented. The forward link of the satellite communication is 11.7 to 12.75 GHz, and the return link is 14.0 to 14.5 GHz. The mobile antenna is designed to be a stair structure using 24 active phased array elements in order to provide a low profile, and to be at a non-periodic array distance using the genetic algorithm. Also, the designed antenna uses the double beam forming method for stable satellite tracking. The fabricated mobile antenna is examined using various experiments to confirm its capability for practical application. From the measured results, the fabricated mobile antenna system is confirmed to have a good performance.

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