• Title/Summary/Keyword: Basic Dye

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Preparation of Silica Core-Hybrid Pigment via Sol-Gel Process and It's Application for Inkjet Dispersion Ink (졸-겔법을 이용한 실리카 핵을 가지는 하이브리드 안료의 제조와 잉크젯 분산 잉크로서 응용)

  • Jeon, Young-Min;Kim, Jong-Gyu;Gong, Myoung-Seon
    • Korean Journal of Materials Research
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    • v.16 no.10
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    • pp.599-605
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    • 2006
  • N-(3-triethoxysilylpropyl)-1,4-diaminoanthrquinone-2,3-dicarboximide (TESP-DADI), an organic blue pigment, has been prepared and incorporated into silica solid matrix reacting triethyl orthosilicate (TEOS) via sol-gel method. Morphology and microstructure of resulting hybrid pigment were studied employing SEM and TEM. The micrographs and particle size distributions showed that uniform pigment can be obtained employing TEOS-based sol-gel method forming silica core. Particle size distribution of dispersed pigment in water was examined using the technique of dynamic light scattering. The ensuing pigment dispersion ink was subjected to various physicochemical evaluation such as viscosity, surface tension, inkjet stability, storage stability, and color change as inkjet ink using spectrophotometric, and microscopic techniques.

Photocurrent and Its Stability Enhancement of Dye-sensitized Nanoparticle $TiO_2$ Solar Cells (염료감응 나노입자 $TiO_2$ 태양전지의 광전류와 그 안정성 향상)

  • Chae Won-Weok;Kang Tae-Sik;Kim Kang-Jin
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.232-236
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    • 1999
  • A solar cell based on dye-sensitized photoelectric conversion was studied by electrochemical and spec-trofluorometric methods for the purposes of enhancing its efficiency and stability of $TiO_2$ solar cells. Nanocrystalline $TiO_2$ was used to prepare photoelectrodes, and photosensitizing dyes such as malachite green oxalate, basic blue3, rhodamine B, and bromocresol purple were chosen as sensitizers. Electrochemical oxidation potentials and absorption and emission wavelengths of dyes were used to determine energy levels of the dyes. By comparing excited energy levels of the dyes with the conduction band edge potential $(E_{c,s})\;of\;TiO_2$ calculated by using the flat-band potential $(E_{fb})\;of\;TiO_2$, properties of a dye required to fabricate a high efficient photosensitizing solar cell with high short-circuit current $(J_{sc})$ were suggested. Enhanced stability of photocurrent was obtained by coating a $TiO_2|ITO$ electrode with Polypyrrole that Possibly Prevented the recombination between the conduction band electrons and oxidized dyes and suppressed the direct electrode redox reactions of dyes on ITO.

Adsorption Characteristics of Coconut Shell-based Granular Activated Carbon on a Basic Dye Basic Blue 3 (염기성 염료 Basic Blue 3에 대한 야자계 입상활성탄의 흡착 특성)

  • Park, Ha Neul;Choi, Han Ah;Won, Sung Wook
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.96-102
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    • 2018
  • In this study, adsorption characteristics of coconut shell-based granular activated carbon (CS-GAC) on Basic Blue 3 (BB3) were evaluated. As the dosage of CS-GAC increased, the removal efficiency of BB3 tended to increase and the initial dye concentration of 50 mg/L was completely removed at 0.2 g dosage. Adsorption equilibrium achieved within 270 and 420 min at the initial concentrations of 25 and 50 mg/L, respectively, and the experimental data were represented by the pseudo-second-order model. The maximum uptakes ($q_{max}$) predicted by the Langmuir model were 34.45, 46.63 and 53.10 mg/g at 298, 308 and 318 K, respectively. The $q_{max}$ value increased as the temperature increased. Also, the Gibbs free energy (${\Delta}G$) was changed to -7.37, -8.19 and -10.40 kJ/mol with increasing temperature. The enthalpy change (${\Delta}H$) and the entropy change (${\Delta}S$) were 34.47 kJ/mol and 0.15 J/mol K, respectively. Therefore adsorption of BB3 by CS-GAC was spontaneous and endothermic.

Azo-Dyes Photo-Aligning; Physics and Applications

  • Chigrinov, V.G.;Kwok, H.S.;Takada, Hirokazu;Takatsu, Haruyoshi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.759-763
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    • 2005
  • This review presents the status of our research in liquid crystal display (LCD) photo-aligning. We present the basic mechanisms of the photo-induced order in various photo-aligning materials and in azo-dye layers in particular and show that photo-aligning methods can provide a controllable pretilt angle and anchoring energy of the liquid crystal cell, as well as its high thermo and UV stability. The photo-aligning of various types of liquid crystal displays is also discussed.

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Modification of Dyeing Property of Polyester Fabrics by UV Irradiation (UV조사에 의한 Polyester직물의 염색성 개질)

  • 배중석;김인회
    • Textile Coloration and Finishing
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    • v.13 no.4
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    • pp.256-263
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    • 2001
  • Polyester fabrics were irradiated by UV produced by the low pressure mercury lamp. UV irradiation broke a C-H bond of PET fiber and caused the carbonyl groups on the fiber surfaces. Surface modification of PET fibers were accelerated by pretreatment with methanol, ethanol and acetone. The irradiated PET was dyed with basic dyes having cationic groups. The dye uptakes were proportional to irradiation times, and in inversely proportional to irradiation distances. The tensile strengths of PET fabrics decreased by UV irradiation. Washing fastness of PET dyeings were good, about 4-5 grade,andlightfastnesswerepoor, about l grade.

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Colour Removal from Aqueous Solutions by Flotation Process (부상공정에 의한 수용액으로부터 색 제거)

  • Roh, Sung-Hee;Yun, Young-Jae;Kim, Jin-Hwan;Kim, Sun-Il
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.576-580
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    • 1999
  • The removal of colours from aqueous solution and/or dispersions has been studied by dispersed-air flotation, in a semi-batch column. Two colours were used for the experiments: Basic Yellow 28(basic) and Direct Orange 31(basic). All two effectively removed by flotation within 8 min. Sodium dodecyl sulfate, sodium oleate and amines were found to be effective as collectors in the removal of colour, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

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For white Hair Cover for Chemical Hair Dye Treated Hair Cosmetic Analysis (백모(白毛) 커버(cover)용 화학염모제 처리 모발의 미용학적 분석)

  • Oh, Jung-Sun;Park, Jang-Soon
    • Journal of the Korea Convergence Society
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    • v.10 no.6
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    • pp.281-286
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    • 2019
  • Appearance is a means of competitiveness for modern people, and one of the factors that harms the desires of modern people is white hair. For the modern man who needs to express beautiful appearance to others by covering white moth, we performed hair analysis after white moth hair dye treatment. The maximum modulus and tangential modulus according to the maximum load, maximum tensile strength, maximum elongation, breaking load, fracture strength, elongation at break, and evaluation interval between 1N-3N experimental group and control group of 1N-Respectively. Maximum load, maximum tensile strength, breaking load and breaking strength tended to be larger than those of the control group, while the maximum elongation and breaking elongation were the highest in the control group and the elongation decreased with the experimental group treatment. The maximum modulus and tangential modulus of the 1N-3N test group were higher than those of the control group at 0~0.15 and 0.15~2.5, respectively. Based on the study on the cosmetic changes of the hair before and after the treatment, it can be used as a basic data to select the correct oxidative hair dye product, the proper amount of application and the time to leave.

Fabrication of computer-interfaced photon counter for single molecule detection in solution (용액내 단일 분자 검출을 위한 컴퓨터 인터페이싱 광자계수기의 제작)

  • 고동섭
    • Korean Journal of Optics and Photonics
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    • v.8 no.1
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    • pp.42-46
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    • 1997
  • In order to acquire the fluorescence burst signals emitted from single dye molecules that pass through a detection space defined by a confocal microscope, a computer-interfaced photon counter has been fabricated. The maximum count rate is about 80 MHz, which is limited by the counter devices used. Using both the operating computer program written by BASIC and the 486 PC computer, the minimum bin-width of 25 $mutextrm{s}$ has been achieved. The characteristics of fluorescence burst signals emitted from JA22 molecules at about 1$\times$$10^{-11}$m mol/L in ethylene glycol are discussed briefly.

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On the Micellization of ${\alpha}$-Amino Capric Acid (${\alpha}$-아미노카프르산의 Micelle 형성을 위한 한계농도에 관하여)

  • Ryu, Ji-Yong;Chang, Sei-Hun
    • Journal of the Korean Chemical Society
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    • v.10 no.4
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    • pp.161-165
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    • 1966
  • The critical concentrations of ${\alpha}$-amino capric acid for micelle formation have been determined by the surface tension measurements in both acidic and alkaline solutions, and also by the dye titration using Rhodamine B in alkaline solutions. The critical micelle concentrations obtained by the two methods show the good agreements within experimental errors. Since ${\alpha}$-amino acid is an ampholyte, it may aggregate to form the micelles in both more acidic and basic media than its isoelectric point. It is found that the basic media are rather preferable for the micelle formation than the acidic media. The effect of gegen ions upon the critical concentration for micelle formation in alkaline media is similar to that expected from the salt effect on the CMC (Critical Micelle Concentration).

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Natural Dyeing of Silk Fabrics with the Extract of Alnus firma Tree Branches (사방오리나무가지 추출액을 이용한 견직물의 천연염색)

  • Ha, Young Kab;Lee, Jeong Sook
    • Fashion & Textile Research Journal
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    • v.19 no.3
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    • pp.337-343
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    • 2017
  • The purpose of this study is to investigate the optimal dyeing conditions and human-friendly properties of the extract from the branches of Alnus firma tree which is widely used for forestation and to provide basic information for quantification and commercialization of natural dyeing by discovering such as dye material. The optimal dyeing conditions, as a result, were shown at 100% of dye concentration, $90^{\circ}C$ of dyeing temperature and 40 minutes of dyeing time. In terms of dye uptake depending on the mordanting methods, it showed the best result in order of Fe, Sn, Cu and Al at pre-mordanting while found strong in order of Fe, Cu, Al and Sn at post-mordanting. Color fastness to washing and dry cleaning was found strong at grade 4-5 and fastness to light was rated at 2. The grade of change in color to rubbing and perspiration was good at 4-5. In aspects of functional properties, it showed excellent results of 98% deodorization rate at 120 minutes of dyeing time, 96.1% UV protection rate and 99.9% bacterial reduction against Staphylococcus aureus and Klebsiella pneuminiae. It is considered, therefore, the extract from Alnus firma tree is of great value as an eco-friendly natural dyestuff.