• Title/Summary/Keyword: Base/acid ratio

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Preparation and Characterization of Primer and Synthesized Chlorinated Polyolefine (CPO)-g-Carboxy Ethyl Acid (β-CEA) (Chlorinated Polyolefine (CPO)-g-β Carboxy Ethyl Acid (β-CEA) 수지의 합성 및 이를 Base Polymer로 하는 프라이머의 제조 및 물성)

  • Jeong, Booyoung;Cheon, Jungmi;Oh, Sangtaek;Kim, Taekyun;Chun, Jaehwan
    • Journal of Adhesion and Interface
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    • v.12 no.2
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    • pp.62-66
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    • 2011
  • In this study, we synthesized a excellent adhesive chlorinated polyolefin (CPO)-g-$\beta$-carboxy ethyl acid ($\beta$-CEA) by radical polymerization. Also, we prepared low-level toxic primer for polypropylene (PP) using CPO-g-$\beta$-CEA and studied toxic and adhesion property. We identified the graft structure and properties of the prepared chlorinated polyolefin-g-$\beta$ CEA using FT-IR, DSC, UTM. Graft ratio were optimum value at 5 wt% $\beta$-CEA contents in CPO-g-$\beta$ CEA. And the primer for PP was prepared with CPO-g-$\beta$ CEA and adhesive builder PX-95 content. Finally, optimum peel strength obtained when PX-95 contents was 3 wt%.

Effects of Simulated Acid Rain on Growth and Contents of Chemical Substances in Needles of Pinus koraiensis Seedlings and on Chemical Properties of the Tested Soil (인공산성우(人工酸性雨)가 잣나무 유묘(幼苗)의 생장(生長), 엽내함유성분(葉內含有成分) 및 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響))

  • Cheong, Yong Moon
    • Journal of Korean Society of Forest Science
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    • v.76 no.1
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    • pp.33-40
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    • 1987
  • Simulated acid rain (pH 4.0, pH 2.0) containing sulfuric and nitric acid in the ratio of 60:40 (chemical equivalent basis) diluted with underground water, and underground water (pH 6.5) as control were treated on potted Pines koraiensis seeds during the growing season (May 1 to August 31) in 1985. The regime of artificial acid rain, in terms of spray frequency and amount per plot, was simulated on the basis of climatological data averaged for 30 years of records. The seedling growth, contents of chemical substances in needles and chemical properties of the tested soil were compared among the various pH levels of acid rain on October 31, 1985. Following results were obtained. 1. With decreasing pH levels of acid rain, S and $K_2O$ contents in leaf tissue were increased, but MgO and $P_2O_5$ contents were decreased. 2. Soil pH was dropped, and exchangeable aluminum content in the tested soil was dramatically increased as the pH levels of acid rain decreased. 3. Exchangeable calcium, magnesium, potassium contents, and base saturation degree of the soil were significantly decreased with decreasing pH levels of acid rain. 4. Sulfate concentrations in the soil were significantly increased as rain pH decreased, but total nitrogen and available phosphate contents were not influenced by acid rain.

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Applications of Acid/Base Modified Activated Carbon for Stabilization of Sediment Contaminated with Organic Compounds (산/염기 개질활성탄을 이용한 유기오염물질 오염 퇴적토 안정화를 위한 적용성 연구)

  • Seunghyun Kang;Jaewoo Park
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.5
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    • pp.5-13
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    • 2024
  • This paper investigates the stabilization feasibility of contaminated sediment contaminated with benzyl butyl phthalate (BBP) using acid/base-modified activated carbon. The efficiency of stabilizers was evaluated by analyzing the impact of the activated carbon on the decomposition and adsorption of the contaminant, along with the biological effects on earthworms. Additionally, the contaminant migration was monitored with the BBP concentration in pore water using low-density polyethylene. The research results indicated that the accumulated concentration of BBP was approximately 2% lower in the experimental group applying a 5% mixture ratio of modified activated carbon compared to the group applying a 10% mixture ratio. The leaching into water was reduced by over 18% in all experimental conditions after 7-day exposure period. Over 25% reduction was observed after 28-day exposure. The pore water concentrations were measured. After 7 days of exposure, the mechanically mixed experimental group exhibited a higher pore water stabilization rate compared to the biologically mixed group. Within the mechanically mixed group, the experimental group with 10% mixture of modified activated carbon showed a 1% higher stabilization rate than the group with 5% mixture. After 28 days of exposure, the biologically mixed experimental group demonstrated a higher pore water stabilization rate compared to the mechanically mixed group. Moreover, within the biologically mixed group, the experimental group with 10% mixture of modified activated carbon showed approximately 0.1% higher stabilization rate than the group with 5% mixture.

Protein Quality Evaluation of Cooked Monkfish (Lophiomus setigerus) Meats

  • Jeung Young-Ae;Ryu Hong-Soo;Shin Eun-Soo;Mun Sook-Im
    • Fisheries and Aquatic Sciences
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    • v.6 no.4
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    • pp.165-171
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    • 2003
  • To investigate the effect of cooking methods on protein quality of domestic fresh monkfish meat (FMM) and imported frozen monkfish meat (IMM), in vitro protein qualities were determined by amino acid anlysis, trypsin indigestible substrate (TIS) formation, and protein digestibility using the four-enzyme method. Crude protein contents of the boiled FMM and IMM were $90\%$ of the dry base, which were higher than fresh FMM $(82\%)$ and IMM $(84\%)$. Profiles of total amino acid in FMM and IMM were not changed by cooking methods. Total free amino acid contents decreased to $ 29.0-33.6\%$ for boiled $(l00^{\circ}C,\;10 min)\;and\;24\%$ for steamed $(100^{\circ}C,\;10\;min)$ samples. In vitro protein digestibilities of boiled and steamed FMM incnased $86.6-86.8\%$, compared to raw IMM $(82.9\%)$, boiled and steamed IMM $85.1-85.5\%$ and raw IMM $(83.6\%)$. TIS of FMM (23.6 mg/g solid) and IMM (15.9 mg/g solid) showed no significant (p<0.05) difference in cooking methods. The C-PERs (computed protein efficiency ratio) of boiled FMM (2.63) and IMM (2.50) were significantly higher (<0.05) than raw (1.97) and steamed FMM(1.97) and IMM(1.94). These results demonstrate that boiling of FMM and IMM improves protein digestibility and C-PER when compared to steamed FMM and IMM. Therefore, boiling could be an excellent means to maintain high-protein quality of monkfish meat. Also, the cooking method may be applicable to the preparation of monkfish stew without any loss of free amino acids.

Processing Flaxseed for Food and Feed Uses

  • Wiesenborn, Dennis;Tostenson, Kristi;Kangas, Nancy;Zheng, Yun-Ling;Hall III, Clifford;Niehaus, Mary;Jarvis, Paul;Schwarz, Jurgen;Twombly, Wesley
    • Food Science and Biotechnology
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    • v.14 no.3
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    • pp.305-310
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    • 2005
  • Flaxseed is outstanding for lignans and oil rich in ${\alpha}$-linolenic acid which protect against several major illnesses. Better understanding of processing and storage characteristics of flaxseed will increase options for food use. Lignans and oil are found in the hull and embryo, respectively. Comparison of pearling and impact-dehulling processes for separation of lignan and oil-rich fractions showed the impact process was less effective, but easier to scale-up. Screw-pressing embryo reduced oil yield compared to whole seed, but doubled productivity and sharply reduced frictional heating of the oil. Flaxseed hull and embryo, also whole, ground and steamed-ground samples, were stable up to 30 weeks in closed containers at $23^{\circ}C$. Steamed-ground samples in open trays at $40^{\circ}C$ deteriorated markedly (peroxide value > 100 by 22 weeks); yet, whole seed remained stable. Incorporation of 18% flaxseed embryo into yellow perch feed increased ${\alpha}$-linolenic acid to 13 to l4% of muscle and liver lipids, compared to 0.5 to 0.7% in the no-embryo control. Feed conversion ratio, weight gain, and survival were similar. These studies are helping to establish the technological base for processing and utilizing flaxseed and flaxseed fractions to improve human diets.

$CO_2$ Buffering and Hydrogen Ion Concentration Gradient across Cell Membrane in Acute Acid-Base Disturbances in Dogs (혈액과 조직의 $CO_2$완충능 및 세포막을 통한 $H^+$농도 경사)

  • Hwang, Sang-Ik;Park, Young-Bae;Min, Byoung-Ku;Kim, Woo-Gyeum
    • The Korean Journal of Physiology
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    • v.17 no.2
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    • pp.119-124
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    • 1983
  • The in vivo and in vitro buffer capacities of true plasma and tissue buffer capaciies were compared on dogs. Intracellular pH was determined on skeletal muscle by a modification of the method of Schloerb and Grantham using $C^{14}$ DMO. The in vivo curve for plasma or extracellular fluid has a much lower slope than the in vitro curve. The in vivo slope of skeletal muscle in the dog is approximately 20 sl. The slope for skeletal muscle in vivo falls between the in vitro and in vivo slopes of true plasma. It appears that intracellular hydrogen ion varies linearly with extracellular hydrogen ion when $CO_2$ tension is changed. Both hydrogen ion gradient and Hi/He ratio vary in skeletal muscle, with an increase in $CO_2$ tension. Infusion of 0.3N HCl gave two distinct patterns, the $H_i-H_e$ gradient decreased; and it would appear that very little hydrogen ion as such penetrated to the inside of the cells during the time of observation. Although lactic acid presumably enters the cell and the same of larger load was given as was used for hydrochloric acid, only very mild intracellular acidosis resulted, ostensibly due to metabolism of this substrate. Gluconic acid produced a more severe acidosis, both intracellularly and extracellularly, but with both of these acids the hydrogen ion gradient decreased and the $H_i/H_e$ ratio also decreased. The experiments on the dogs with hemorrhagic shock the hydrogen ion increase producing the acidosis originates inside the cells. Even so, the hydrogen ion gradient increased only very slightly in the acute experiments. This may suggest that even over short intervals of time skeletal muscle cells have a capacity to pump out hydrogen ions at a rate which maintains approximately the normal $H_i/H_e$ gradient when the source of the hydrogen ion is in the interior of the cell.

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Production of GABA-rich Tomato Paste by Lactobacillus sp. Fermentation (유산균 발효에 의한 GABA 함유 토마토 페이스트의 생산)

  • Cho, Seok-Cheol;Kim, Dong-Hyun;Park, Chang-Seo;Koh, Jong-Ho;Pyun, Yu-Ryang;Kook, Moo-Chang
    • The Korean Journal of Food And Nutrition
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    • v.25 no.1
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    • pp.26-31
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    • 2012
  • For the purpose of production of GABA-rich tomato paste, this study was carried out to investigate GABA producing lactic acid bacteria from Korean traditional fermented food, Kimchi and optimize the culture conditions. As a result of fermentation, Lactobacillus brevis B3-20 among lactic acid bacteria isolated at the pre-experiments was the best producer of GABA at the tomato paste medium with 50%(wet-base) levels of dionized water. At the result of fermentation on the tomato paste medium with 0.5%(w/w) yeast extract, as a source of nitrogen, 3%(w/w) MSG(monosodium glutamate) and dionized water(the ratio of tomato paste and water was 2:8), Lb. brevis B3-20 produced the maximum GABA concentration, 143.38 mM. GABA-rich tomato paste showed the activity of free radical scavenging. Because GABA-rich tomato paste have functional ingredients such as ascorbic acid, lycopene, carotenoid, as well as GABA by lactic acid bacteria fermentation, GABA-rich tomato paste can be considered high functional materials.

Leaching of Soil Cations by Simulated Acid Rains of Different Compositions (구성성분이 다른 인공산성비에 의한 토양의 양이온 용탈에 관한 연구)

  • Ryu, Kwan-Shig;Min, Tai-Gi
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.407-413
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    • 1998
  • The influence of the anion composition of simulated acid rain on cation leaching of two soils with different surface charge properties was examined. Four mixtures of mole ratio of $SO_4:NO_3$(1:0, 2:1, 1:1, 0:1) with pH 2.0 simulated acid rain were applied to an Inceptisols(Gyuam series) and Andisols(Pyeongdae series). The Andisols had higher $SO_4{^{2-}}$ adsorption capacity than the Inceptisols because of its higher point of zero charge(PZC, pH 6.5) than Inceptisols(PZC pH 3.1). Cation leaching in Andisols varied directly with the $NO_3$ content of the leaching input due to higher mobility of $NO_3$ compared with $SO_4$ that was absorbed. The pH of the Andisols was higher with the addition of $Na_2SO_4$ than the addition of $NaNO_3$ indicating that this soil behaves as a base and has a high $SO_4$ adsorption capacity. The relative $NO_3{^-}/SO_4{^{2-}}$ content input had no effect on cation leaching of the Inceptisols. Amounts of leaching on the Andisols by simulated acid rain were higher than Inceptisols. This experiment explained that anion composition of acid rain plays a significant role in the cation leaching of soils which are able to adsorb $SO_4$.

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Preparation of Sea Urchin Skeleton Film Containing Robinia pseudoacacia Flower Extract (아까시 꽃 추출물을 첨가한 성게 껍질 필름의 제조)

  • Yang, Hyun-Ju;Song, Kyung Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.5
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    • pp.778-781
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    • 2016
  • Sea urchin skeleton (SUS) generated from production of sea urchin eggs was used as a biodegradable film base material, and its composite film with gelatin was prepared. In addition, Robinia pseudoacacia flower extract (RFE) was incorporated into the film-forming solution to provide antioxidant and anti-microbial activities. The tensile strength (TS) of the SUS/gelatin composite films increased with increasing gelatin content, whereas elongation at break (E) decreased. Among the composite films, SUS/gelatin film at a ratio of 8:2 (w/w) exhibited the most desirable TS and E values. Furthermore, SUS composite film containing RFE showed a reduced TS and increased E compared to the control film. Based on 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) and 2,2-diphenyl-1-picrylhydrazyl radical scavenging assays and disc diffusion results against growth of Listeria monocytogenes, antioxidant and anti-microbial activities of films increased with increasing RFE concentration. Consequently, SUS composite film containing RFE showed proper physical properties as well as antioxidant and anti-microbial activities. These results indicate that SUS can be used as a film base material while the SUS composite film containing RFE can be utilized as active packaging.

Coal Bottom Ash Application on Park Site Soil and Its Impacts on Turfgrass Growth and Soil Quality

  • Oh, Se Jin;Kim, Yong Hyok
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.2
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    • pp.127-134
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    • 2017
  • Bottom ash (BA) has different macro- and micronutrients such as B, Mo, Fe, Ca, and Mg, providing useful resources for plant growth and soil quality. The objective of this study was to evaluate the applicability of artificial top-soil treated with BA in park area as a vegetation base material, especially for turfgrass growth. Collected BA was mixed with peat moss and clay at the ratio of 70:10:20 (w/w). In order to evaluate the park quality and turfgrass growth in park area, the artificial soil was applied with BA along with the control or without BA. Result showed that exchangeable K and P were increased by $11.4mg\;kg^{-1}$ and $163mg\;kg^{-1}$, respectively, compared to the control soil when the artificial soil was treated with BA. Microbial population and enzyme activity (Acid-phosphatase, APA) in artificial soil having BA also increased as 2 times and 10%, respectively, compared to the control soil. Comparing turfgrass growth and yield between general soil and artificial soil, about 2 times higher plant yield (fresh weight) was observed as artificial soil was applied comparing to general soil. Furthermore, nutrient concentration in turfgrass was averaged as 0.440% for $P_2O_5$, 0.456% for CaO, 1.198% for $K_2O$ and 0.188% for MgO that all values are higher than general soil (0.323% for $P_2O_5$, 0.416% for CaO, 0.610% for $K_2O$ and 0.173% for MgO). Application of BA can be useful for vegetation base material in park site.