• Title/Summary/Keyword: Barrier free

Search Result 416, Processing Time 0.034 seconds

Characteristics of Zr-base Passivation Layers of Tinplate (전기주석도금강판의 Zr계 화학처리 피막 특성)

  • Bae D.C.;Kim T.Y.;Cho K.
    • Journal of the Korean institute of surface engineering
    • /
    • v.36 no.3
    • /
    • pp.251-255
    • /
    • 2003
  • With increasing environmental demands in surface treatment of steel sheets, the passivation layers containing hexavalent chromium $(Cr^{+6})$ are being replaced by non-chromium or trivalent chromium compounds. After review on the various types of inorganic compounds, the zirconates was chosen as the candidate for alternative to sodium dichromate in the aspect of its barrier properties with excellent adhesion to organics. The ammonium zirconium carbonate (AZC) and sodium hexafluorozirconate (SFZ) could be reach $70-80\%$ level of CDC (cathodic dichromate) treatment by their single applications. But high porosity in the AZC layer and poor electrical conductivity of SFZ solution limit the single application of zirconate. Mixed composition of zirconates to compensate their inferiorities or incorporation of organic compounds to seal the porosity seems to be inevitable to match up the target level of Cr-free passivation of tinplate.

Electrical characterization of OLED using metal free phthalocyanine (H2Pc) layer (무금속 프탈로시아닌(metal free phthalocyanine: H2Pc) 층이 삽입된 OLED의 전기적 특성 분석)

  • Ahn, Tae-Jun;Lee, Jong Ho;Choi, Bum Ho;Yu, Yun Seop
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2018.10a
    • /
    • pp.195-196
    • /
    • 2018
  • We have investigated electrical and optical characteristics of $H_2Pc$ introduced OLED devices. $H_2Pc$ layer acted on tunnel barrier for incident electrons. we have also observed that energy band of the proposed structure was varied as applied electric field by simulation using TCAD program.

  • PDF

Relative Reactivity of Various Al-substituted-dialkylalans in Reduction of Carbonyl Compounds: A Theoretical Study on Substituent Effect

  • Nahm, Keepyung;Cha, Jin Soon
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.8
    • /
    • pp.2335-2339
    • /
    • 2013
  • Relative reactivity of various Al-substituted dialkylalans ($AlR_2(X)$) in reduction of acetone has been studied with density functional theory and MP2 method. Formation of the alan dimers and the alan-acetone adduct, and the transition state for the Meerwein-Ponndorf-Verley (MPV) type reduction of the adduct were calculated to figure out the energy profile. Formation of dimeric alans is highly exothermic. Both the relative free energies for acetone-alan adduct formation and the TS barriers for the MPV type reduction with respect to alan dimers and acetone were calculated and they show the same trend. Based on these energetic data, relative reactivity of alans is expected to be; $AlR_2(Cl)$ > $AlR_2(OTf)$ > $AlR_2(O_2CCF_3)$ > $AlR_2(F)$ > $AlR_2(OMs)$ > $AlR_2(OAc)$ > $AlR_2(OMe)$ > $AlR_2(NMe_2)$. The energy profile is relatively well correlated with the experimental order of the reactivity of Al-substituted dialkylalans. It is noted that the substituents of alans have initial effects on the relative free energies for the carbonyl-adduct formation. Therefore, an $AlR_2(X)$ which forms a more stable carbonyl-adduct is more reactive in carbonyl reduction.

Constructing Proteome Reference Map of the Porcine Jejunal Cell Line (IPEC-J2) by Label-Free Mass Spectrometry

  • Kim, Sang Hoon;Pajarillo, Edward Alain B.;Balolong, Marilen P.;Lee, Ji Yoon;Kang, Dae-Kyung
    • Journal of Microbiology and Biotechnology
    • /
    • v.26 no.6
    • /
    • pp.1124-1131
    • /
    • 2016
  • In this study, the global proteome of the IPEC-J2 cell line was evaluated using ultra-high performance liquid chromatography coupled to a quadrupole Q Exactive Orbitrap mass spectrometer. Proteins were isolated from highly confluent IPEC-J2 cells in biological replicates and analyzed by label-free mass spectrometry prior to matching against a porcine genomic dataset. The results identified 1,517 proteins, accounting for 7.35% of all genes in the porcine genome. The highly abundant proteins detected, such as actin, annexin A2, and AHNAK nucleoprotein, are involved in structural integrity, signaling mechanisms, and cellular homeostasis. The high abundance of heat shock proteins indicated their significance in cellular defenses, barrier function, and gut homeostasis. Pathway analysis and annotation using the Kyoto Encyclopedia of Genes and Genomes database resulted in a putative protein network map of the regulation of immunological responses and structural integrity in the cell line. The comprehensive proteome analysis of IPEC-J2 cells provides fundamental insights into overall protein expression and pathway dynamics that might be useful in cell adhesion studies and immunological applications.

Structural and electrical properties of lead free ceramic: Ba(Nd1/2Nb1/2)O3

  • Nath, K. Amar;Prasad, K.;Chandra, K.P.;Kulkarni, A.R.
    • Advances in materials Research
    • /
    • v.2 no.2
    • /
    • pp.119-131
    • /
    • 2013
  • Impedance and electrical conduction studies of $Ba(Nd_{1/2}Nb_{1/2})O_3$ ceramic prepared using conventional high temperature solid-state reaction technique are presented. The crystal symmetry, space group and unit cell dimensions were estimated using Rietveld analysis. X-ray diffraction analysis indicated the formation of a single-phase cubic structure with space group $Pm\bar{3}m$. Energy dispersive X-ray analysis and scanning electron microscopy studies were carried to study the quality and purity of compound. The circuit model fittings were carried out using the impedance data to find the correlation between the response of real system and idealized model electrical circuit. Complex impedance analyses suggested the dielectric relaxation to be of non-Debye type and negative temperature coefficient of resistance character. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in $Ba(Nd_{1/2}Nb_{1/2})O_3$. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy.

Review on Tin Perovskite Solar Cells: Material and Device Properties (주석 페로브스카이트 태양전지에 관한 고찰: 재료 및 장치적 특성)

  • Dayeong Choi;Seyeong Lim;Hangyeol Kim
    • Current Photovoltaic Research
    • /
    • v.11 no.1
    • /
    • pp.18-26
    • /
    • 2023
  • Tin perovskite solar cells have attracted a lot of attention due to their potential to address the toxicity of lead, which is the biggest barrier to commercialization of perovskite solar cells. Unlike other lead-free perovskite, tin perovskite have a direct bandgap, which is suitable for use as light harvesting, and relatively good stability, which has led to a lot of attention. Since the first tin perovskite solar cell was reported in 2014, it has achieved an impressive power conversion efficiency of 14.81%. However, this efficiency is still low compared to that of lead perovskite solar cells, and the stability of tin perovskite solar cells is also an issue that needs to be addressed. In this review, we will discuss the basic properties of the tin atom in comparison to the lead atom, and then discuss the crystal structure, phase transition, and basic properties of tin perovskite. We will then discuss the advantages, applications, challenges, and strategies of tin perovskite, In particular, we will focus on how to prevent the oxidation of tin, which is arguably the biggest challenge for using tin perovskite solar cells. At the end, we summarize the key factors that need to be addressed for higher efficiency and stability, emphasizing what is needed to commercialize tin perovskite solar cells.

A Comparative Study on the Regulation-Free Special Zone and the Regional Special Development Zone (규제자유특구와 지역특화발전특구에 대한 비교 연구)

  • Choi, Ho-Sung;Kim, Jung-Dae
    • Journal of Digital Convergence
    • /
    • v.17 no.2
    • /
    • pp.31-36
    • /
    • 2019
  • New technologies are being created and resulted as new types of fusion complex as the barrier between technology and industries are being broken and convergence is becoming more activated in the global economy of the era of fourth industrial revolution. Korea government is trying to foster innovative technologies for new technologies and new services to prepare for the fourth industrial revolution and gain global competitiveness, but many regulations make it difficult to verify and commercialize them. In response, the Korea government is pushing for the introduction of a regulation-free special zone system in which sandboxes are applied so that new technology and new service-based innovation projects can be freely commercialized through experiment and demonstration. This study aims to examine the limitations of the special zones for regional specialization development applied to the zones that are applied uniformly throughout the country and suggest ways for the deregulation special zone to be fostered as an empirical test bed based on new technologies and as a base for regional innovation.

Actual Use and Characteristics of Clues for Blind Person's Independent Walking - Case Study of Kansai Region in JAPAN - (전맹인의 단독 보행을 유도하는 단서 사용실태와 특성 - 일본 간사이(關西) 지방 사례를 중심으로 -)

  • Cho, Minjung;Chie, Murosaki
    • Journal of The Korea Institute of Healthcare Architecture
    • /
    • v.18 no.1
    • /
    • pp.15-23
    • /
    • 2012
  • The purpose of this research is support blind person's daily walking. In order to achieve the purpose, we investigate how the environmental information is used for their daily walking both in residential and commercial areas considering the characteristics of walking. In the investigation, interview to the persons concerned is carried out and all the conversation with them is recorded with a voice recorder. Moreover, the environmental information that may become clues is plotted on a map together with photos. The results are as follows; (1) Environmental information which the blind persons use is different depending on the role of its own of place, such as place confirmation, direction decision, distance understanding. (2) It is demonstrated that the information acquisition from sound is effective when they especially understand place and location.

A Study on the Analyzation of Handicapped Facility in Residential outside Area (공동주택단지 옥외공간의 장애인 편의시설 실태분석에 관한 연구)

  • Park, Kwang-Jae;Seong, Ki-Chang
    • Journal of The Korea Institute of Healthcare Architecture
    • /
    • v.11 no.2
    • /
    • pp.45-54
    • /
    • 2005
  • The purpose of this paper is to analyze the handicapped facility in residential outside area, to found how to improve the law in analyzing the residential area and to suggest consideration factor in design phase. To concentrate the study, the objects of case study are selected carefully, also case study method is selected as well as objects. After observing the summary of objects, the checklist is made accordance with the improvement law of facility. The checklist has the general and detail factor about outdoor residential area, and the detail factor is based on the improvement law of facility and is used to examine and analyze.

  • PDF

A Study on the Service Policies for Dyslexia-Friendly Libraries (DFL(Dyslexia Friendly Library)을 위한 서비스 정책에 관한 연구)

  • Kim, Seon-Ho
    • Journal of the Korean Society for Library and Information Science
    • /
    • v.46 no.1
    • /
    • pp.201-221
    • /
    • 2012
  • The study identified the various service factors for dyslexia-friendly library in promoting accessibilities and eliminating barriers. The results from the in-depth interviews and social survey for dyslexia students and their guardians suggested some of the new library policies. These are: 1) more intensive need for PR and ads programs; 2) the revision of the existing library regulations and the assignment of dyslexia librarians; and 3) the expansion and customization of library stocks and dyslexic private rooms.