• Title/Summary/Keyword: Barrier energy

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Study on Reactive Non-thermal Plasma Process combined with Metal Oxide Catalyst for Removal of Dilute Trichloroethylene

  • Han Sang-Bo;Oda Tetsuji;Park Jae-Youn;Park Sang-Hyun;Koh Hee-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.292-300
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    • 2006
  • In order to improve energy efficiency in the dilute trichloroethylene removal using the nonthermal plasma process, the barrier discharge treatment combined with manganese dioxide was experimentally studied. Reaction kinetics in this process was studied on the basis of final byproducts distribution. Decomposition efficiency was improved to about $99\;\%$ at the specific energy of 40 J/L with passing through manganese dioxide. C=C ${\pi}$ bond cleavage of TCE substances gave DCAC, which has the single bond of C-C through oxidation reaction during the barrier discharge plasma treatment. Those DCAC were broken easily in the subsequent catalytic reaction due to the weak bonding energy about $3{\sim}4\;eV$ compared with the double bonding energy in TCE molecules. Oxidation byproducts of DCAC and TCAA from TCE decomposition are generated from the barrier discharge plasma treatment and catalytic surface chemical reaction, respectively. Complete oxidation of TCE into COx is required to about 400 J/L, but $CO_2$ selectivity remains about $60\;\%$.

Development on Thermal Bridge Barrier Between Window Frame and Wall (건축물의 창틀과 벽체 사이 열교 차단을 위한 단열공법 개발)

  • Park, Cheol-Yong;Kim, Woong-Hoi;Lee, Sang-Hee
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.10-11
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    • 2018
  • Internal Insulation system is applied to the most apartment building in Korea. However due to the importance of building energy enhanced the interest of the exernal insulation system. The extermal insulation system has better thermal performance because the thermal bridge through the structure are rarely formed. But the thermal bridge around the window decrease the thermal performance of the envelope system. Therefore the technology for reducing the thermal bridge around window improves energy efficiency of the building. In order to this it is necessary to minimize the thermal bridge around window of building. In this study it is aimed to minimize the thermal bridge around the window of building. It was confirmed that the use of thermal bridge barrier imporved the heat transfer rate by 64% or more and the condensation reduction phenomenon by 42% or more compared with the exist technology. These thermal bridge barrier will be used as the main technology to improve the energy efficiency of building.

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Graphene Oxide/Polyimide Nanocomposites for Gas Barrier Applications (산화그래핀이 함유된 폴리이미드 나노복합막의 기체차단성 평가 및 활용)

  • Yoo, Byung Min;Lee, Min Yong;Park, Ho Bum
    • Membrane Journal
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    • v.27 no.2
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    • pp.154-166
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    • 2017
  • Polymeric films for gas barrier applications such as food packaging and electronic devices have attracted great interest due to their cheap, light and easy processability among gas barrier materials. Especially in electronic devices, extremely low gas permeance is necessary for maintaining the device performance. However, current polymeric barrier films still suffer from relatively high gas permeance than other materials. Therefore, there have been strong needs to enhance the gas barrier performance of polymeric barrier films while keep their own advantages. Recently, graphene is highlighted as a 2D-layered material for gas barrier applications. However, owing to the poor workability and difficulty to produce in engineering scale, graphene oxide (GO) is on the rise. GO consists of oxygen-containing functional groups on surface with intrinsic 2D-layered structure and high aspect ratio, and it can be well-dispersed in aqueous polar solvents like water, resulting in scalable mass production. Here, we prepared GO incorporated polyimide (PI) nanocomposites. PI is widely used barrier polymer with high mechanical strength and thermal and chemical stability. We demonstrated that PI/GO nanocomposites could perform as a gas barrier. Furthermore, surfactants (Triton X-100 (TX) and Sodium deoxycholate (SDC)) are introduced to enhance the gas barrier performance by improving the degree of dispersion of GO in PI matrix. As a result, TX enhanced the gas barrier performance of PI/GO nanocomposites which is similar to predicted value. This finding will provide new insight to polymer nanocomposites for gas barrier applications.

Oxygen Barrier Coating with Carbon Interlayer on Polypropylene

  • Kim, Seong-Jin;Song, Eun-Gyeong;Jo, Gyeong-Sik;Yun, Tae-Gyeong;Mun, Myeong-Un;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.210-210
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    • 2012
  • Gas barrier coating from dense thin film deposition has been one of the important applications such as food-packaging and organic display. Especially for food-packaging, plastic container has been widely used due to its low price and high through-put in mass production. However, the plastic container with low surface energy like polypropylene (PP) has been limited to apply gas barrier coating. That is because a gas barrier coating could not adhere to PP due to its too low surface energy and high porosity of PP. In this research, we applied carbon coating consisting of Si and O as an interlayer between silicon oxide (SiOx) and PP. A carbon layer was found to provide better adhesion, which was experimentally proved by oxygen transmission rate (OTR) and SEM images. However, we also found that there is a limitation in the maximum thickness of a carbon layer and SiOx film due to their high stress level. For this conflict, we obtain the optimal thickness of a carbon layer and SiOx film showing optimal gas barrier property.

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Analysis of Energy Flow and Barrier Rib Height Effect using Ray-Optics Incorporated Three-dimensional PDP Cell Simulation

  • Chung, Woo-Joon;Jeong, Dong-Cheol;Whang, Ki-Woon;Park, Jae-Hyeung;Lee, Byoung-Ho
    • Journal of Information Display
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    • v.2 no.4
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    • pp.46-51
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    • 2001
  • Using ray-optics code incorporated with three-dimensional PDP cell simulation, we have analysed the energy flow in the PDP cell from the electric power input to the visible light output. Also, the visible light output profile and viewing angle distribution were obtained. We applied our code to the analysis of the barrier rib height effect on the visible light luminance and efficiency of the sustaining discharge. Although cells with higher barrier rib generate more VUV photons, less ratio of visible photons are emitted toward front panel due to the shadow effect. Thus, there exists optimal barrier rib height giving the highest visible luminance and efficiency. This kind of code can be a powerful tool in designing cell geometry.

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Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • v.15 no.3
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

Evaluation of U-value for Radiant Barrier Systems in Relation to Surface Emissivity (표면방사율에 따른 복사단열시스템의 열관류성능 평가 연구)

  • Kim, K.S.;Lee, D.G.;Yoon, J.H.;Song, I.C.
    • Solar Energy
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    • v.20 no.3
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    • pp.39-50
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    • 2000
  • Radiant barrier systems(RES) constructed with low emissivity materials bounded by an open air space can be used to reduce the net radiation transfer between two surfaces. To analyze the heat transfer characteristics of the radiant barrier systems which consist of a single-glass and radiation barriers, a simple theoretical model based on energy balances was suggested. And the model was validated by means of the experimental results. Using a guarded hot box, the temperatures of layers in selected RES and energy use for each cases were measured. The results show that the model well explained the heat transfer characteristics of those RES. Also, the heat transfer coefficient correlations considering natural and forced convection heat transfer ware suggested. It is found that the heat transfer efficiency of a RBS with aluminium surface improved up to 66.6% over that of a single glazing system.

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Analysis of Electrical Properties of Ti/Pt/Au Schottky Contacts on (n)GaAs Formed by Electron Beam Deposition and RF Sputtering

  • Sehgal, B-K;Balakrishnan, V-R;R Gulati;Tewari, S-P
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.1
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    • pp.1-12
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    • 2003
  • This paper describes a study on the abnormal behavior of the electrical characteristics of the (n)GaAs/Ti/Pt/Au Schottky contacts prepared by the two techniques of electron beam deposition and rf sputtering and after an annealing treatment. The samples were characterized by I-V and C-V measurements carried out over the temperature range of 150 - 350 K both in the as prepared state and after a 300 C, 30 min. anneal step. The variation of ideality factor with forward bias, the variation of ideality factor and barrier height with temperature and the difference between the capacitance barrier and current barrier show the presence of a thin interfacial oxide layer along with barrier height inhomogenieties at the metal/semiconductor interface. This barrier height inhomogeneity model also explains the lower barrier height for the sputtered samples to be due to the presence of low barrier height patches produced because of high plasma energy. After the annealing step the contacts prepared by electron beam have the highest typical current barrier height of 0.85 eV and capacitance barrier height of 0.86 eV whereas those prepared by sputtering (at the highest power studied) have the lowest typical current barrier height of 0.67 eV and capacitance barrier height of 0.78 eV.

Vertical Diffusion of Ammonia Into Amorphous Ice Sturcture

  • Kim, Yeong-Sun;Mun, Ui-Seong;Gang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.280-280
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    • 2012
  • We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

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Hydrodynamic performance of a vertical slotted breakwater

  • George, Arun;Cho, Il Hyoung
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.12 no.1
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    • pp.468-478
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    • 2020
  • The wave interaction problem with a vertical slotted breakwater, consisting of impermeable upper, lower parts and a permeable middle part, has been studied theoretically. An analytical model was presented for the estimation of reflection and transmission of monochromatic waves by a slotted breakwater. The far-field solution of the wave scattering involving nonlinear porous boundary condition was obtained using eigenfunction expansion method. The empirical formula for drag coefficient in the near-field, representing energy dissipation across the slotted barrier, was determined by curve fitting of the numerical solutions of 2-D channel flow using CFD code StarCCM+. The theoretical model was validated with laboratory experiments for various configurations of a slotted barrier. It showed that the developed analytical model can correctly predict the energy dissipation caused by turbulent eddies due to sudden contraction and expansion of a slotted barrier. The present paper provides a synergetic approach of the analytical and numerical modelling with minimum CPU time, for better estimation of the hydrodynamic performance of slotted breakwater.