• 한국세라믹학회지
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• 제11권2호
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• pp.17-21
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• 1974

Miscibility of barium sulfate in tricalcium silicate was investigated by firing 3CaCO3·SiO2 mixture containing barium sulfate at 1530℃. Added amount of barium sulfate to the mixture was zero to 5 mole % with intervals of 1 mole %. Lattice parametres were also calculated. Results were as follow; 1) Dissolution of barium sulfate in tricalcium silicate does not alter the symmetry in room temperature, but influences it's polymorphic transition forms, temperatures and thermal effects; modification triclinic Ⅱ is stabilized in room temperature. 2) Barium sulfate dissolves about up to 2 mole % in tricalcium silicate and more than this amount, tricalcium silicate formation is inhibited. 3) Unit cell volume of tricalcium silicate is slightly decreased with dissolution of barium sulfate, mainly because of contraction in c axis.

• The Journal of Advanced Prosthodontics
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• 제14권5호
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• pp.315-323
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• 2022

PURPOSE. The purpose of this study was to investigate the effect of barium silicate filler contents on mechanical properties of resin nanoceramics (RNCs) for additive manufacturing (AM). MATERIALS AND METHODS. Additively manufactured RNC specimens were divided into 4 groups depending on the content of ceramic fillers and polymers: 0% barium silicate and 100% polymer (B0/P10, control group); 50% barium silicate and 50% polymer (B5/P5); 60% barium silicate and 40% polymer (B6/P4); 67% barium silicate and 33% polymer (B6.7/P3.3). The compressive strength (n = 15) and fracture toughness (n = 12) of the specimens were measured, and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) analyses were performed. Independent sample Kruskal-Wallis tests were performed on the compressive strength and fracture toughness test results, and the significance of each group was analyzed at the 95% confidence interval through post-tests using the Bonferroni's method. RESULTS. B6/P4 and B6.7/P3.3 exhibited much higher yield strength than B0/P10 and B5/P5 (P < .05). Compared to the control group (B0/P10), the other three groups exhibited higher ultimate strength (P < .05). The fracture toughness of B6/P4 and B6.7/P3.3 were similar (P > .05). The content of barium silicate and fracture toughness showed a positive correlation coefficient (R = 0.582). SEM and EDS analyses revealed the presence of an oval-shaped ceramic aggregate in B6/P4 specimens, whereas the ceramic filler and polymer substrate were homogeneously mixed in B6.7/P3.3. CONCLUSION. Increasing the ceramic filler content improves the mechanical properties, but it can be accompanied by a decrease in the flowability and the homogeneity of the slurry.

• Nuclear Engineering and Technology
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• 제55권7호
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• pp.2366-2372
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• 2023

Are borate and silicate glasses suitable for working as shieling materials against fast neutrons? To correctly answer the above question, some silicate, and borate-based glasses were fabricated and irradiated with various doses of fast neutrons varied between 1.73 and 12.10 MGy. The color and hardness of the fabricated glasses were affected by the fast neutron fluence where the transparent glasses turned colored as well as the hardness of the fabricated glasses was decreased. The gamma-ray spectrometric analysis shows a high activity concentration produced in the barium borate glasses due to the formation of radioisotopes Ba-131 and Ba-133 reaches to 5.92E+05 Bq and 4.25E+03 Bq, respectively for sample Cd-5 Batch 3. Additionally, the gamma-ray spectrometric analysis for the sodium silicate glasses shows low activity concentrations emitted from isotopes formed due to the activation of Y₂O₃-associated impurities. These activities are low compared to that emitted by barium borate-based glasses.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.89.2-89.2
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• 2010

고체산화물 연료전지는 $800{\sim}1000^{\circ}C$인 고온에서 작동하므로 적용되는 밀봉재의 요구조건은 매우 중요하다. 본 연구에서는 SOFC 밀봉재로서 $SiO_2-B_2O_3-RO$계 결정화 유리를 선정하였으며 작동온도 부근에서 결정화를 유도하여 고온점성유동을 제어하고자 하였다. 따라서 $SiO_2-B_2O_3-RO$계에 RO인 CaO, SrO, BaO, MgO를 상호 치환하였을 때 결정상의 생성, 생성온도, 생성결정의 종류가 sealing 특성에 어떠한 영향을 주는가를 검토하였다. 결정화유리를 $800^{\circ}C$로 유지하였을 때 생성되는 주 결정상은 Calsium silicate, Strontium silicate, Barium silicate, Magnesium silicate이였으며 Strontium silicate 의 생성속도가 가장 빨랐으며 결정상은 불산으로 에칭하여 SEM으로 관찰하였다. Barium silicate를 유도한 결정화 유리가 $800^{\circ}C$에서 1000시간 유지하였을 경우 가장 내화학성이 우수하며 강도값도 154MPa로 가장 높았다. 또한 부분 결정화를 통해 $800^{\circ}C$ 점성유동이 제어됨을 고온현미경을 통해 관찰하였다.

• 폴리머
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• 제31권2호
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• pp.141-147
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• 2007

치아 수복용 충전제로서 인체 뼈의 주성분인 수산화인회석(hydroxyapatite)이 혼성화된 바륨실리케이트 (barium silicate, BaSi)를 사용하여 제조한 고분자 복합체의 치과적 물성을 분석하였다. 복합체 제조에 사용된 아크릴계 기재는 가시광선을 사용하여 경화시켰다. 실험 결과, 혼성화된 충전제 내에서의 BaSi 함량이 증가할수록 복합체의 기계적 강도는 일정하게 증가하였으며 치의학에서 규정한 값들을 상회하여 치아 수복재료로 충분한 값임을 확인할 수 있었다. 그러나 충전제 내에서의 BaSi 함량 증가에 따른 복합체의 내마모도는 약간 감소하였다. 한편, 복합체의 중합깊이는 충전제의 구성비에 관계없이 $6\sim9mm$ 정도로서 일반적 치과용 수복재료로 충분한 값들임을 확인하였으며 중합전환율과 중합수축률은 충전제 구성비에의 직접적 의존 경향성은 거의 없음을 확인할 수 있었다.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
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• pp.35-58
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• 2000

The demand for sub-micrometer or nanometer functional ceramic powders with a better suspension behavior in aqueous media in increasing. Redispersible barium titanate (BT) nanocrystals, green light emitting Mn2+ doped Zn$_2$SiO$_4$ and ZnS nanoparticle phosphors were synthesized by a hydrothermal method or chemical precipitation with surface modification. The nanoparticle redispersibility for BT was achieved by using a polymeric surfactant. X-ray diffraction(XRD) results indicated that the BT particles are of cubic phase with 80 nm in size. XRD results of zinc silicate phosphor indicate that seeds play an important role in enhancing the nucleation and crystallization of Zn$_2$SiO$_4$ crystals in a hydrothermal condition. This paper describes and discuss the methods of surface modification, and the resulting related properties for BT, zinc silicate and zinc sulfide.

• 한국세라믹학회지
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• 제11권1호
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• pp.29-35
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• 1974

Effect of calcium sulfate and barium sulfate on the formation of portland cement clinker was studied by means of chemical analysis. DTA and X-ray diffraction analysis. In the presence of liquid phase, effect of the additives on the formation of tricalcium silicate was examined according to the reaction, 2CaO.$SiO_3$＋CaO$\longrightarrow$3CaO.$SiO_3$, which is the principal reaction in portland cement clinkerization, and optimum conditions in firing clinker concerning amount of additive, firing time and temperature were determined, and its kinetics was referred to. The experimental results are summerized as follow: (1) Appropriate burning temperature range of cement clinker is more limited as the content of calcium sulfate in clinker is increased. Amount of calcium sulfate, firing time and temperature in proper condition of clinkerization is related to each others. Being added suitable quantity of calcium sulfate, firing temperature of clinker can be lowered about $100^{\circ}C$. (2) When 3-5 mole% of calcium sulfate is added, firing time of 15-30 minutes at about $1380^{\circ}C$ is reasonable, and if the content is over7 mole %, firing for 1 hr. or more at $1350^{\circ}C$ is anticipated to be optimum condition. (3) In the reaction of tricalcium silicate formation, the role of barium sulfate as a mineralizer is similar to that of calcium sulfate, but the optimum firing temperature of cement clinker containing barium sulfate tends to be 20-$30^{\circ}C$ higher than that of clinker containing calcium sulfate. (4) When barium sulfate is used as mineralizer, 2-3 mole % of it to tricalcium silicate is recommended and if it is added more than this amount, free CaO is increased rapidly in clinker and alite formation is inhibited.

• 공업화학
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• 제16권1호
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• pp.117-122
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• 2005

가시광선 중합형의 치아수복용 고분자 복합체(polymeric dental restorative composites, PDRC)에 있어서 여러 종류의 3급 아민계 광증감제가 PDRC의 치과적 물성에 미치는 영향을 기계적 물성과 심미적 특성을 분석한 후 고찰하였다. PDRC 제조에 사용한 barium silicate 필러는 아크릴계 resin matrix와의 혼화성 증가를 위해 표면을 소수성으로 처리하여 사용하였다. 광중합에 필요한 광개시제로는 resin matrix를 기준으로 camphorquinone을 0.5 wt%로 하여 사용하였다. 그 결과, 제조된 PDRC의 기계적 물성과 심미적 특성은 사용한 광증감제의 함량보다는 화학적 구조에의 의존성이 더 큼을 알 수 있었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.555-556
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• 2009

본 연구에서는 시멘트를 대신하여 고로슬래그를 원재료로 사용한 무시멘트 알칼리 활성 고로슬래그 콘크리트의 압축강도 발현 특성에 대하여 살펴보았다. 콘크리트의 강도성능을 높이기 위하여 알칼리 활성화제로 규산나트륨, 규산칼륨, 수산화바륨을 첨가하였고, 내수성 증진을 위해 수산화칼슘을 사용하여 실험하였다.

• 공업화학
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• 제16권3호
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• pp.422-426
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• 2005

가시광선에 의해 활성화되는 치아수복용 고분자 나노복합체를 제조하고 이들의 주요 물성을 고찰하였다. 복합체 제조에 사용한 충진재는 barium silicate와 나노 크기의 fumed silica가 혼합된 하이브리드 충진재를 사용하였으며 bisphenol A glycerolate methacrylate와 triethyleneglycol dimethacrylate로 구성되는 resin matrix와의 계면력 향상을 위해 실란 결합제로 표면을 소수성으로 처리하였다. 제조된 고분자 나노복합체의 기계적 물성을 평가한 결과, 나노 충진재가 첨가됨에 따라 내마모성이 향상되었다. 그러나 중합수축률 값은 나노 충진재 함량에 관계없이 3 vol% 이하로 거의 일정하였으며 광조사가 끝난 후에도 중합수축은 지속적으로 일어남을 알 수 있었다. 또한 복합체의 색차는 나노 충진재 함량이 늘어남에 따라 근소한 차이로 증가되었다.