• 분석과학
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• 제10권1호
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• pp.31-34
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• 1997

pH 4~5에서$ Ti^{4+}$ 이온을 여분의 옥살산 음이온으로 안정화시킨 다음 같은 당량의 $Ba^{2+}$ 이온이 첨가된 환경수 시료와 일시에 혼합시켜 줌으로써 barium titanate의 선구물질인 barium titanyl oxalate를 합성하였다. 이 때 환경수 시료 속에 미량으로 존재하는 $Cd^{2+}$ 및 $Pb^{2+}$ 이온이 정량적으로 공침되었으며, 이 공침법은 이들 원소의 분석을 위한 사전 농축법으로 활용 가능하였다.

• Korea-Australia Rheology Journal
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• 제18권2호
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• pp.103-107
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• 2006

Organic-inorganic composite of polyaniline and barium titanate (PANI-$BaTiO_3$) was synthesized via an in-situ oxidation polymerization of aniline in the presence of barium titanate ($BaTiO_3$) nanoparticles dispersed in an acidic medium. Barium titanate has large electric resistance and relatively high dielectric constant which is one of the essential properties for its electrorheological (ER) applications. The microstructure and composition of the obtained PANI/$BaTiO_3$ composite were characterized by SEM, FT-IR and XRD. In addition, we also employed a rotational rheometer to investigate the rheological performance of the ER fluids based on both pure PANI particle and PANI/$BaTiO_3$ composite. It was found that the composite materials possess much higher yield stresses than the pristine PANI due to unique dielectric properties of the inorganic $BaTiO_3$ particles. Finally, we also examined dynamic yield stress by analyzing its extrapolated yield stress data as a function of electric field strengths. Using the critical electric field strengths deduced, we further found that the universal yield stress equation collapses their data onto a single curve.

• Transactions on Electrical and Electronic Materials
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• 제18권3호
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• pp.163-168
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• 2017

The aim of the current research was to develop and present an effective methodology for simulating and analyzing the electrical and structural properties of piezoelectric material. The finite element method has been used to make precise numerical models when dielectric, piezoelectric and mechanical properties are known. The static and dynamic responses of circular ring-shaped barium titanate piezoelectric material have been investigated using the commercially available finite element software ABAQUS/CAE. To gain insight into the crystal morphology and to evaluate the purity of the material, a microscopic study was conducted using a scanning electron microscope and energy dispersive x-ray analysis. It is found that the maximum electrical potential of 6.43 V is obtained at a resonance frequency of 35 Hz by increasing the vibrating load. The results were then compared with the experimentally predicted data and the results agreed with each other.

• Biomaterials and Biomechanics in Bioengineering
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• 제4권1호
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• pp.33-44
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• 2019

This paper presents a novel structural composition for artificial bone scaffolds with an appropriate biocompatibility and biodegradability capability. To achieve this aim, carbon nanotubes, due to their prominent mechanical properties, high biocompatibility with the body and its structural similarities with the natural bone structure are selected in component of the artificial bone structure. Also, according to the piezoelectric properties of natural bone tissue, the barium titanate, which is one of the biocompatible material with body and has piezoelectric property, is used to create self-healing ability. Furthermore, due to the fact that, most of the bone tissue is consists of hydroxyapatite, this material is also added to the artificial bone structure. Finally, polycaprolactone is used in synthetic bone composition as a proper substrate for bone growth and repair. To demonstrate, performance of the presented composition, the mechanical behaviour of the bone scaffold is simulated using ANSYS Workbench software and three dimensional finite element modelling. The obtained results are compared with mechanical behaviour of the natural bone and the previous bone scaffold compositions. The results indicated that, the modulus of elasticity, strength and toughness of the proposed composition of bone scaffold is very close to the natural bone behaviour with respect to the previous bone scaffold compositions and this composition can be employed as an appropriate replacement for bone implants.

• Applied Microscopy
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• 제48권1호
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• pp.27-32
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• 2018

Barium titanate ($BaTiO_3$) nanoparticle is one of the most promising materials for future multi-layer ceramic capacitor and ferroelectric random access memory. It is well known that electrical property of nanoparticles depends on the atomistic structure. Although surface may possibly have an impact on the atomistic structure, reconstructed structure at the surface has not been widely investigated. In the present study, Ba-ion position near surface in a $BaTiO_3$ nanoparticle has been quantitatively characterized by scanning transmission electron microscopy. It was found that some Ba ions at the surface were greatly displaced in non-uniform directions.

• Transactions on Electrical and Electronic Materials
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• 제4권4호
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• pp.18-21
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• 2003

Sol-gel processing of $BaTiO_3$ ceramics doped with La(0.01-1.00 at. $\%$) were prepared from metal barium, titanium n-butoxide and lanthanum iso-propoxide. Characterization of the sol-gel-derived powder using XRD, SEM is also reported. The obtained results showed that insulator to semiconductor transition for highly donor-doped barium titanate was closely related to the incorporation of donor into the grains and to the resultant grain size, which were significantly affected by the sinterability of $BaTiO_3$ powders and sintering conditions used.

• 한국세라믹학회지
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• 제36권9호
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• pp.965-973
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• 1999

• 한국분말재료학회지
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• 제9권5호
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• pp.346-351
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• 2002

Pure and fine, two-component titanate powders (barium titanate, calcium titanate etc.) were synthesized by an ethylene glycol method. Titanium isopropoxide and other metal ionic salts were dissolved in liquid-type ethylene glycol without any precipitation. In non-aqueous system, the amount of ethylene glycol affected the solubility and homogeneity of metal cation sources in the solution. At the optimum amount of the polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. Most of the synthesized powders had sub-micron or nano-size primary particles after calcination and the agglomerated calcined powders were easily ground by ball milling process. All synthesized titanate powders had stable crystallization behavior at low temperature and high specific surface area after ball milling. The crystallization behavior and the microstructures of the calcined powders were affected on the ethylene glycol content.

• 한국결정학회:학술대회논문집
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• 한국결정학회 2002년도 정기총회 및 추계학술연구발표회
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• pp.19-19
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• 2002

Perovskite-type titanate dielectrics have attracted much attention in memory devices such as DRAMs or FeRAMs due to their high dielectric constants. However, low volatility of the Ba, Sr, Pb or Zr precursors with only thd ligands has limitations in obtaining high quality thin films by liquid source metal organic chemical vapor deposition (LS-MOCVD) processes. To improve the volatility of these precursors, many attempts have been made such as adding polyether ligands to satisfy the coordinative saturation. We report the synthesis of new precursors Ba(thd)₂(tmeea) and Sr(thd)₂(tmeea), where tmeea = tris[2-(2-methoxyethoxy)ethyl]amino, and LS-MOCVD of barium strontium titanate (BSTO) thin films using these precursors. Due to increased basicity of amines compared with ethers, it is expected that the nitrogen-donor ligand will make a strong bond to a metal than an analogous oxygen-donor ligand, consequently improving the volatility and thermal behavior of these precursors. Thin films of BSTO were grown on Pt(111)/SiO₂/Si(100) substrates by LS-MOCVD using a cocktail source consisting of the conventional Ti precursor Ti(thd)₂(O/sup i/Pr), and these new Ba and Sr precursors. As-grown films were characterized by XPS, SEM, XRD, XRF, and C-V and I-V measurements. BSTO films grown at 420℃ were stoichiometric barium strontium titanate with very smooth surface morphology and their dielectric constants were found to be as targe as 450. Dependence of the composition, microstructure and the electrical properties of the BSTO films on the growth temperature, annealing temperature, working pressure, and the composition of the cocktail source will be discussed.

• 한국세라믹학회지
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• 제32권10호
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• pp.1169-1177
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• 1995

Barium nitrate and yittrium nitrate were dissolved into distilled water. Titaium hydroxide precipitated from titanium chloride with NH4OH was dissolved into nitric acid. Each aqueous solution was mixed for 12 hr in the composition of Ba1-xYxTiO3 (x=0.1∼0.6) and the concentration of mixed solution was 0.1 mol/ι. The mixed solution was sprayed with an ultrasonic atomizer and carried into an electric furnace which was kept at 900∼1000$^{\circ}C$ and pyrolyzed. Pyrolyzed powders were collected on the glass filter with vacuum pump. Aqueous Mn solutiion was added into the synthesized powders, mixed with ultrasonic vibration and sintered at 1300∼1400$^{\circ}C$. Synthesized powders were characterized with SEM, XRD, DT-TGA, and BET. Microsture and resistivity of sintered body were investigated with SEM and multimeter. The results of this experiment were as follows; 1) Yittrium dooped BaTiO3 powders were synthesized above 950$^{\circ}C$. 2) The average particle sizes of powders from BET specific surface area and SEM were 0.045$\mu\textrm{m}$, 0.046$\mu\textrm{m}$ respectively. The particle size distribution was narrow in the range of 0.1∼1.0$\mu\textrm{m}$ from SEM. 3) Room temperature resistivity and pmax/pmin of 0.4 mol% Y doped specimen which was sintered at 1375$^{\circ}C$ were 102∼3 (Ω$.$cm) and 102∼3 respectively. 4) Room temperature resistivity and pmax/pmin of 0.4 mol% Y and 0.04 at% Mn added specimen which was sintered at 1375$^{\circ}C$ were 102∼3 (Ω$.$cm) and 106∼7 respectively. 5) Grain growth was inhibited with addition of Y2O3 and enhanced in addition of Mn by 0.05 atm%.