• 열처리공학회지
• /
• 제35권2호
• /
• pp.57-65
• /
• 2022

In this study, the effect of the initial particle size distribution (PSD) of (K_0.5Na_0.5)NbO₃ powders on the microstructure of sintered ceramics was investigated. (K_0.5Na_0.5)NbO₃ powders with uni-, bi-, tri-, and quad-modal PSDs were obtained through a planetary ball-mill. For the specimens sintered at 1080℃, the growth of abnormal grains was promoted from the powders exhibiting quad- and tri-modal PSDs with a high content of large particles, resulting in a microstructure in which huge abnormal grains were predominant. However, as the number of peaks in PSD and the overall particle size decreased, the abnormal grain growth was suppressed and the grain growth of small particles started, resulting in a microstructure with a uniform grain size. For the specimens sintered at 1100℃, huge abnormal grains were not observed due to the decrease in the critical driving force for 2D nucleation even when powders with quad- and tri-modal PSDs were used. It was confirmed that when powder with unimodal PSD was used, a uniform microstructure that was not significantly affected by the sintering temperature could be obtained. The results of this study demonstrate that the microstructure of (K_0.5Na_0.5)NbO₃-based ceramics can be controlled by controlling the particle size of the initial powder.

• 한국분말재료학회지
• /
• 제30권3호
• /
• pp.249-254
• /
• 2023

The influence of MgO addition on the densification and microstructure of alumina (Al₂O₃) was studied. Compacted alumina specimens were manufactured using ball-milling and one-directional pressing followed by sintering at temperatures below 1700℃. Relative density, shrinkage, hardness, and microstructure were investigated using analytical tools such as FE-SEM, EDS, and XRD. When the MgO was added up to 5.0 wt% and sintered at 1500℃ and 1600℃, the relative density exhibited an average value of 97% or more at both temperatures. The maximum density of 99.2% was with the addition of 0.5 wt% MgO at 1500℃. Meanwhile, the specimens showed significantly lower density values when sintered at 1400℃ than at 1500℃ and 1600℃ owing to the relatively low sintering temperature. The hardness and shrinkage data also showed a similar trend in the change in density, implying that the addition of approximately 0.5 wt% MgO can promote the densification of Al₂O₃. Studying the microstructure confirmed the uniformity of the sintered alumina. These results can be used as basic compositional data for the development of MgO-containing alumina as high-dielectric insulators.

• 한국분말재료학회지
• /
• 제30권5호
• /
• pp.415-423
• /
• 2023

With the increasing attention to environmental pollution caused by particulate matter globally, the automotive industry has also become increasingly interested in particulate matter, especially particulate matter generated by automobile brake systems. Here, we designed a coating composition and analyzed its mechanical properties to reduce particulate matter generated by brake systems during braking of vehicles. We designed a composition to check the mechanical properties change by adding Cr₃C₂ and YSZ to the WC-Ni-Cr composite composition. Based on the designed composition, coating samples were manufactured, and the coating properties were analyzed by Vickers hardness and ball-on-disk tests. As a result of the experiments, we found that the hardness and friction coefficient of the coating increased as the amount of Cr₃C₂ added decreased. Furthermore, we found that the hardness of the coating layer decreased when YSZ was added at 20vol%, but the friction coefficient was higher than the composition with Cr₃C₂ addition.

• 한국분말재료학회지
• /
• 제31권1호
• /
• pp.30-36
• /
• 2024

The aerospace and power generation industries have an increasing demand for high-temperature, high-strength materials. However, conventional materials typically lack sufficient fracture toughness and oxidation resistance at high temperatures. This study aims to enhance the high-temperature properties of Nb-Si-Ti alloys through ball milling. To analyze the effects of milling time, the progression of alloying is evaluated on the basis of XRD patterns and the microstructure of alloy powders. Spark plasma sintering (SPS) is employed to produce compacts, with thermodynamic modeling assisting in predicting phase fractions and sintering temperature ranges. The changes in the microstructure and variation in the mechanical properties due to the adjustment of the sintering temperature provide insights into the influence of Nb solid solution, Nb5Si3, and crystallite size within the compacts. By investigating the changes in the mechanical properties through strengthening mechanisms, such as precipitation strengthening, solid solution strengthening, and crystallite refinement, this study aims to verify the applicability of Nb-Si-Ti alloys in advanced material systems.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
• /
• pp.130-133
• /
• 2009

$Cu_2ZnSnSe_4$(CZTSe) is one of the promising materials for the solar cell due to its abundant availability in the nature. In this study, we report the fabrication of CZTSe thin film by Pulsed Laser Deposition(PLD) method using quaternary compound target on sodalime glass substrate. The quaternary CZTSe compound target was synthesized by solid state reaction method using elemental powders of Cu, Zn, Sn and Se. Powders were milled in high purity ethanol using zirconia ball with mixed size of 1 and 3 mm at the same proportions for 72 hours milling time. The structural, chemical and mechanical properties of the synthesized CZTSe powders were investigated prior to the deposition process. The CZTSe compound powder, and $500^{\circ}C$ of sintering temperature shows the best properties for PLD target. Results show that the as-deposited CZTSe thin films with the precursors by PLD have a composition near-stoichiometric.

• 한국식품위생안전성학회지
• /
• 제16권1호
• /
• pp.37-40
• /
• 2001

였고 6일 후에는 5개 모든 시료에서 곰팡이가 발생하였다. 겨자를 개는 물의 온도는 겨자의 항균성에 아무 영향을 주지 않았다. 계피와 산초의 경우 4일째부터 곰팡이가 발생하기 시작하였고, 고추냉이의 경우에는 6일째 곰팡이가 발생하였으며 겨자의 경우에는 8일이 지나도 곰팡이가 발생하지 않았다. 물에 의한 추출물 중 겨자와 고추냉이의 추출물이 항균력이 강하였고, 산초는 그보다 낮은 항균력을 나타내었다. 그러나 계피 추출물은 항균력의 거의 없었다. 에탄올에 의한 추출물 중 계피에서 추출한 것만 항균력이 조금 나타났고, 나머지의 경우에는 항균력이 거의 없었다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제54권4호
• /
• pp.139-143
• /
• 2005

For application of carbon nano-tube (CNT) as a counter electrode materials of dye-sensitized solar cell (DSSC), the electrochemical behavior of CNT electrode was studied, employing cyclic-voltammetry (C-V) and impedance spectroscopy. Fabrication of CNT-paste and formation of CNT-counter electrode for characteristic measurement have been carried out using ball-milling and doctor blade process, respectively. Unit cell for measurements was assembled using Pt electrode, CNT electrode, and iodine-embedded electrolyte. Field emission-scanning electron microscopy (FE-SEM) was used for structural investigation of CNT powder and electrode. Sheet resistance of electrode was measured with 4-point probe method. Electrochemical properties of electrode, C-V and impedance spectrum, were studied, employing potentiogalvanostat (EG&G 273A) and lock in amplifier (EG&G 5210). As a results, the sheet resistance of CNT electrode is almost similar to that of F-doped SnO2 (FTO) coated glass substrate as approximately 10 ohm/sq. From C-V and impedance spectroscopy measurements, it was found that CNT electrode has high reaction rate and low interface reaction resistance between CNT surface and electrolyte. These results provides that CNT electrode were superior to that of conventional Pt electrode. Particularly, the reaction rate in the CNT electrode is about thrice high than Pt electrode. Therefore. CNT electrode is to be good candidate material for counter electrode in DSSC.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
• /
• pp.648-651
• /
• 2003

Fine $LaAlO_3$ powders were successfully synthesized from $La_2O_3$ and ${\gamma}-Al_2O_3$ powders milling for $10{\sim}50hrs$ via the high energy milling technique (mechanochemical methode) in room temperature and air. The particle size of $LaAlO_3$ powder were estimated from XRD patterns and SEM images to be $160{\sim}180nm$. The $LaAlO_3$ ceramics are derived for the synthesized powders (milling for 10, 30 and 50hrs) by sintering at $1400^{\circ}C$. The micrographs of grains showed a agglomeration and the degree of agglomeration increased with the milling time. The $LaAlO_3$ made from synthesized powders milling for 30hrs can be sintered to 98% of theoretical density at $1,400^{\circ}C$ for 4hrs.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.209-212
• /
• 2001

Aircraft industry is developed very fast so titanium scrap was generated to manufacture. Titanium scrap was wasted and used to deoxidize cast iron so we are study recycling of it. In this research were studied that metal hydride of reacted in hydrogen chamber of AMS4900, 4901, return scrap titanium alloy and sponge titanium granule. The temperature of hydrogenation was 40$0^{\circ}C$ in the case of pure sponge titanium but return scrap titanium alloy were step reaction temperature at 40$0^{\circ}C$ and 50$0^{\circ}C$, and after the hydride of titanium alloy were crushed by ball mill for 5h. Titanium hydride contains to 4wt.% of hydrogen theoretically as theory. It was determined by heating and cooling curve in reaction chamber. The result of XRD was titanium hydride peak only that it was similar to pure titanium. Titanium hydride Powder particle size was about 45${\mu}{\textrm}{m}$, and recovery ratio was 95w% compared with scrap weight for a aluminum foam agent.

• 대한치과기공학회지
• /
• 제25권1호
• /
• pp.21-28
• /
• 2003

The purpose of this study was to process bio-active glass ceramic composite, reinforced with sapphire fibers, by hot press. Also to study the interface of the matrix and the sapphire fiber, and the mechanical properties. Glass raw materials melted in Pt crucible at 1300$^{\circ}C$ during 3.5 hours. The melt was crushed in ball mill and then crushed material, ground and sieved to $<40{\beta}{\mu}m$. Sapphire fibers cut (30mm) and aligned. Powder and fibers hot pressed. The micrographs show good bonding between the matrix and the fiber and no porosity in the glass matrix. This means ideal fracture phenomena. Glass is fractured before the fiber. This is indication of good fracture strength. EDXS showing aluminum rich phase and crystalline phase. Bright field image of the matrix showing crystalline phase. Also diffraction pattern of TEM showing the crystalline phase and more than one phase. Strength of the samples was determined by 3 point bend testing. Strength of the 10vol% sample was approximately 69MPa, while strength of the control sample is 35MPa. Conclusions through this study as follow: 1. Micrographs show no porosity in the glass matrix and the interface. 2. The interface between the fiber and the glass matrix show no gaps. 3. Fracture of the glass indicates characteristic fiber-matrix separation. 4. Presence of crystalline phase at high processing temperature. 5. Sapphire is compatible with bioactive glass.