• 제목/요약/키워드: Back-diffusion

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One-dimensional Analytical Solutions for Diffusion from a Low-permeability Layer (1차원 해석해를 이용한 저투수성 매체에서의 확산에 관한 연구)

  • Jang, Seonggan;Yang, Minjune
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.11-21
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    • 2020
  • One-dimensional analytical solutions were used for forward and back diffusion of trichloroethylene (TCE) and tetrachloroethylene (PCE) in a single system with high- and low-permeability layers. Concentration profiles in a low-permeability layer, diffusive fluxes at the interface between the high- and low-permeability layers, and contaminant persistence in the high-permeability layer due to back diffusion were simulated with a comparison of semi-infinite and finite analytical solutions. In order to validate the analytical solutions used in this study, the results of one-dimensional analytical solutions developed by Yang et al. (2015) were compared with Nash-Sutcliffe model efficiency coefficient (NSE). When compared with Yang et al. (2015), the analytical solutions used in this study showed good agreements (NSE = 0.99). When compared with semi-infinite analytical solutions, TCE and PCE concentration profiles in the low-permeability layer, the diffusive fluxes, and the contaminant tailings of the high-permeability layer were underestimated. In order to determine the appropriate analytical solutions based on the effective diffusion coefficient, the thickness of the low-permeability layer, and the diffusion time in the TCE and PCE contaminated site, a term of dimensionless diffusion length (Zd) was used. If the Zd is less than 0.7, the semi-infinite solutions can be used to simulate accurate concentration profiles in low-permeability layers. If the Zd is greater than 0.7, the reliability of simulations may be improved by using the finite solutions.

Non-equilibrium Monte Carlo Simulations for Critical Flux of Hard Sphere Suspensions in Crossflow Filtration

  • Kim, Albert S.
    • Proceedings of the Membrane Society of Korea Conference
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    • 2008.05a
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    • pp.33-47
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    • 2008
  • Non-equilibrium (irreversible) themodynamics is used to investigate colloidal back-diffusion during crossflow membrane filtration. The chemical potential is generalized as a superposition of equilibrium and irreversible contributions, originating from Brownian and shear-induced diffusion, respectively. As a result, an effective drag force is derived using the irreversible thermodynamics for a particle undergoing both Brownian and shear-induced diffusion in a sheared concentrated suspension. Using the drag force, a hydrodynamic force bias Monte Carlo method is developed for crossflow membrane filtration to determine the critical flux of hard sphere suspensions. Effects of shear rate and particle size on the critical flux are studied, and results show a good agreement with experimental observations reported in the literature.

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Life time test & Failure mode analysis of LED chip level for LCD back lighting unit (LCD BLU 광원용 LED chip level의 수명시험 및 고장모드 분석)

  • Park, Seung-Hyun;Lim, Sue-Hyun;Hwang, Nam;Cho, Young-Ick
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1556-1557
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    • 2007
  • LCD BLU에 광원의 수명을 측정하고, 고장모드를 분석하기 위해서는 광원을 구성하고 있는 각각의 성분 중에서 광원 자체를 구성하고 있는 R/G/B 광원에 대한 Burn-in test 및 고장모드를 분석하였다. LCD BLU에 있어서 R/G/B LED광원의 역할은 BLU 자체의 수명과 성능에 가장 큰 영향을 미친다. 서로 각각 사용조건하에서의 수명과 성능의 차이에 따라서 BLU 자체의 수명이 결정된다. 이를 평가가기 위해 LED device에 대한 가속수명테스트를 위한 Burn-in test를 실시하였으며, 발생한 고장모드를 분석하였다. 분석결과 누설전류 증가로 인한 불량이 주로 발생하였다. 누설전류 증가를 평가하기 위해 Photo emission microscope(PHEMOS-1000, MoDooTEK Inc.)을 이용하여 저전류에서의 LED chip의 누설전류에 의한 발광을 관찰함으로 인해, LED chip의 신뢰성 및 평가 기준이 됨을 알 수 있다.

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PROPERTIES OF Mo COMPOUNDS AS A DIFFUSION BARRIER BETWEEN Cu AND Si PREPARED BY CO-SPUTTERING

  • Lee, Yong-Hyuk;Park, Jun-Yong;Bae, Jeong-Woon;Yeom, Geun-Young
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.433-439
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    • 1999
  • In this study, the diffusion barrier properties of $1000\AA$ thick molybdenum compounds (Mox=1-5 Si) were investigated using sheet resistance measurements, X-ray diffractometry (XRD), and Rutherford back scattering spectrometry (RBS). Each barrier material was deposited by the de and rf magnetron co-sputtering of Mo and Si, respectively, and annealed at $500-700^{\circ}C$ for 30 min in vacuum. Each barrier material was failed at low temperatures due to Cu diffusion through grain boundaries and defects of barrier thin films or through the reaction of Cu with Si within Mo-barrier thin films. It was found that Mo rich thin films were less effective than Si rich films to Cu penetration activating Cu reaction with the substrate at a temperature higher than $500^{\circ}C$.

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Investigation of Al Back Contact and BSF Formation by In-situ TEM for Silicon Solar Cells

  • Park, Sungeun;Song, Jooyoung;Tark, Sung Ju;Kim, Young Do;Choi, Chel-Jong;Kwon, Soonwoo;Yoon, Sewang;Kim, Donghwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.38.1-38.1
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    • 2010
  • The trend to thinner crystalline silicon solar wafers in production of solar cells investigates re-evolution of back surface field (BSF) formation. We have studied mechanisms of back contact formation in Al evaporation and screen printed Al paste for Si solar cells by TEM analysis. We observed that Si diffuse into Al during heat up. The Si diffusion process made vacancies in Si wafer. The Al began to seep into the Si wafer (Al spike). During heat down, the Al spike were shrink which causes the doped region (BSF).

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Performance Characteristics of a Polymer Electrolyte Fuel Cell with the Anodic Supply Mode (고분자 전해질 연료전지의 수소극 공급모드에 따른 성능특성)

  • Lee, Yong-Taek;Park, Cha-Sik;Heo, Jae-Hyeok;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.7 s.262
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    • pp.588-595
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    • 2007
  • The water transport inside a polymer electrolyte fuel cell (PEFC) varied according to the anodic supply mode. The performance characteristics of a PEFC which can be affected by the water transport were observed with the anodic supply mode. In the flow-through and recirculation mode the performance showed no reduction with time because the flow in the anode was not stagnated. In the dead-end mode, without any discharged gas, the water remains inside of the anode, which caused the reduction of the performance with the lapse of time. However, even in the dead-end mode, little reduction of the performance with time was shown when only the anode was humidified externally. It means that the back-diffusion was the major factor to the accumulation of water in the anode rather than external humidification.

Time-Delay and Amplitude Modified BP Imaging Algorithm of Multiple Targets for UWB Through-the-Wall Radar Imaging

  • Zhang, Huamei;Li, Dongdong;Zhao, Jinlong;Wang, Haitao
    • Journal of Information Processing Systems
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    • v.13 no.4
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    • pp.677-688
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    • 2017
  • In order to solve the undetected probability of multiple targets in ultra-wideband (UWB) through-the-wall radar imaging (TWRI), a time-delay and amplitude modified back projection (BP) algorithm is proposed. The refraction point is found by Fermat's principle in the presence of a wall, and the time-delay is correctly compensated. On this basis, transmission loss of the electromagnetic wave, the absorption loss of the refraction wave, and the diffusion loss of the spherical wave are analyzed in detail. Amplitude compensation is deduced and tested on a model with a single-layer wall. The simulating results by finite difference time domain (FDTD) show that it is effective in increasing the scattering intensity of the targets behind the wall. Compensation for the diffusion loss in the spherical wave also plays a main role. Additionally, the two-layer wall model is simulated. Then, the calculating time and the imaging quality are compared between a single-layer wall model and a two-layer wall model. The results illustrate the performance of the time-delay and amplitude-modified BP algorithm with multiple targets and multiple-layer walls of UWB TWRI.

A Study on the CIGS cells with Na-doped Mo back contact (Na이 첨가된 Mo 전극을 이용한 CIGS 박막 태양전지 연구)

  • Yun, Jae-Ho;Kim, Ki-Hwan;Kim, Min-Sik;Ahn, Byung-Tae;Ahn, Se-Jin;Lee, Jeong-Chul;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.218-221
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    • 2006
  • The photovoltaic properties of CIES cells on alumina substrate were improved by using the Na-doped Mo as theabotom layer of hilo back contact. Na was supplied to the CIGS bulk region from alumina/Na-doped Mo/Mo/alumina? structure, as same assimilar to the Na diffusion from soda-lime glass. The content diffusion of Na from Na-doped bfo was smaller more controlled than that from SLG. These Our results indicate that Na-doped bfo act as Na source material and contents of Na amount can be controlled without the use of an alkali barrier layer. The best CIGS solar cell with conversion efficiency of 13.34%, $J_{sc}=34.62mA/cm^2,\;V_{oc}=0.58V$ and FF=66% for an active area of $0.45cm^2$ on the alumina substrate was obtained in the condition of for 100nm Na-doped Mo/1000nm Mo.

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Thermal diffusion properties of Zn, Cd, S, and B at the interface of CuInGaSe2 solar cells

  • Yoon, Young-Gui;Choi, In-Hwan
    • Current Photovoltaic Research
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    • v.1 no.1
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    • pp.52-58
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    • 2013
  • Two different window-structured $CuInGaSe_2$(CIGS) solar cells, i.e., CIGS/thin-CdS/ZnO:B(sample A) and CIGS/very thin-CdS/Zn(S/O)/ZnO:B(sample B), were prepared, and the diffusivity of Zn, Cd, S, and B atoms, respectively, in the CIGS, ZnO or Zn(S/O) layer was estimated by a theoretical fit to experimental secondary ion mass spectrometer data. Diffusivities of Zn, Cd, S, and B atoms in CIGS were $2.0{\times}10^{-13}(1.5{\times}10^{-13})$, $4.6{\times}10^{-13}(4.4{\times}10^{-13})$, $1.6{\times}10^{-13}(1.8{\times}10^{-13})$, and $1.2{\times}10^{-12}cm^2/s$ at 423K, respectively, where the values in parentheses were obtained from sample B and the others from sample A. The diffusivity of the B atom in a Zn(S/O) of sample B was $2.1{\times}10^{-14}cm^2/sec$. Moreover, the diffusivities of Cd and S atoms diffusing back into ZnO(sample A) or Zn(S/O)(sample A) layers were extremely low at 423K, and the estimated diffusion coefficients were $2.2{\times}10^{-15}cm^2/s$ for Cd and $3.0{\times}10^{-15}cm^2/s$ for S.

Enhancement of the Light Harvesting of Dye-sensitized Solar Cell by Inserting Scattering Layer (중간 광전극에 삽입된 산란층에 의한 염료감응 태양전지의 광수집 성능 향상)

  • Nam, Jung-Gyu;Kim, Bum-Sung;Lee, Jai-Sung
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.305-309
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    • 2009
  • The effect of light scattering layers (400 nm, TiO$_2$ particle) of 4 $\mu$m thickness on the dye-sensitized solar cell has been investigated with a 12 $\mu$m thickness of photo-anode (20 nm, TiO$_2$ particle). Two different structures of scattering layers (separated and back) were applied to investigate the light transmitting behaviors and solar cell properties. The light transmittance and cell efficiency significantly improved with inserting scattering layers. The back scattering layer structure had more effective transmitting behavior, but separated scattering layer (center: 2 $\mu$m, back: 2 $\mu$m) structure (9.83% of efficiency) showing higher efficiency (0.6%), short circuit current density (0.26 mA/cm$^2$) and fill factor (0.02). The inserting separating two scattering layers improved the light harvesting, and relatively thin back scattering layer (2 $\mu$m of thickness) minimized interruption of ion diffusion in liquid electrolyte.