• Title/Summary/Keyword: Back-Fill

Search Result 96, Processing Time 0.033 seconds

Crystal structure analysis of CIGS solar cell absorber by using in-situ XRD

  • Kim, Hye-Ran;Kim, Yong-Bae;Park, Seung-Il
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.319-319
    • /
    • 2010
  • 칼코젠계 태양전지의 광흡수층으로 사용되는 CuInSe2은 직접천이형 반도체로 광흡수계수가 $1{\times}105cm-1$로 매우 높고, 전기광학적 안정성이 우수하여 실리콘 결정질 태양전지를 대체할 고효율 태양전지로 각광받고 있다. 광흡수층의 밴드갭 에너지가 증가하면 태양전지의 개방전압(Voc)이 증가하여 광변환 효율을 향상시킬 수 있으므로, CuInSe2에서 In의 일부를 Ga으로 치환하여 에너지 밴드갭의 변화를 주는 연구가 많이 진행되고 있다. 그러나 화합물내의 Ga 조성비가 증가하면 단락전류(Jsc), 충진률(fill factor)이 낮아져 태양전지 효율을 저하시키게 되므로 CIGS 박막의 적절한 화합물 조성비를 갖도록 최적조건을 확립하는 것이 매우 중요하다. 본 실험에서는 광흡수층 형성을 위해 Sputtering법으로 금속 전구체를 증착하고, 고온에서 셀렌화 열처리를 수행하는 Sequential process(2단계 증착법)를 이용하였다. soda-lime glass 기판에 Back contact으로 Mo를 증착하고, 1단계로 CuIn0.7Ga0.3 조성비의 타겟을 이용하여 Sputtering법으로 $0.5{\sim}2{\mu}m$ 두께의 CIG 전구체를 증착하였다. 2단계로 CIG 전구체의 셀렌화열처리를 통하여 CIGS 화합물 구조의 박막을 형성시켰다. 이때 형성된 CIGS 화합물 박막의 두께는 동일하게 함으로써, 열처리온도에 의한 박막의 구조변화를 비교하였다. 증착된 CIGS 박막은 고온 엑스선회절분석을 통해 증착 두께와 온도 변화에 따른 CIGS 층의 구조 변화를 확인하고, 동일한 증착조건으로 Buffer layer, Window layer, Grid 전극을 형성하여 태양전지셀 특성을 평가함으로써 CIGS 태양전지 광흡수층의 결정구조에 따른 광변환 효율을 비교하였다.

  • PDF

Electrochemical Properties of Platinized Counter Electrode on based Stainless Steel Sheet for Dye-Sensitized Solar Cells (SUS 기판을 이용한 염료감응형 태양전지용 백금 상대전극의 전기화학적 특성)

  • Park, Kyung-Hee;Kim, Tae-Young;Back, Hyung-Ryul;Gu, Hal-Bon;Kim, Seung-Jai;Cho, Sung-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.11a
    • /
    • pp.262-263
    • /
    • 2005
  • Pt counter electrode based on flexible metal for dye-sensitized solar cells(DSCs) has been investigated. Photovoltaic structures on lightweight substrates have several advantages over the heavy glass-based structures in both terrestrial and space applications. Cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of Pt counter electrode both FTO glass and SUS sheet substrate. The DSCs composed of the counter electrode based on a stainless steel substrate has obtained conversion efficiencies comparable to that based on the conducting glass. The counter electrode based on the stainless steel substrate has the merit of improving the fill factor and conversion efficiency of the DSCs by reducing its internal resistance.

  • PDF

Global Increases in Dissolved Organic Carbon in Rivers and Their Implications

  • Kang, Ho-Jeong;Jang, In-Young;Freeman, Chris
    • Korean Journal of Ecology and Environment
    • /
    • v.43 no.4
    • /
    • pp.453-458
    • /
    • 2010
  • DOC (Dissolved Organic Carbon) is an operational terminology for organic carbon molecules dissolved in natural waters. DOC has been studied by ecologists extensively, because it plays a key role in various ecological functions such as substrates for secondary production and the carbon cycle. DOC also represents a substrate for microbial growth within potable water distribution systems, and can react with disinfectants (e.g., chloride) to form harmful disinfection by-products. In addition, residual DOC may carry with it organically bound toxic heavy metals. DOC in aquatic ecosystems may ultimately be transported to the oceans, or released back to the atmosphere by heterotrophic respiration, which can accelerate global climate change. There is evidence that DOC concentrations in aquatic ecosystems are increasing in many regions of the world including Europe, North America, and even in Korea. Land use changes, elevated temperature, elevated $CO_2$, recovery from acidification, and nitrogen deposition have been proposed as mechanisms for the trend. However, the key driving mechanism is yet to be conclusively determined. We propose that more extensive and longer-term observations, research of chemical properties of DOC, impacts of elevated DOC on environmental issues and interdisciplinary approaches are warranted as future studies to fill the gaps in our knowledge about DOC dynamics.

Comparison of Compressibility between the Oedometer Tests with the Field Measurements in Namak Clay (계측결과를 이용한 남악점토의 압축특성 비교)

  • Kim, Dongbeum;Ahn, Taebong
    • Journal of the Korean GEO-environmental Society
    • /
    • v.9 no.5
    • /
    • pp.15-20
    • /
    • 2008
  • Compressibility of the marine clay was mainly studied velocity of consolidation and numerical analysis by this time but studies of reevaluated from the field measurement data was a little. For last three years, areal fills and extensive field instrumentations including settlement and pore water pressure were performed in the site of the Youngsan River estuary site, South Korea. From the settlement data, field consolidation curves for sub-layers were reconstructed. Effective surcharge loads during the staged loadings were calculated using the fill heights and the excess pore water pressures in the ground. In the numerical analysis (PLAXIS), prefabricated vertical drains were also simulated. Laboratory, field, and numerical analysis showed good agreements in compressibility. Due to different conditions and limitations of the clay was the same range of the oedometer tests.

  • PDF

Nonlinear Seismic Behavior Analysis of Skewed Bridges Considering Pounding Between Deck and Abutment (상판과 교대의 충돌을 고려한 사교의 비선형 지진거동 해석)

  • Kang, Seung Woo;Choi, Kwang Kyu;Song, Si Young;Son, Min Kyu
    • Journal of the Earthquake Engineering Society of Korea
    • /
    • v.20 no.5
    • /
    • pp.301-310
    • /
    • 2016
  • There are differences in seismic behavior between non-skewed bridges and skewed bridges due to in-plane rotations caused by pounding between the skewed deck and its abutments during strong earthquake. Many advances have been made in developing design codes and guidelines for dynamic analyses of non-skewed bridges. However, there remain significant uncertainties with regard to the structural response of skewed bridges caused by unusual seismic response characteristics. The purpose of this study is performing non-linear time history analysis of the bridges using abutment-soil interaction model considering pounding between the skewed deck and its abutments, and analyzing global seismic behavior characteristics of the skewed bridges to assess the possibility of unseating. Refined bridge model with abutment back fill, shear key and elastomeric bearing was developed using non-linear spring element. In order to evaluate the amplification of longitudinal and transverse displacement response, non-linear time history analysis was performed for single span bridges. Far-fault and near-fault ground motions were used as input ground motions. According to each parameter, seismic behavior of skewed bridges was evaluated.

Strength Evaluation of I-Type Connecting System on a Segmental Retaining Reinforced Wall Consideration the Backfill Settlement (배면침하 영향을 고려한 보강토 옹벽의 I형 연결시스템 강도 평가)

  • Moon, Hee-Jung;Han, Jung-Geun;Lee, Jong-Young;Cho, Sam-Deok;Lee, Kwang-Wu
    • Journal of the Korean Geosynthetics Society
    • /
    • v.6 no.1
    • /
    • pp.27-32
    • /
    • 2007
  • This paper describes the applicability of geogrid with I-type coupling system, which permits vertical displacement on back fill ground of the reinforced retaining wall and also minimize the damage between block and geogrid. The improvement of coupling method allowed the reduction of approximately 700 mm in the existing geogrid, and as a result, the tensile strength at the coupling joint showed approximately 53% of the maximum tensile strength. It is expected from the laboratory investigations that the coupling strength of geogrid with the combination of in-situ supporting material should be predominant in the field condition.

  • PDF

Study on Manufacturing Actual Mal-gun from Joseon Dynasty -Based on the Excavated Mal-gun from Seok-nam-dong, In-chceon- (조선시대[朝鮮時代] 말군의 실물 제작법에 관한 연구)

  • Jeong, Mi-Sook;Song, Mi-Kyung
    • Journal of the Korean Society of Costume
    • /
    • v.57 no.7
    • /
    • pp.153-161
    • /
    • 2007
  • In 2004, Mal-gun(抹裙) was excavated from a plastered tomb in Seok-nam-dong, In-cheon. This tomb is assumed to be from an upper-class woman. The excavated Mal-gun was used to fill in the empty spaces in coffin, and it was seriously damaged and foxed dark. The Mal-gun is made with thin, loose Sook-cho(숙초), and the width of the fabric is 70cm. Both sides of the crotches are overlapped in front, and the back is opened. The waist straps are detached, leaving a little part to show the width of the straps. The hems of the Mal-gun are sewed straight, without any pleats, except some spaces for the feet to go through. This study compared the Mal-gun of Joseon Dynasty from the documentary records and picture records with the excavated Mal-gun from Seok-nam-dong, In-chceon. Also, actual Mal-gun was manufactured according to the excavated Mal-gun to study the process of manufacturing and the formation. As a result, the excavated Mal-gun has the same form of that shown in Ak-hak-gwae-bum, a documentary record from the early period of Joseon Dynasty.

Study on manufacture of Mo back contact films for CIGS solar cell by the cathodic arc ion plating (아크 이온 플레이팅법을 이용한 CIGS용 Mo 후면전극 제조에 관한 연구)

  • Kim, Gang-Sam;Jo, Yong-Gi;Jeong, Yong-Deok;Kim, Je-Ha
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2011.05a
    • /
    • pp.128-129
    • /
    • 2011
  • Mo 박막은 전기전도성과 열적 안전성이 우수하여 CIGS 용 후면전극으로 사용되고 있다. 많은 연구자들이 스퍼터링법을 이용하여 Mo 박막을 이중 박막으로 제조하고 있으며, CIGS 용 기판재로 SLG(Soda Lime Glass)와 연성기판재등이 주로 이용되고 있다. 연구에서는 SLG 기판재를 이용하여 스퍼터링법과 증착속도 및 이온화 등이 우수한 아크 이온 플레이팅법으로 Mo 박막을 제조하였으며, 제조된 Mo 박막을 CIGS 증착공정을 통하여 태양전지 효율을 측정하였다. 스퍼터링법과 아크 이온 플레이팅법으로 제조된 CIGS용 Mo 후면전극 위에 CIGS 박막 제조시 최대 효율은 11.43%, 11.14% 을 나타내었으며 Fill factor 는 67%와 57.3% 의 결과을 얻었다. 제조된 CIGS 셀의 단면 구조를 분석하기 위해 SEM 과 EDS 를 이용하였다. 두 공정방법으로 제조된 CIGS 셀의 단면을 관찰하여 Mo 전극위에 CIGS 박막 성장시의 입자크기가 스퍼터링법보다 아크 이온 플레이팅법이 박막성장이 더딘 것을 알 수 있었다. 그리고 아크 이온 플레이팅법을 이용한 SLG 기판재위에 CIGS 용 Mo 후면전극의 제조와 적용 가능성에 대해 알아보았다.

  • PDF

LFC 태양전지에서 접촉 면적 가변을 통한 전지 효율 변화 분석

  • Lee, Won-Baek;Lee, Yong-U;Jeong, Seong-Uk;Jang, Gyeong-Su;Park, Hyeong-Sik;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.300-300
    • /
    • 2010
  • 후면 패시베이션, back contact의 가변, 후면 접촉면적의 가변 등으로 Laser Fired Contact 태양전지의 효율을 증가 시킬 수 있다. 이 중 spacing의 가변으로 후면 접촉 면적을 가변 할 수 있으며, 이로 인하여 LFC 태양 전지의 효율을 높일 수 있을 것으로 전망된다. 본 연구에서는 후면 접촉 면적을 가변하였으며 이에 따른 효과를 확인하였다. series resistance가 작고, open circuit voltage 가 높은 최적의 조건을 찾는 것에 그 목적을 두었다. 실험 순서는 texturing 후, 후면에 SiNx를 10nm 증착하였으며, drive-in 방법으로 $POCl_3$을 도핑하였다. ARC후, spacing 조건 가변으로 접촉 면적을 가변시키면서 소자의 특성 변화를 비교하였다. 접촉 면적 및 spacing 조건은 5개의 set에 대하여 reference, 50%의 접촉 면적을 가지는 $150{\mu}m$ line, 10%의 접촉 면적을 가지는 $700{\mu}m$ line, 1%의 접촉 면적을 가지는 $700{\mu}m$ dot, 그리고 0.2%의 접촉 면적을 가지는 $1500{\mu}m$ dot으로 하였다. 각각의 경우에 대한 short circuit current density, fill factor, seris resistance, sheet resistance, open circuit voltage를 측정하였으며, 특히 series resistance는 각각의 경우에 대하여 $6.1m{\Omega}$, $5.1m{\Omega}$, $7.8m{\Omega}$, $10.1m{\Omega}$, 그리고 $15.7m{\Omega}$으로 측정되었다. wafer의 외각 테두리를 접촉 면적이 증가함에 따라서 sheet resistance가 증가하는 것을 확인 할 수 있었다.

  • PDF

Evaluation of the Adhesion Stability According to the Backfilling Area of the Tile back of the Bathroom of an Apartment House (공동주택 욕실의 타일배면 뒤채움 피착면적에 따른 부착안정성 평가)

  • Kim, Bum Soo;Song, Je Young;Oh, Sang Keun
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2021.05a
    • /
    • pp.14-15
    • /
    • 2021
  • Recently, the size of tiles used for bathroom walls in apartment houses is gradually increasing in size. The problem is that when these large-sized tiles are attached by the sticking method, due to the nature of the method, there is a concern about the stability of the attachment to the part (pupil) where the tile and the adhesive are not attached. The problem is serious as it leads to lawsuits in the outbreak court. In addition, it is urgent to verify the adhesion stability of the sticking method because secondary damage occurs due to a safety accident caused by the falling of the tile. Ministry of Land, Infrastructure and Transport [Investigation of defects in apartment houses, calculation of repair cost and defect determination criteria] ① The tile adhesion strength is 0.39N/mm2 or more and ② It is specified to fill 80% or more of the base area of the tile backside, but this is currently trendy. It is considered that large-sized tiles need to be verified from multiple angles, and as part of that, we intend to verify the adhesion stability according to the area to be attached to large-sized tiles.

  • PDF