• Title/Summary/Keyword: BaSrTiO

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Dielectric Properties of (Ba,Sr)$TiO_3$ Thin Films with Substrate Temperature (기판온도에 따른 (Ba,Sr)$TiO_3$ 박막의 유전특성)

  • Lee, Sang-Chul;Chung, Jang-Ho;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1879-1881
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    • 1999
  • (Ba,Sr)$TiO_3$[BST] thin films were fabricated on Pt/Ti/$SiO_2$/Si substrate by RF sputtering. We investigated the effects of substrate temperature on the structural and dielectric properties of BST thin films. Increasing the substrate temperature, barium multi titanate phases were decreased, and BST (100), (200) peaks were increased. The relative dielectric constant and dielectric loss of the BST thin films at the substrate temperature of $500^{\circ}C$ were 300 and 0.018, respectively at l[kHz]. In all films, the dielectric constants decreased. Dielectric losses increased as increasing the frequency. The switching voltage was 5V of the BST thin films at the substrate temperature of $500^{\circ}C$.

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The properties of $(Ba_{0.7}\;Sr_{0.3})TiO_3$ by Multilayer structure (다층 구조에 의한 $(Ba_{0.7}\;Sr_{0.3})TiO_3$의 물리적 특성)

  • Hong, Kyung-Jin;Cho, Jae-Cheal
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.31-34
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    • 2006
  • In this study, $(Ba_{0.7}\;Sr_{0.3})TiO_3$ was coated on Pt/Ti/$SiO_2$/Si wafer by using Sol-Gel method. Coating process was repeated 3~5 times and then sintered at 750[$^{\circ}C$] for 1 hour. Each specimen was analyzed structure and electrical characteristics. In structure characteristics, EDX analyzed the samples ratio of the formation on the structural property. Thermal behavior was observed with TG-DTA and concluded that the heat-treatment of the samples was degreed 750[$^{\circ}C$]. Surface and section of thin films were observed with SEM.

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Electrical Properties of ${Ba_{0.5}}{Sr_{0.5}}{TiO_3}$Thin Film with Various Heat Treatment Conditions (다양한 열처리 조건에 따른 ${Ba_{0.5}}{Sr_{0.5}}{TiO_3}$박막의 전기적 특성)

  • 손영국
    • Journal of the Korean Ceramic Society
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    • v.38 no.5
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    • pp.492-498
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    • 2001
  • Ba$_{0.5}$Sr$_{0.5}$TiO$_3$타겟을 이용 Pt/Ti/SiO/Si 기판 위에 R.F magnetron sputtering 방법으로 BST 박막을 증착하여 다양한 열처리 조건에 따른 BST 박막의 전기적 성질(정전용량, 누설전류)에 대해 박막의 결정성과 미세구조의 연관성에 대하여 연구하였다. BST 박막의 유전상수는 grain size에 영향 받으며, 열처리 온도가 증가할수록 유전상수는 증가함을 보였고 온도에 따른 누설전류는 저전압 영역에서는 Hopping conduction, 고전압 영역에서는 Schottky conduction mechanism을 따르는 것으로 나타났다.

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Tunable properties and low temperature sintering of BST thick films added ${Li_2}{CO_3}$ (${Li_2}{CO_3}$첨가에 의한 $BaSr(TiO_3)$의 저온 소결과 가변유전 특성)

  • Kim, In-Sung;Min, Bok-Ki;Jeong, Soon-Jong;Song, Jae-Sung;Jeon, So-Hyun
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.7-9
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    • 2006
  • $(BaSr)TiO_3$ thick films were prepared by tape casting method using $BaTiO_3$ and $SrTiO_3$ powder slurry in order to investigate dielectric properties and low temperature sintering. Sintering density was $5.7\;g/cm^3$ and the BST sample exhibited the maximum dielectric constant, tunability at temperatures near phase transition point. The dielectric constant was increased and curie temperature was shifted to higher temperature with increasing of annealing temperature.

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Structural and Dielectric Properties of (Ba,Sr,Ca)$TiO_3$ Thick films Doped with $Dy_{2}O_{3}$ ($Dy_{2}O_{3}$가 첨가된 (Ba,Sr,Ca)$TiO_3$ 후막의 구조 및 유전 특성)

  • Yun, Sang-Eun;Lee, Sung-Gap;Park, Sang-Man;Noh, Hyun-Ji;Lee, Young-Hie;Bae, Seon-Gi
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1275-1276
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    • 2007
  • For fabrication of $BaTiO_3$ system Ferroelectric thick films, (Ba,Sr,Ca)$TiO_3$ (BSCT) powders, prepared by using the alkoxide-based sol-gel method, were doped $MnCO_3$ as acceptor and $Dy_{2}O_{3}$ as donor. $MnCO_3$ and $Dy_{2}O_{3}$-doped (Ba,Sr,Ca)$TiO_3$ thick films were fabricated by screen printing techniques on high purity alumina substrates. The structure and dielectric properties were investigated with variation of $Dy_{2}O_{3}$ amount. As a result of the differential thermal analysis(DTA), exothermic peak was observed at around $670^{\circ}C$ due to the formation of the polycrystalline perovskite phase. All the BSCT thick films, sintered at $1420^{\circ}C$ for 2h, showed the typical XRD patterns of perovskite polycrystalline structure and no pyrochlore phase was observed. The average grain size and thickness of specimens no doped with $Dy_{2}O_{3}$ was 1.32mm, 52mm, respectively. The relative dielectric constant decreased and dielectric loss increased with increasing amount of $Dy_{2}O_{3}$ dopant, the values of the BSCT thick films no doped with $Dy_{2}O_{3}$ were 4043 and 0.4% at 1 kHz, respectively. The relative dielectric constant gradually decreased in the measured frequency range from 0.1 to 100 kHz

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Crystal Growth and their photorefractive properties for optical memo (광메모리 단결정의 성장과 그 특성)

  • 유영문
    • Broadcasting and Media Magazine
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    • v.6 no.1
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    • pp.78-87
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    • 2001
  • Seven kinds of most representative photorefractive crystals expected to contribute to the realization of the volume holographic storage were reviewed The growth conditions and problems for highly homogeneous optical qualities of the following crystals depending on the growth methods were discussed;(1) $LiNbO_3$ and $Bi_2SiO_{20}$ by Czochralski method (2) $Bi_{12}TiO_{20}$, $KNbO_3$ and $BaTiO_3$ by top seeded solution growth and (3) $(Sr_{1-x}Ba_{x})Nb_{2}O_{6}$ and $(K_{1-y}Na_y)_{2A-2}(Sr_{1-x}Ba_x)_{2-A}Nb_2O_6$ by Stepanov method, And then the figure of merits for the estimation of phororefractive materials on performances, such as $Q_1$, $Q_2$ and sensitivity, were discussed.

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Influences of A($Cu_{1/3}Nb_{2/3}$)$O_3$(A=Pb, Ba and Sr) on the Ferroelectric Paraelectric Phase Transition of $BaTiO_3$ Ceramics ($BaTiO_3$의 강유전-상유전 상전이에 미치는 A($Cu_{1/3}Nb_{2/3}$)$O_3$ (A=Pb, Ba 및 Sr)의 영향)

  • Park, Hyu-Bum;Kim, Jung;Kim, Si-Joong
    • Journal of the Korean Ceramic Society
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    • v.28 no.12
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    • pp.969-974
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    • 1991
  • The influences of A(Cu1/3Nb2/3)O3(A=Pb, Ba and Sr) on the ferroelectric-paraelectric phase transition of BaTiO3 ceramics has been investigated. The tetragonality of crystal structure decreased with increasing A(Cu1/3Nb2/3)O3 content at room temperature. A linear correlation between Curie point and the tetragonality of lattice was not observed. In all three systems the variation of Curie point with the mole fraction showed similar tendency that the Curie point decreased at lower mole fraction but gradually increased in the region of higher mole fractions, Diffuse phase transitions were observed at higher mole fractions. The variation of Curie points could be explained by internal stress and Jahn-Teller distortion of BO6 due to Cu2+, and it was thought that the diffuse character of phase transition was caused by compositional fluctuation.

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Characteristics of (Ba,Sr)RuO$_3$Bottom Electrodes by Liquid Delivery Metalorganic Chemical Vapor Deposition (액체 운반 유기 금속 화학 기상 증착법에 의한 $(Ba,Sr)RuO_3$ 하부전극의 특성)

  • Choe, Eun-Seok;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.997-1000
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    • 2001
  • Conducting perovskite oxide, $(Ba,Sr)RuO_3(BSR)$, which has many advantages for $(Ba,Sr)TiO_3(BST)$ due to their similarity in crystal structure, lattice constant and chemical composition, was prepared on n-type Si (100) by liquid delivery metalorganic chemical vapor deposition(LDMOCVD). The deposition characteristics of BSR were controlled by gas-phase mass-transfer in the experiment. The BSR films deposited at 50$0^{\circ}C$ and oxygen flow rate of 100 sccm(standard cc/min) showed an average roughness of 22 $\AA$and resistivity of 810 $\mu$$\Omega$-cm. The roughness of BSR films with oxygen flow rate showed a close relationship with the resistivity of films. BSR (110) peak shifted toward lower Bragg angle with increase of x in the$(Ba_x,Sr_{1-x})TiO_3$. The resistivity of BSR films increased from 810 to 924 $\mu$$\Omega$-cm with increase of Ba content(x).

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