• Journal of Korean Society on Water Environment
• /
• v.27 no.3
• /
• pp.322-328
• /
• 2011

This study was performed to investigate the characteristics of nutrient removal of municipal wastewater in the membrane bioreactor system with the different types of membrane. Membrane bioreactor consists of three reactors such as two intermittent anaerobic and the submerged membrane aerobic reactor with flat sheet and hollow fiber membrane, respectively. The removal efficiencies of $COD_{cr}$, BOD, SS, TN and TP on the flat sheet membrane bioreactor were 94.3%, 99.0%, 99.9%, 70.3% and 63.1%, respectively. In addition, The removal efficiencies of $COD_{cr}$, BOD, SS, TN and TP on the hollow fiber membrane bioreactor were 94.0%, 99.3%, 99.9%, 69.9% and 66.9%, respectively. The estimated true biomass yield, specific denitrification rate (SDNR), specific nitrification rate (SNR) and phosphorus removal content on the flat sheet membrane bioreactor were $0.33kgVSS/kgBOD{\cdot}d$, $0.043mgNO_3-N/mgVSS{\cdot}d$, $0.031mgNH_4-N/mgVSS{\cdot}d$, and 0.144 kgP/d, respectively. In addition, the estimated true biomass yield, specific denitrification rate (SDNR), specific nitrification rate (SNR) and phosphorus removal content on the hollow fiber membrane bioreactor were $0.30kgVSS/kgBOD{\cdot}d$, $0.067mgNO_3-N/mgVSS{\cdot}d$, $0.028mgNH_4-N/mgVSS{\cdot}d$, and 0.121 kgP/d, respectively. There was little difference between the flat sheet and hollow fiber on the nutrient removal efficiencies except SNR and SDNR. These differences between them were caused by the air demand to prevent the membrane fouling. The flux and oxygen demand for air scouring were $19.0L/m^2/hr$ and $2.28m^3/min$ for the flat sheet membrane, and $20.7L/m^2/hr$ and $1.77m^3/min$ for the hollow fiber membrane on an average.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.12
• /
• pp.3521-3526
• /
• 2014

A magnetic sonophotocatalyst $Fe_3O_4@SiO_2@TiO_2$ is synthesized for the enhanced biodegradability of organophosphate pesticide. The as-prepared catalysts were characterized using different techniques, such as X-ray diffraction (XRD) and transmission electron microscopy (TEM). The radial sonophotocatalytic activity of $Fe_3O_4@SiO_2@TiO_2$ nanocomposite was investigated, in which commercial dichlorvos (DDVP) was chosen as an object. The degradation efficiency was evaluated in terms of chemical oxygen demand (COD) and enhancement of biodegradability. The effect of different factors, such as reaction time, pH, the added amount of catalyst on $COD_{Cr}$ removal efficiency were investigated. The average $COD_{Cr}$ removal efficiency reached 63.13% after 240 min in 12 L sonophotocatalytic reactor (catalyst $0.2gL^{-1}$, pH 7.3). The synergistic effect occurs in the combined sonolysis and photocatalysis which is proved by the significant improvement in $COD_{Cr}$ removal efficiency compared with that of solo photocatalysis. Under this experimental condition, the $BOD_5/COD_{Cr}$ ratio rose from 0.131 to 0.411, showing a remarkable improvement in biodegradability. These results showed that sonophotocatalysis may be applied as pre-treatment of pesticide wastewater, and then for biological treatment. The synthesized magnetic nanocomposite had good photocatalytic performance and stability, as when it was used for the fifth time, the $COD_{Cr}$ removal efficiency was still about 62.38%.

• International Journal of Highway Engineering
• /
• v.16 no.6
• /
• pp.9-17
• /
• 2014

PURPOSES : The purpose of this study is to assess removal efficiency of non-point pollutants and applicability for non-point pollutant reduction facilities by conducting the demonstration project operation. METHODS : In order to analyze removal efficiency of non-point pollutants for facilities such as a grassed swale, a small constructed wetland, a free water surface wetland, a horizontal sub-surface flow wetland, and a sand filtration, the field data including specifications of facilities, rainfall, inflow and runoff rainfall effluent etc. was acquired after occurring rainfall events, and the acquired data was analyzed for removal efficiency rate to assess road non-point pollutants facilities using event mean concentration (EMC) and summation of load (SOL) methods. RESULTS : The results of analyzing rainfall effluent, non-point pollutant sources showed that total suspended solid (TSS), chemical oxygen demand (COD), biochemical oxygen demand (BOD), total nitrogen (TN), total phosphorus (TP), chrome (Cr), zinc (Zn), and lead (Pb) can be removed through non-point pollutant reduction facilities by 60.3% ~ 100%. Especially removal efficiency of TSS, COD and BOD is relatively higher than removal efficiency of other non-point pollutant sources in all kind of non-point pollutant facilities. CONCLUSIONS : Based on the result of this study, even though natural type of non-point pollutant reduction facilities for roads occupy small areas comparing with drainage basin areas, most of non-point pollutant sources would be removed through the facilities.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.40 no.3
• /
• pp.83-92
• /
• 1998

Field experiment was performed from August 1996 to January 1998 to examine the applicability of constructed wetland system for wastewater treatment in rural area. The pilot plant was installed in Kon-Kuk University and the school building septic tank effluent was used as an influent to the treatment basin. Hydraulic loading rate was about 0.1 6$0.16^3/m^2$ day and theoretical detention time in the system was 1.38 days. The treatment basin was composed of sand and reed. The influent DO concentration was low and many cases close to zero, but effluent concentration was higher than the influent which implies that oxygen was supplied naturally. The average concentration of influent BOD was 126mg/L, and with average removal rate of 69 % the average effluent concentration was 4Omg/L which satisfied the effluent water quality standard for the system of interest. The average influent concentration of COD was 2Olmg/L and average effluent concentration was 75mg/L with average removal rate of 60%. The performance of BOD and COD tends to deteriorate in the low temperature, and appropriate action needs to be taken during the cold winter time for stable operation. The average influent concentration of SS was 5Omg/L, and effluent was 1 1mg/L with average removal rate of 76% which satisfied the effluent water quality standard for the system of interest. The results for the regulated components, SOD and SS, from the experiment showed that constructed wetland system can meet the effluent water quality standards. The average influent concentration of total phosphorus was 25.6mg/L and average effluent concentration was 7.8mg/L with average removal rate of 63%. Not like the performance of the above components, average nitrogen removal rate was only 11.2% which is not satisfactory. Although, nitrogen is not regulated at this moment, it can cause many environmental problems including eutrophication. Therefore, nitrogen removal efficiency should be improved for actual application. From the result of the field experiment, constructed wetland system was thought to be an appropriate alternative for wastewater treatment in rural area.

• Korean Journal of Soil Science and Fertilizer
• /
• v.50 no.5
• /
• pp.325-335
• /
• 2017

This study was carried out for 30 days in aeration type and agitation type reactor to characterize organic matter decomposition and ammonia volatilization during the liquid composting of pig slurry, and organic matter and nitrogen removal rate through mass balance analysis was analyzed. In the aeration type reactor, the pH increased from 7.0 to 9.13, and TS 34.5%, VS 33.4%, $BOD_5$ 71.2%, $COD_{Cr}$ 62.3% and TOC 83.2% were removed. In addition, 44.6% of TN and 65.0% of ${NH_4}^+-N$ were removed. In the agitation type reactor, the pH increased from 7.0 to 8.10, and the removal rates of TS 0.9%, VS 0.5%, $COD_{Cr}$ 27.5%, $BOD_5$ 28.9% and TOC 41.3% were obtained. And TN and ${NH_4}^+-N$ showed removal rate of 25.3% and 29.2%, respectively. The first order kinetics constant related to $BOD_5$ degradation was $-0.039day^{-1}$ for aerobic liquid composting and $-0.013day^{-1}$ for agitated reactor. Nitrogen loss in aerobic liquid composting was about 2.3 times higher than that of agitated reactor, whereas FAN/TAN in aerobic liquid composting was about 7.9 times higher than that of agitation type reactor. Therefore, despite the low FAN/TAN in the agitation type reactor, the nitrogen loss rate was relatively high.

• Journal of environmental and Sanitary engineering
• /
• v.18 no.3 s.49
• /
• pp.59-63
• /
• 2003

This study was carried out to get efficient of organic material removal and wastage sludge production minimized effects on the treatment of Brewhouse wastewater using aerobic RBC and curtain biological film contact process. As a results of biofilm attachment experiment aggravation of water quality due to excessive biofilm showed after every 13 days of operating times. The concentration of BOD at raw wastewater was 3800${\sim}$5300 mg/L and COD was 2300${\sim}$3100 mg/L. The average BOD of effluent was maintained 18 mg/L and average COD was 26 mg/L. The result of this experiment was wastage sludge did not almost generated.

• Microbiology and Biotechnology Letters
• /
• v.4 no.3
• /
• pp.117-121
• /
• 1976

A microbial strain capable of degrading ABS (alkyl benzene sulfonate) was isolated and identified as Pseudomonas caryophylli. During the incubation of the isolated bacterium in a synthetic effluent containing 10 ppm of ABS, the extents of removal of ABS, BOD and COD were 40％, 89％ and 71％, respectively. The degradability of ABS by pure culture with the isolated strain was twice higher than that of mixed culture with natural microflora. The biodegradability of some commercial detergents in Korea by the isolated organism was as follows: Hiti 46.2％, Kleenup 37.5％, No.1 29％, and OK 27.9％.

• Journal of Environmental Health Sciences
• /
• v.29 no.3
• /
• pp.16-20
• /
• 2003

Nitrogen(N) and phosphorus(P) in surface streams mainly lead to euthrophication. It aggravates water quality and consequently increases the purification costs. As a resolution of water contamination caused by household drainage through irrigation route by 70% of the 1,300 community residents in Eum-Am Myun, Seo-San city, was implemented biological self-purification method by growing Oenanthe Javanica along the polluted water tunnel. The contaminated water was efficiently purified after passing the dropwort field; DO conc. of effluent water was increased 8.3∼61.9% after through the drop wort field. HRT of experiment system was changed 0.05∼1.50/day. 50% of BOD was eliminated at the range above 12 mg/l of Influent BOD conc. Also, 50% of COD was eliminated at the range above 30 mg/l of Influent COD conc. Finnally, the influent T-N loading at range below 1.5 g/m$^3$/d reduced 50% of Influent T-N conc., and so did influent T-P loading at the range below 0.03 g/m$^3$/dwas reduced 50% of Influent T-P conc.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.33 no.3
• /
• pp.44-51
• /
• 2001

Sedimentation characteristics such as SS, $BOD_5$, COD removal efficiency of waste water in the toilet paper mill using milk carton were examined. Optimum dosage of coagulant, rapid mixing time and slow mixing time were determined by turbidity, SS, COD, $BOD_5$ and then equation for treatment efficiency was suggested. Mechanical strength of floc was determined by turbidity. For the coagulant, polyacrylamide (PAM) is more efficient for removing pollution than the aluminium sulfate. Effective mixing ratios of PAM and aluminum sulfate to remove pollution are 70:30 and 30:70. The lowest turbidity was showed when rapid mixing at 300 rpm after coagulant injection was applied. That which indicates the highest point of flocs mechanical strength.

• Journal of the Korean Chemical Society
• /
• v.58 no.2
• /
• pp.198-204
• /
• 2014

In this present study, bagasse based pulp and paper industry wastewater was treated under different operating conditions such as initial pH (6-8), temperature ($25-35^{\circ}C$) and contact time (3-7 days) by using Bacillus subtilis. Response surface methodology (RSM) coupled with Box-Behnken response surface design (BBD) was employed to investigate the effect of process variables on the responses such as turbidity, biological oxygen demand (BOD) and chemical oxygen demand (COD) removal. The experimental data were analyzed by Pareto analysis of variance (ANOVA) and the second order polynomial models were developed. Interactive effects of the process variables on the responses were studied using plotting 3D response surface contour graph and the optimum process conditions were found to be: initial pH of 7, temperature of $30^{\circ}C$ and contact time of 5 days. Under these conditions, removal efficiencies of turbidity, BOD and COD were found to be 85%, 93% and 80% respectively which are close agreement with real experiments. These results indicate that the treatment of bagasse based pulp and paper industry wastewater using Bacillus subtilis is an effective and novel technique.