• Title/Summary/Keyword: BOD$_{5}$

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Removal of Color and non-biodegradable organic matter from biologically treated effluent by coagulation. (응집에 의한 생물학적 처리수의 색도 및 난분해성 유기물 제거)

  • Seo, Tae-Gyeong;Park, Sang-Min;Park, No-Baek;Jeon, Hang-Bae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.859-863
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    • 2008
  • 축산폐수, 침출수 등의 고농도 폐수를 생물학적으로 처리할 경우 최종 방류수는 강한 색도를 띠며 고분자량의 유기물질을 다량 함유한다. 이는 생물학적으로 분해하기 어려운 유기성 복합체와 생화학적 반응에 의한 중간생성물로 색도를 띠는 천연유기물질(NOM)을 포함한다. 생물학적 처리수의 색도는 심미적인 불안감, 방류수역의 수질오염 및 공중보건상의 잠재적 위해성을 갖는다. 또한, 수자원 이용측면에서 정수처리공정에서의 약품투입량 증가와 특히, 소독부산물 생성이라는 잠재적 문제점이 뒤따른다. 따라서 이러한 문제점을 해소하기 위한 생물학적 2차 처리수의 후속처리가 요구되며, 실제로 난분해성 유기물과 색도를 제거하기 위한 흡착, 막 분리, 고급산화(AOP) 및 화학적 응집 등의 물리-화학적 공정에 대한 연구가 수행되어왔다. 특히, 화학적 응집은 무기응집제 또는 고분자중합체(Polymer)를 이용하여 콜로이드성 입자와 색도를 띠는 난분해성 유기물을 전기적 불안정화를 유도함으로서 흡착 및 응집과정을 통해 제거하는 공정으로 많은 연구자들에 의해 연구되어왔다. 그러나 난분해성 유기물과 색도제거는 대상원수의 성상과 화학적 특성 등에 따라 각각의 제거효율과 최적 운전조건이 상이하게 나타난다. 화학적 응집공정은 비교적 높은 제거효율을 보이지만, 운전 및 유지관리의 기술적 어려움, 경제적 비효율성 등으로 인하여 적용에 어려움을 겪고 있는 실정이다. 본 논문에서는 생물학적 혐기-호기성 공정에서 방류되는 축산폐수의 2차 처리수를 대상으로 화학적 응집에 의한 색도 및 난분해성 유기물의 제거거동을 고찰하였다. 대상 처리수의 $TCOD_{Cr}$ 농도는 평균 410 mg/L인 반면, $BOD_5$는 7-15 mg/L 범위로 난분해성 유기물을 다량 함유하고 있음을 알 수 있었다. 이에 황산알루미늄(Aluminium sulfate; $Al_2(SO_4){\cdot}14H_2O$)과 염화철(ferric chloride)의 무기응집제를 이용하여 자 테스트(jar test)를 수행한 결과, 동일한 응집제 주입량에서 염화철의 유기물 제거 효율이 높은 것으로 나타났다. 황산알루미늄과 염화철의 경우 각각의 응집제 주입율 5.85mM에서 89%, 7.03mM에서 97.5%의 최대 유기물 제거효율을 보여주었으며, 이 때 최종 pH는 4.0-5.6 범위이었다. 한편, 대상 원수 내의 콜로이드성 입자 또는 용존성 유기물의 작용기(functional group)는 일반적으로 음으로 하전 되어 있어 응집에 의해 잘 제거되지 않는 특성을 가지고 있다. 따라서 과량의 응집제를 주입하여 다가의 양이온성 금속염을 흡착시켜 전기적으로 중화시키고, 생성된 침전성 수화물 내에 포획 또는 여과시켜 제거하게 된다. 이 때, 금속염 수화종의 전하밀도가 응집효율에 영향을 주는 것으로 알려져 있는데, 다가의 양이온은 전기적 이중층(Double layer) 압축에 의한 불안정화를 향상시킬 수 있기 때문에다. 또한, 2가 금속염은 색도유발물질과 흡착하여 humate 또는 fulvate 등의 착화합물(complex)을 형성시켜 응집효율을 향상시킬 수 있다. 따라서 본 연구에서는 생물학적 2차 처리수의 화학적 응집처리에 있어서 알루미늄염 등의 다가이온 첨가가 응집에 미치는 영향을 관찰하고, 후속되는 플록형성 및 침전공정에 의한 제거효율을 비교, 평가함으로써 2차 처리수로부터 난분해성 유기물과 색도를 보다 효과적이고 경제적으로 제거할 수 있는 최적인자를 도출하고자 하였다.

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Evaluation of Algal Growth Limiting Factor in the Nakdong River by MBOD Method (MBOD법에 의한 낙동강의 조류증식 제한인자 추정)

  • Song, Kyo-Ook;Seo, In-Suk;Shin, Sung-Kyo;Lee, Suk-Mo;Park, Chung-Kil
    • Journal of Environmental Science International
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    • v.4 no.5
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    • pp.83-83
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    • 1995
  • The increase of population and industrial activities had brought into eutrophication in the Nakdong river. A remarkable acceleration of eutrophication brought about serious problems for water supply. Therefore, for the purpose of conservation of water quality in the Nakdong river it is necessary to control nutrients. MBOD method was use to evaluate algal growth limiting factor and algal growth potential in the Nakdong river from June to August 1994. The modified biochemical oxygen demand(MBOD) depends on the amount of available inorganic nutrient and organic substrate during 5 day incubation in the dark at 20$^{circ}C$. The MBOD assay depends on inorganic nutrients such as P and N as well as reduced carbon and called the MBOD, the MBOD-P, and the MBOD-N, respectively. The results of bioassay by MBOD(Modified BOD) method showed that the MBOD, MBOD-P and MBOD-N value were found to be in the ranges of 3.8∼96.0 mg$O_2$/l, 5.6∼94.0 mg$O_2$/l and 42.0∼220 mg$O_2$/l, respectively. And the the bioassay value was found to be the highest in Koryong area and the lowest in Waekwan area throughout the Nakdong river. The variations of MBOD-P and MBOD-N value showed similar tendencies to the variations of phosphorus and nitrogen value, respectively. By MBOD method, the relationships of MBOD, MBOD-P and MBOD-N value were MBOD ≒ MBOD-P 《 MBOD-N. The MBOD value was nearly equal to the MBOD-P value, and the MBOD-N value was 3 to 20 times more than the MBOD-P value, approximately. Therefore, in the Nakdong river, phosphorus was the limiting factor for algal growth during summer season. The algal growth potential as the concentration of chlorophyll-a in the summer was maximum 5 times more than standing crop as it.

Seasonal Variations in Nutrients and Principal Ions Contents of the Han River Water, and its Water Characteristics (한강의 영양염류 및 주요이온류의 년변화와 그 수질적고찰)

  • Choe, Sang;Chung, Tai Wha;Kwak, Hi-Sang
    • 한국해양학회지
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    • v.3 no.1
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    • pp.26-38
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    • 1968
  • Nutrients and principal ions contents in downstream water of the Han River, near Seoul, measured at somewhat three week intervals over a period of two years were shown its characteristic seasonal cycles. The annual ranges of nutrients were 0.5-7.7 $\mu\textrm{g}$ at/L of ammonia, 0.12-0.90 $\mu\textrm{g}$ at/L of nitrite, 2.9-35.9 $\mu\textrm{g}$ at/L of nitrate, 8.8-42.0 $\mu\textrm{g}$ at/L of tatal soluble nitrogen, 0.09-0.57 $\mu\textrm{g}$ at/L of phosphorus, and 3.0-15.3 mg/L of silicate, and these were lower in spring and fall closely correlate with phytoplankton blooms and higher in winter except ammonia and silicate contents. Annual variations of BOD and COD were 0.10-2.14 ml/L, 0.88-6.82 mg/L, respectively. The ionic concentrations of Cl, Ca and Mg were not high of which Cl 5.0-13.1 mg/L, Ca 3.7-9.1 mg/L and Mg 1.5-10.4 mg/L of annual ranges. Fe ranged 18.5-82.8 $\mu\textrm{g}$/L, Mn 15-58 $\mu\textrm{g}$/L, Cu 0.3-4.7 $\mu\textrm{g}$/L annually In general, the Han River water is low in nutrients, mineral contents, and may be said not yet polluted, excellent quantity and quality of river water.

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Analysis of Water Quality Characteristics According to Short-term Fluctuation of Water Level in the New Dam: Focused on the Upstream Watershed of Yeongju Multipurpose Dam (신규 댐 건설 전후의 수질변동 분석: 영주댐 상류유역을 중심으로)

  • Lee, Saeromi;Park, Jae Roh;Hwang, Tae Mun;Ahn, Chang Hyuk
    • Journal of Korean Society on Water Environment
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    • v.36 no.5
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    • pp.431-444
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    • 2020
  • The relationship between dam construction and water quality has recently come to be considered an important issue. A dam is a physical factor which causes changes to the river system around it. Considering these points, this study was conducted to obtain basic data by analyzing the relationship between water level fluctuations and water quality parameters in the short-term. In terms of methodology, the new construction of the Yeongju Dam (M5) in 2016 was divided into Stage 1 as the lotic system and Stage 2 as the lentic system, with four years in each period, and the water level fluctuations and water quality were analyzed using official data. As a result of this study, M5, a stagnant area in which organic matter and nutrients accumulate, was found to be an important factor in water quality management. In addition, the water level changed rapidly (0.9±0.2 m → 10.9±7.1 m) as the river environment condition was converted from the lotic system to the lentic system. In addition, water quality parameters such as BOD, COD, TOC, and Chl-a significantly changed in the short-term. Further, since the transport of organic matter and nutrients occurred well in the lotic system, sedimentation was expected to be dominant in the lentic system. Therefore, it was determined that when the river flow is blocked, autochthonous organic matter is an important factor for long-term water quality management in the future. This process can increase the trophic state of the water body. As a result of this study, the TSIKO value was converted from mesotrophic in Stage 1 to eutrophic in Stage 2. Eventually, short-term changes in the river environment will affect not only changes in water level but also changes in water quality. Thus, a comprehensive and strategic approach is needed for long-term water quality management in the future.

Vertical Flow Zeolite-Filled Reed Bed with Intermittent Feeding for Sewage Treatment (수직 흐름 제올라이트 갈대 여과상에 의한 생활하수 처리)

  • Seo, Jeoung-Yoon
    • KSBB Journal
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    • v.22 no.2
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    • pp.102-108
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    • 2007
  • A sewage was treated using a vertical flow zeolite-filled reed bed. The sewage from the student dormitory of Changwon National University was fed into the reed bed for 10 minutes every 6 hours at the hydraulic load of $314L/m^3{\cdot}$day. The filtering height of the reed bed was 100 em and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolite: 0.5$\sim$1 mm and 1$\sim$3 mm in diameter. Annual average removal efficiency was 88 89.9%, $COD_{Cr}$ 86.1 %, $COD_{Mn}$ 81.2%, T-N 34.0%, $NH_4^+$-N 97.3% and T-P 34.6%. T-N of effluent was mostly $NO_3^-$-N and the concentration of $NO_2^-$-N in effluent was lower than 0.1 mg/L. All removal efficiencies did not show a remarkable seasonal change. The ranking of phosphorous fractions fixed to the zeolite in column test was Ca-P > Fe-P > reductant soluble Fe-P > occluded P > saloid P > AI-P at all depths of the filter. All phosphorous fractions except for AI-P reduced at deeper filter layer, while their content ratios increased at deeper filter layer. Organic matter content was the highest at the highest layer (0$\sim$5 cm from the top of the filter) and only small differences were observed at the deeper filter layer than 5 em from the top. Organic matter content increased at all depths of the filter with the operating time.

A Study on the establishment of an evaluation system for the implementation of National Comprehensive Nonpoint Source Pollution Management Plan (비점오염원 관리 종합대책 이행평가체계 마련 연구)

  • Lee, Hyunji;Kang, Moon Seong;Kim, Jihye;Kim, Seok Hyeon;Kwak, Jihye;Kim, Sinae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.506-506
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    • 2022
  • 비점오염원에서 배출되는 오염부하량(BOD, T-P)은 점오염원의 2배 이상을 차지하고 있어 비점오염원 관리에 대한 관심이 증대되고 있다. 이에 비점오염원의 효율적 관리를 위한 전략 및 추진과제 마련을 위해 제1차('04-'11), 제2차('12-'20) 비점오염원 관리 종합대책(이하 종합대책)이 수립 및 이행되었다. 이어 2016년 물환경보전법 개정에 따라 종합대책의 수립이 법제화되고 지난 2020년 말 제3차 비점종합대책('21~'25)이 수립되었다. 제3차 비점종합대책은 수질개선이 체감되는 비점오염원 관리라는 비전을 가지며 도시, 농·축산, 산림, 관리기반의 4개 분야에 총 71개의 세부 추진과제를 제시하고 있다. T-P 비점오염배출부하량 5% 감축, 불투수율 감축, 비점오염관리지역개소 확대, 고랭지 흙탕물 관리지역 구역 확장, 지역 거버넌스 구축을 대책의 목표와 각 분야별 관리지표로 제시하고 있다. 물환경보전법 제53조의5와 동법 시행령 제75조의3에 따라 환경부장관은 매년 이행사항을 점검 및 평가하여 그 결과를 비점오염원 관리 정책의 수립 및 집행에 반영해야 한다. 지난 제1·2차 대책의 경우 성과 점검 및 관리를 위한 체계가 부재하여 사업의 실효성 확보에 한계가 있었으며 이에 따라 소관별 이행사항 점검 및 평가체계의 필요성이 제기되었다. 따라서 본 연구에서는 종합대책 이행평가 전략 및 세부 추진체계를 마련하여 효율적인 소관별 이행사항 점검 및 평가를 도모하고자 하였다. 분야별 세부 추진과제는 매년, 대책의 목표와 각 분야별 관리지표는 대책 시행 후 5차년에 점검 및 평가할 수 있도록 구성하였다. 또한 종합대책의 최종 목표 달성 시뮬레이션을 통해 5차년 이후 원활한 평가가 이루어질 수 있도록 하였다. 본 연구에서 마련한 이행평가 체계를 통해 적절한 이행평가 및 효율적인 비점오염원 관리를 도모할 수 있을 것으로 사료된다.

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Environmental Changes after Timber Harvesting in (Mt.) Paekunsan (백운산(白雲山) 성숙활엽수림(成熟闊葉樹林) 개벌수확지(皆伐收穫地)에서 벌출직후(伐出直後)의 환경변화(環境變化))

  • Park, Jae-Hyeon
    • Journal of Korean Society of Forest Science
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    • v.84 no.4
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    • pp.465-478
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    • 1995
  • The objective of this study was to investigate the impacts of large-scale timber harvesting on the environment of a mature hardwood forest. To achieve the objective, the effects of harvesting on forest environmental factors were analyzed quantitatively using the field data measured in the study sites of Seoul National University Research Forests [(Mt.) Paekunsan] for two years(1993-1994) following timber harvesting. The field data include information on vegetation, soil mesofauna, physicochemical characteristics of soil, surface water runoff, water quality in the stream, and hillslope erosion. For comparison, field data for each environmental factor were collected in forest areas disturbed by logging and undisturbed, separately. The results of this study were as follows : The diversity of vegetational species increased in the harvested sites. However, the similarity index value of species between harvested and non-harvested sites was close to each other. Soil bulk density and soil hardness were increased after timber harvesting, respectively. The level of organic matter, total-N, avail $P_2O_5$, CEC($K^+$, $Na^+$, $Ca^{{+}{+}}$, $Mg^{{+}{+}}$) in the harvested area were found decreased. While the population of Colembola spp., and Acari spp. among soil mesofauna in harvested sites increased by two to seven times compared to those of non-harvested sites during the first year, the rates of increment decreased in the second year. However, those members of soil mesofauna in harvested sites were still higher than those of non-harvested sites in the second year. The results of statistical analysis using the stepwise regression method indicated that the diversity of soil mesofauna were significantly affected by soil moisture, soil bulk density, $Mg^{{+}{+}}$, CEC, and soil temperature at soil depth of 5(0~10)cm in the order of importance. The amount of surface water runoff on harvested sites was larger than that of non-harvested sites by 28% in the first year and 24.5% in the second year after timber harvesting. The level of BOD, COD, and pH in the stream water on the harvested sites reached at the level of the domestic use for drinking in the first and second year after timber harvesting. Such heavy metals as Cd, Pb, Cu, and organic P were not found. Moreover, the level of eight factors of domestic use for drinking water designated by the Ministry of Health and Welfare of Korea were within the level of the first class in the quality of drinking water standard. The study also showed that the amount of hillslope erosion in harvested sites was 4.77 ton/ha/yr in the first year after timber harvesting. In the second year, the amount decreased rapidly to 1.0 ton/ha/yr. The impact of logging on hillslope erosion in the harvested sites was larger than that in non-harvested sites by seven times in the first year and two times in the second year. The above results indicate that the large-scale timber harvesting cause significant changes in the environmental factors. However, the results are based on only two-year field observation. We should take more field observation and analyses to increase understandings on the impacts of timber harvesting on environmental changes. With the understandings, we might be able to improve the technology of timber harvesting operations to reduce the environmental impacts of large-scale timber harvesting.

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Recovery and Utilization of Proteins and Lipids from Washing Wastewater in Marine Manufacture by Isoelectric Point Precipitation Method 1. The Coagulation Treatment for Washing Wastewatfr of Minced Mackerel Meat (수산가공공장 폐액의 등전점 침전처리에 의한 유용성분 재회수 이용 1. 고등어 육 고기풀 제조시 발생되는 폐액의 처리장치 개발)

  • 서재수;조순영
    • KSBB Journal
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    • v.10 no.1
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    • pp.1-8
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    • 1995
  • A lot of water soluble proteins and lipids are released from minced mackerel meat and lost into the washing waste during the leaching process of Kamaboko or surimi manufacture. The removed proteins and lipids are not only an edible things but also a big burden for treating the wastewater. In order to recover the proteins from the effluent and to use as food stuff, the "pH-shifting" treatment, a modified isoelectric point precipitation method, was tried. This method is based on a myogen-aggregation phenomenon, which occurs when a solution of sarcoplasmic proteins is acidified or alkalified beyond the critical pH zone of 2∼3 or 12∼13 respectively and then neutralized. The maximum amount of precipitation was obtained by shifting the pH of the wastewater from original pH to isoelectric point (pH 4) or alkali pH 12 and then changing to neutral pH. The precipitates were easily collected by filteration or centrifuging at 10,000rpm. The oils which were only floating in the washing wastewater are easily recovered by seperating with oil separator after pouring. The recovered proteins were slightly denaturated during this pH shifting precipitation process, while the composition of amino acids was good balance as a food.

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Investigation of Microbiological and Physiochemical Quality for Irrigation Water used in Napa Cabbage Cultivation (배추 재배에 이용되는 농업용수의 미생물 오염도 조사 및 이화학성분 분석)

  • Yun, Bohyun;Kim, Min Kyung;Ryu, Jin Hee;Kim, Won-Il;Park, Byeong-Yong;Kim, Hyun-Ju;Lee, Seung-Don;Kim, Se-Ri
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.396-403
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    • 2017
  • The purpose of this study was to investigate water quality for irrigation water used in Napa cabbage cultivation. The water samples were analyzed for physiochemical and microbiological quality for a total of 111 samples including surface water (n = 75) and groundwater (n = 36) collected from five different regions where Napa cabbage is massively grown. As a conclusion, the levels of fecal indicators for surface water were higher than those for groundwater. The numbers of coliform from surface water and groundwater were 1.96-4.96 and 0-3.98 log MPN/100 mL, respectively. Enterococci were detected in 95% (72/75) of surface water samples and 22% (8/36) of groundwater samples. Besides, 97% (73/75) of surface water samples were observed being contaminated with Escherichia coli, and 22% (8/36) of groundwater sample was positive for E. coli. In the case of surface water, E. coli and coliform correlate to T-P, and enterococci showed relevance to the suspended solid (SS) and biochemical oxygen demand (BOD). In groundwater, fecal indicator bacteria showed relevance to the SS and chemical oxygen demand (COD). These results could be provided as fundamental date for establishing microbial standard of water used in leafy vegetables cultivation.

Dynamic Studies on the Process of the Biological Denitrification 1. Variation of Bacterial Flora in the Waste Water Treatment of Fish Meat Paste Plant (생물학적 탈질공정에 관한 동력학적 연구 1. 연제품공장 폐수처리시의 세균Flora의 변동)

  • SHIN Suk U
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.17 no.5
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    • pp.398-404
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    • 1984
  • This study was attempted to investigate variation of the bacterial flora in waste water treatment of fish meat paste plant by batch and continuous culture. The results of the experiment are as follows : 1. The removal rate of BOD in waste water treatment by activated sludge of continuous culture was above $90\%$. 2. In the process of nitric acidification of protein waste water, $NH_4-N\;and\;NO_2-N$ increased untill the lapse of 48 hours from culture, but $NO_3-N$ showed little change. 3. In activated sludge obtained from acclimation by batch culture for 10 days, bacteria good in capacity of nitric acidification were not appeared. 4. Among 120 strains of isolated bacteria, the most predominantly appeared bacterial flora were Enterobacteriaceae ($28\%$) and Pseudomonas spp. ($25\%$), In the latter term of aeration during which ammonia originates in abundance, Pseudomonas spp. was decreased but Enterobarteriaceae was increased. 5. Fifty percent of the isolated strains were able to grow in $0\%,\;3\%$ NaCl and $75\%$ artificial sea water, Therefore, it is suggested that sea water can be used as dilution water instead of tap water during the treatment of waste water.

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