• 한국도로학회논문집
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• 제16권5호
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• pp.9-18
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• 2014

PURPOSES : The objective of this study is to evaluate the applicability of the pitch, which is produced during SDA petroleum upgrading process, as a pavement paving material. In order for the purpose, the physical and chemical properties of the pitch are analyzed, and then the various plasticizers are applied in the pitch. METHODS : Two types of pitch are selected from oil refinery companies, which are owned the SDA petroleum upgrading process. Also, two types of asphalt binders, PG 64-22 and PG 58-22, are employed to compare with the pitch because these two types of asphalt binders are currently used as paving materials. For the chemical property of the pitch, the composition of SARA (Saturate, Aromatic, Resin, Asphaltene), the elementary composition, and the functional group are analyzed. For the physical property of the pitch, the basic material property tests, such as penetration test, softening point test, flash point test, ductility test, and rotational viscometer test, are performed. Also, the DSR (Dynamic Shear Rheometer) test and the BBR (Bending Beam Rheometer) test are conducted using asphalt binder specimens obtained by both short term aging (Rolling Thin Film Oven, RTFO) and long term aging (Pressure Aging Vessel, PAV) processes. The rheological property of each pitch type is evaluated as a function of temperatures and loading cycles. PG 64-22 asphalt binder is used as a control material. RESULTS AND CONCLUSIONS : The Pitch may not be suitable for the pavement paving material without modifications, but the pitch can be used as alternatives of modified addictive or asphalt. If low molecular component, such as saturate and aromatic components, are added in the pitch based on the development of various plasticizers, it has a strong possibility for the pitch to be used as a alternative. However, in order to verify the performance property of the pitch, further research is needed.

• 한국도로학회논문집
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• 제17권6호
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• pp.55-63
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• 2015

PURPOSES : The objective of this study is to investigate the properties of recycled asphalt binders with five different rejuvenators, in order to evaluate the applicability of the recycled asphalt binders compared with the original asphalt binder. METHODS : In order to simulate recycled asphalt binders, fresh asphalt binders are aged by various Superpave aging procedures, such as the rolling thin-film oven (RTFO) and the pressure aging vessel (PAV). Then, selected rejuvenators are added to the aged asphalt binders in the amount of 5%, 10%, and 15%. The asphalt binder properties are evaluated by the dynamic shear rheometer (DSR), the rotational viscometer (RV), and the bending beam rheometer (BBR). In this study, AP-5 (penetration grade 60-80, PG 64-16) asphalt binder is used. A total of five types of rejuvenators are employed. RESULTS AND CONCLUSIONS : When considering aged asphalt without a new asphalt binder, it seems that the percentage of rejuvenator used in Korea is a bit too low, and that it fails to possess the characteristics of the original binder. From the current practice of evaluating the properties of recycled binder based on penetration ratio only, the amount of rejuvenator required is similar for the long-term-aged binder, but is excessive for the longest-term aged binder, causing deterioration of workability and stiffness of the recycled binder.

• Journal of the Korean Data and Information Science Society
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• 제21권4호
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• pp.669-679
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• 2010

지역교육청 수요자 만족도조사를 위한 표본설계는 경상남도의 2009년 경남지역교육청 고객만족도 조사의 표본크기에 기초하여 시 군별 지역교육청평가에 맞추어 설계하였다. 대도시의 구단위 지역 교육청과 달리 지방의 시 군 교육청은 학생수와 학교수, 학급당 학생수 등의 변동이 크다. 시간 비용 등을 고려하여 전체 표본크기를 작게 하면서도 각 시 군 교육청 평가에 필요한 최소표본수를 확보하도록 설계하였다. 경상남도는 10개의 시지역과 10개의 군지역을 가지고 있고, 학생수가 상대적으로 작은 군지역교육청 평가에 필요한 최소표본수를 확보하기위해 지역별 평가에 필요한 최소표본을 우선배분한 후, 나머지는 지역별 학급수에 비례배분하였고, 표본학교는 지역과 학교설립유형별로 층화하여 학급수에 비례하여 추출하였다. 표본학교 내에서 조사대상 학생은 2단집락추출하였다. 지역별 추출율의 상이함을 보정하기 위해 가중치를 산정하였다. 조사자료의 분석은 가중치를 적용하여 가중평균, 가중총합 등을 이용하며, 분산의 추정은 통계소프트웨어에서 제공하는 균형반복복제, 잭나이프, 선형화방법 등을 사용할 수 있다.

• 한국지역지리학회지
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• 제13권3호
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• pp.235-253
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• 2007

본 연구에서는 우리나라 7대 대도시를 대상으로 지속가능발전성을 비교 평가하였다. 국가지속가능발전지표 목록 등을 참고하여 3개 부문, 14개 지표군, 42개 하위지표를 선정하여 정량적 지표체계를 구축하였다. 대도시간 비교분석을 위해 지표별로 7대 대도시의 평균값을 기준으로 지속가능성을 상대평가 하였으며, 이 때 필요시 역기능지표를 순기능 지표화 하여 모든 지표를 동일한 스케일로 비교 가능하도록 하였다. 그 결과 서울이나 울산과 같이 특정산업이 집중한 도시에서 경제적 지속가능성이 높았으나 환경적 지속가능성은 낮았고, 지역경제가 낙후된 광주에서 환경적 지속가능성이 높은 것으로 나타났다. 부산, 대구, 인천은 전반적으로 지속가능성이 낮은 반면, 대전은 3개 부문 모두에서 조화롭게 지속가능성이 높아 대도시 중 통합적 지속가능성이 제일 높은 것으로 나타났다.

• Journal of Microbiology and Biotechnology
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• 제20권11호
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• pp.1491-1499
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• 2010

Rhizosphere microorganisms possessing phytase activity are considered important for rendering phytate-phosphorus (P) available to plants. In the present study, the Citrobacter braakii phytase gene (appA) was overexpressed in rhizobacteria possessing plant growth promoting (PGP) traits, for increasing their potential as bioinoculants. AppA was cloned under the lac promoter in the broadhost-range expression vector pBBR1MCS-2. Transformation of the recombinant construct pCBappA resulted in high constitutive phytase activity in all of the eight rhizobacterial strains belonging to genera Pantoea, Citrobacter, Enterobacter, Pseudomonas (two strains), Rhizobium (two strains), and Ensifer that were studied. Transgenic rhizobacterial strains were found to display varying levels of phytase activity, ranging from 10-folds to 538-folds higher than the corresponding control strains. The transgenic derivative of Pseudomonas fluorescens CHA0, a well-characterized plant growth promoting rhizobacterium, showed the highest expression of phytase (~8 U/mg) activity in crude extracts. Although all transformants showed high phytase activity, rhizobacteria having the ability to secrete organic acid showed significantly higher release of P from Ca-phytate in buffered minimal media. AppA overexpressing rhizobacteria showed increased P content, and dry weight (shoot) or shoot/ root ratio of mung bean (Vigna radiata) plants, to different extents, when grown in semisolid agar (SSA) medium containing Na-phytate or Ca-phytate as the P sources. This is the first report of the overexpression of phytase in rhizobacterial strains and its exploitation for plant growth enhancement.

• Current Photovoltaic Research
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• 제3권3호
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• pp.80-84
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• 2015

We suggest new emitter formation method using solid-phase epitaxy (SPE); solid-phase epitaxy emitter (SEE). This method expect simplification and cost reduction of process compared with furnace process (POCl3 or BBr3). The solid-phase epitaxy emitter (SEE) deposited a-Si:H layer by radio-frequency plasma-enhanced chemical vapor deposition (RF-PECVD) on substrate (c-Si), then thin layer growth solid-phase epitaxy (SPE) using rapid thermal process (RTP). This is possible in various emitter profile formation through dopant gas ($PH_3$) control at deposited a-Si:H layer. We fabricated solar cell to apply solid-phase epitaxy emitter (SEE). Its performance have an effect on crystallinity of phase transition layer (a-Si to c-Si). We confirmed crystallinity of this with a-Si:H layer thickness and annealing temperature by using raman spectroscopy, spectroscopic ellipsometry and transmission electron microscope. The crystallinity is excellent as the thickness of a-Si layer is thin (~50 nm) and annealing temperature is high (<$900^{\circ}C$). We fabricated a 16.7% solid-phase epitaxy emitter (SEE) cell. We anticipate its performance improvement applying thin tunnel oxide (<2nm).

• Bulletin of the Korean Chemical Society
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• 제14권2호
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• pp.266-271
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• 1993

The reaction of $(CO_5$)M=C(OMe)Tol (M=Cr, Mo, W and $Tol=p-C_6H_4Me)$ and $BBr_3$ followed by treatment with tetramethylethylenediamine (TMEDA) yields a mixture of two diastereomers, trans, $cis-Br(CO)_2(tmeda)M{\equiv}$CTol [M=Cr(1a), Mo(2a), W(3a)] and cis, $trans-Br(CO)_2(tmeda)M{\equiv}$CTol [M=Cr(1b), Mo(2b), W(3b)], respectively. These compounds have been isolated as crystalline solids and characterized by spectroscopic (infrared, mass, $^1H$ and $^{13}C-NMR)$ data. The trans, cis-Br(CO)2(tmeda)Cr${\equiv}$CTol (1a), has been examine via a single crystal X-ray diffraction study : $BrCrO_2N_2C_{16}H_{23}$, Mr=407.27, triclinic, $P{\bar{1}},\;a=12.792(2),\;b=13.400(5),\;c= 11.645(4)\;{\AA},\;{\alpha}=101.26(2)^{\circ},\;{\beta}=103.04(2)^{\circ},\;{\gamma}=91.88(2)^{\circ},\;{\nu}=1907(1){\AA}^3,\;Z=2,\;{\rho}(calcd)=1.418\;gcm^{-3},\;{\lambda}(MoK{\alpha})=0.71069\;{\AA},\;{\mu}=26.25 cm^{-1},\;F(000)=831.97,\;T=295K,\;R=0.0977$ for 1332 significant reflections $[F_0>5{\sigma}(F_0)]$. There are two essentially equivalent molecules in the crystallographic asymmetric unit. Each molecule is octahedral with the bromide ligand trans to the alkylidyne carbon, the two cis-carbonyl ligands, and the bidentate TMEDA ligand.

• 한국도로학회논문집
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• 제9권2호
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• pp.51-62
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• 2007

최근 국내에서는 교면포장의 파손에 따른 교량 바닥판의 열화 및 운전자 안정성의 문제가 대두되고 있다. 기존 아스팔트 재료는 교량에서 발생하는 열악한 환경에 적용하기에는 한계가 있어 교량 바닥판을 보호하고 상대적으로 큰 처짐에 대하여 장기간 견딜 수 있는, 피로저항성이 우수한 고내구성 교면포장 아스팔트 혼합물의 개발이 필요하게 되었다. 이에 SBS 첨가물과 첨가제를 사용하여 생산성 및 작업성이 우수하고 피로균열저항성이 뛰어난 교면포장용 아스팔트 바인더를 개발하였다. 새로운 아스팔트 바인더는 회전점도시험 (RV test), 인화점시험 (Flash point test), 동적전단시험(DSR test), 저온빔시험(BBR test) 등을 통하여 PG 70-34의 공용등급으로 확인되었다. 본 연구에서 개발된 아스팔트 바인더를 사용한 혼합물의 공용성을 평가하기 위하여, 피로시험, 휠트래킹시험, 수분손상시험 등을 실시하였으며 실물크기의 윤하중시험을 통하여 소성변형 저항성 및 피로균열 저항성에 대하여 평가하였다. 실내공용성 시험을 통하여 교면포장용 아스팔트 혼합물이 SBS 개질 혼합물에 비하여 3배 이상의 피로수명을 가졌다. 또한, 윤하중시험에서도 소성흐름이 발생하지 않았고, 피로균열은 250,000회 이상을 재하하여도 PG 64-22 혼합물의 38% 밖에 나타나지 않았다.