• 전기화학회지
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• 제4권3호
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• pp.98-103
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• 2001

EDLC(electric double layer capacitor)용 활성탄소전극의 제조공정을 dip coating method, doctor blade coating method, paste rolling method로 달리하여 전기화학적 특성과 비축전 용량을 조사하였다. Dip coating method에 의한 전극제조시 전해질염으로 LiPF6를 이용하고 유기용매로 PC-DEC를 이용한 EDLC의 비축전 용량이 130F/g으로 가장 우수하였고, 선형의 시간전압곡선에서의 IR-drop도 0.11V로 작았으며 CV(cyclic voltammetry) 분석 또한 이상적인 EDLC의 특성을 나타내었다.

• Journal of Magnetics
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• 제21권2호
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• pp.286-292
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• 2016

This study evaluates the change of computer tomography (CT) number in the case of the metal artifact reduction (MAR) algorithm, using the phantom. The images were obtained from dual CT using a gammex 467 tissue characterization phantom, which is similar to human tissues. The test method was performed by dividing pre and post MAR algorithm and measured CT values of nonmagnetic materials within the phantom. In addition, the changes of CT values for each material were compared and analyzed after measuring CT values up to 140 keV, using the spectral HU curve followed by CT scan. As a result, in the cases of N rod (trabecular bone) and E rod (trabecular bone), the CT numbers decreased as keV increasing but were constant above 90 keV. In the cases of I rod (dense bone) and K rod (dense bone), the CT numbers also decreased as keV increased but were uniform above 90 keV. The CT numbers from 40 keV to 140 keV were consistent in the cases of J rod (liver), D rod (liver), L rod (muscle), and F rod (muscle). For A rod (adipose), G rod (adipose), B rod (breast) and O rod (breast), the CT numbers increased as keV increased but were constant after 90 keV. The CT numbers from 40 keV to 140 keV were consistent in the cases of C rod (lung (exhale)), P rod (lung (exhale)), M rod (lung (inhale)) and H rod (lung (exhale)). Conclusively, because dual CT exhibits no changes in image quality and is able to analyze nonmagnetic materials by measuring the CT values of various materials, it will be used in the future as a useful tool for the diagnosis of lesions.

• The Plant Pathology Journal
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• 제36권6호
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• pp.558-569
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• 2020

Fusarium head blight (FHB) is a devastating fungal disease of wheat (Triticum aestivum L.). The lack of genetic resources with stable FHB resistance combined with a reliable and rapid screening method to evaluate FHB resistance is a major limitation to the development of FHB resistant wheat germplasm. The present study utilized an immature wheat spike culture method to screen wheat spike culture derived variants (SCDV) for FHB resistance. Mycotoxin concentrations determined by liquid chromatography-tandem mass spectrometry (LC-MS/MS) correlated significantly (P < 0.01) with FHB severity and disease progression during in vitro spike culture. Selected SCDV lines assessed for FHB resistance in a Fusarium field disease nursery in Carman, Manitoba, Canada in 2016 showed significant (P < 0.01) correlation of disease severity to the in vitro spike culture screening method. Selected resistant SCDV lines were also crossed with an elite cv. CDC Hughes and the progeny of F₂ and BC₁F₂ were screened by high resolution melt curve (HRM) analyses for the wheat UDP-glucosyl transferase gene (TaUGT-3B) single nucleotide polymorphism to identify resistant (T-allele) and susceptible (G-allele) markers. The progeny from the crosses were also screened for FHB severity using the immature spike culture method and identified resistant progeny grouped according to the HRM genotyping data. The results demonstrate a reliable approach using the immature spike culture to screen for FHB resistance in progeny of crosses in early stage of breeding programs.

• 한국자기학회지
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• 제4권1호
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• pp.25-31
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• 1994

코발트와 철의 이온을 혼합한 산성수용액 중에서, 알루미늄 양극산화피막에 전해석출 하여 제작된 자성막은, 코발트조성이 증가함에 따라 발크합금의 경우와 마찬가지로 상전이(phase shifting) 하였다. 입자직경이 $150\;{\AA}$의 시료의 경우 조성이 25-35 at% Co에서 큰 포화자화, 고항자력, 큰 자기이방성 에너지 및 우수한 각형비 등에 기인하는 큰 자기에너지 적($BH_{max}$)이 얻어진다. 그러나 입자직경이 $450\;{\AA}$의 경우에는, 코발트가 50-70 at% 일때 초기석출부 에 강자성체인 FeC가 아주 강하게 배향하므로, 입자의 큰 형상이방성(수직자기이방성)이 없어지고 면내 방향의 자기이방성을 나타낸다. 그리고 같은 조성에서 초기석출부를 제거하여 FeC의 영향을 없앨때, 주직자기이방성이 회복되었다.

• 분석과학
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• 제37권1호
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• pp.25-38
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• 2024

The study aimed to investigate a novel approach by utilizing liquid chromatography (LC) and liquid chromatography-mass spectrometry (LC-MS) to separate, identify and characterize very nominal quantities of degradation products (DPs) of balsalazide along with its process related impurities without isolation from their reaction mixtures. The impurities along with balsalazide were resolved on spherisorb ODS2 (250×4.6 mm, 5.0 ㎛) column at room temperature using 0.2 M sodium acetate solution at pH 4.5 and methanol in the ratio of 55:45 (v/v) as mobile phase pumped isocratically at 1.0 mL/min as mobile phase and UV detection at 255 nm. The method shows sensitive detection limit of 0.003 ㎍/mL, 0.015 ㎍/mL and 0.009 ㎍/mL respectively for impurity 1, 2 and 3 with calibration curve liner in the range of 50-300 ㎍/mL for balsalazide and 0.05-0.30 for its impurities. The balsalazide pure compound was subjected to stress studies and a total of four degradation products (DPs) were formed during the stress study and all the DPs were characterized with the help of their fragmentation pattern and the masses obtained upon LC-MS/MS. The DPs were identified as 3-({4-[(E)-(4-hydroxyphenyl) diazenyl]benzoyl}amino)propanoic acid (DP 1), 4-[(E)-(4-hydroxyphenyl)diazenyl] benzamide (DP 2), 5-[(E)-(4-carbamoylphenyl)diazenyl]-2-hydroxybenzoic acid (DP 3) and 3-({4-[(E)-phenyldiazenyl]benzoyl}amino)propanoic acid (DP 4). Based on findings, it was concluded that, the proposed method was successfully applicable for routine analysis of balsalazide and its process related impurities in pure drug and formulations and also applicable for identification of known and unknown impurities of balsalazide.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 1999년도 추계학술발표회 초록집
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• pp.15-15
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• 1999

In chip plating, several parameters must be taken into consideration. Current density, solution concentration, pH, solution temperature, components volume, chip and media ratio, barrel geometrical shape were most likely found to have an effect to the process yields. The 3 types of barrels utilized in chip plating industry are the conventional rotating barrel. vibrational barrel (vibarrel), and the centrifugal type. Conventional rotating barrel is a close type and is commonly used. The components inside the barrel are circulated by the barrel's rotation at a horizontal axis. Process yield has known to have higher thickness deviation. The vibrational barrel is an open type which offers a wide exposure to electrolyte resulting to a stable thickness deviation. It rotates in a vertical axis coupled with multi-vibration action to facilitate mixed up and easy transportation of components, The centrifugal barrel has its plated work centrifugally compacted against the cathode ring for superior electrical contact with simultaneous rotary motion. This experiment has determined the effect of barrel vibration intensity to the plating thickness distribution. The procedures carried out in the experiment involved the overall plating process., cleaning, rinse, Nickel plating, Tin-Lead plating. Plating time was adjusted to meet the required specification. All other parameters were maintained constant. Two trials were performed to confirm the consistency of the result. The thickness data of the experiment conducted showed that the average mean value obtained from higher vibrational intensity is nearer to the standard mean. The distribution curve shown has a narrower specification limits and it has a reduced variation around the target value, Generally, intensity control in vi-barrel facilitates mixed up and easy transportation of components, However, it is desirable to maintain an optimum vibration intensity to prevent solution intrusion into the chips' internal electrode. A cathodic reaction can occur in the interface of the external and internal electrode. $2HD{\;}+{\;}e{\;}{\rightarrow}20H{\;}+{\;}H_2$ Hydrogen can penetrate into the body and create pressure which can cause cracks. At high intensity, the chip's motion becomes stronger, its contact between each other is delayed and so plating action is being controlled. However, the strong impact created by its collision can damage the external electrode's structure thereby resulting to bad plating condition. 1 lot of chip was divided into two equal partion. Each portion was loaded to the same barrel one after the other. Nickel plating and tin-lead plating was performed in the same station. Portion A maintained the normal barrel vibration intensity and portion B vibration intensity was increased two steps higher. All other parameters, current, solution condition were maintained constant. Generally, plating method find procedures were carried out in a best way to maintained the best plating condition. After plating, samples were taken out from each portion. molded and polished. Plating thickness was investigated for both. To check consistency of results. 2nd trial was done now using different lot of another characteristics.

• 한국항공우주학회지
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• 제42권5호
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• pp.368-375
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• 2014

지역기반 위성항법보강시스템 (GBAS : Ground Based Augmentation System)은 환경적인 요인에 많은 영향을 받기 때문에 설치 운영될 지역의 환경 요인 분석이 중요하다. 본 연구는 위성 앙각을 고려한 B-Value의 시그마 팽창을 제안하여 대립가설의 VPL (Vertical Protection Level) 성능을 분석하였다. 또한 해당지역의 환경조건을 만족하는 데이터를 수집하여 위성앙각 $5^{\circ}$ 간격의 시그마 팽창계수를 산출하였다. 산출된 결과는 위성앙각에 따라 커브피팅을 통해 함수화하여, 실험지역의 환경조건 (태양활동, 습윤 지연)에 알맞은 시그마 팽창을 제안하였다. 위성 앙각에 따른 시그마 팽창계수 분석결과 습윤 지연에 의한 영향은 미미했으나, 태양활동에 의한 영향은 태양활동이 활발할수록 시그마 팽창계수가 증가하는 것을 확인할 수 있었다. 또한, 위성 앙각을 고려한 시그마 팽창 계수의 적용으로, 기존 방법 대비 무결성 뿐만 아니라 고앙각 위성에서의 불필요한 마진 제거가 가능하여 가용성이 향상됨을 확인할 수 있었다.

• 한국자기학회지
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• 제17권2호
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• pp.60-64
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• 2007

Ba-ferrite 단결정을 제조하여 자기적 성질을 Mossbauer 분광법으로 연구하였다. 단결정 시료를 c-축 방향으로 얇게 절단하고 그 면에 감마선을 조사한 결과 결정 전체에 걸쳐 Fe 이온의 스핀 방향이 c-축과 일치함을 확인하였다. 온도에 따른 초미세자기장의 감소 추세는 입자상태와 거의 비슷하였으며 결정 내 Fe원자의 이온 상태 역시 일치하였다. 결정구조는 Magnetoplumbite로서 결정상수는 $a_0=5.892{\AA},\;b_0=5.892{\AA},\;c_0=23.198{\AA}$로 정되었으며 그 외의 다른 상은 존재하지 않는 것으로 나타났다. $M\"{o}ssbauer$ spectrum은 결정 내에 존재하는 Fe의 자리에 따라 5의 각각의 다른 subspectrum이 존재하였는데 감마선의 방향이 c-축과 일치하여 모든 자리에서 4개의 공명흡수선 만이 존재하였다. 따라서 결정의 형태는 전체적으로 단일상으로 형성되었음을 확인하였고 여분의 ${\alpha}-Fe_2O_3$ 등은 존재하지 않음을 명확히 하였다. 자기이력곡선을 통하여 실온상태에서 포화자기모멘트는 70.71 emu/g, 보자력이 320 Oe의 값으로 측정되었다.

• Journal of Preventive Medicine and Public Health
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• 제17권1호
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• pp.269-279
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• 1984

The optimum conditions for measuring cadmium content of less than 0.2ppm by flame atomic absorption spectrophotometry were investigated. The cadmium in urine was extracted by APDC-MIBK for the analysis by atomic absorption spectrophotometry after ashing them by a wet method. 1. Optimum conditions by APDC-MIBK and DDTC-MIBK extractions. The acidic aqueous solution was prepared with appropriate amount of 0.IN nitric acid, 5ml of 25% (W/V) sodium potasstum tartarate, 10ml of saturated ammonium sulfate, and 2ml of 2% APDC(or 1 ml of 5% DDTC) chelating agent. The total volume of solution was adjusted to 55 ml and pH to $2{\sim}10$ (or$7{\sim}10$). The aqueous solution was extracted with 10ml MIBK. Concentration of Triton X-100 did not effect the absorbance for APDC-MIBK extraction of cadmium, but absorbance decreased as the concentration increased for DDTC-MIBK extraction. The sensitivity and detection limits for the cadmium determination from APDC-MIBK extraction were 0.0038ppm and 0.0102, 0.0022ppm and 0.0116 for DDTC-MIBK, and 0.0132ppm and 0.0034 for 0.1N nitric acid. APDC-MIBK and DDTC-MIBK extractions were 3 times higher than 0.1N nitric acid for the sensitivity. 2. Excretion of cadmium in 24-hour urine by APDC-MIBK extraction. Determination of cadmium in urine by atomic absorption spectrophotometry of A.A. (Cd=2 mA) mode and B.C. (Cd=4 mA) mode and B.C. (Cd=4mA, $D_2=20mA$) mode showed some difference (p<0.05). The difference of cadmium determination and recovery according to method of standard additions and standard calibration curve method in urine was not significant (p>0.05, $93.48{\pm}11.78%,\;94.83{\pm}22.00%$). Excretion of cadmium in 24-hour urine collection from normal person and variance analysis within measurement variation was not significant (p>0.05), but between interindividual was significant (0.05). Determination of cadmium content by two different methods of flame atomic absorption spectrophotometry and dithizone colorimetry showed that the results from the two methods can be described by a regression line with a good correlation (y=1.0153x-0.2927, x=Cd by D.C., y=Cd by A.A.S., $r=0.8651^*$, p<0.01).

• 한국산림과학회지
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• 제34권1호
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• pp.21-30
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• 1977

일본잎갈나무는 우리나라의 주요조림수종(主要造林樹種)으로 전국각지(全國各地)에 많은 조림지(造林地)와 임분(林分)이 있다. 이 수종(樹種)의 임분밀도관리(林分密度管理)의 지침(指針)을 마련하여 생산력예측(生產力豫則), 간벌계획(間伐計劃)과 수확량(收穫量) 사정(査定)을 용이하게 하는 일은 임업기술(林業技術)의 계량적(計量的), 생태적(生態的) 및 경제적(經濟的) 관점(觀點)에 대단(大端)이 의의있는 일로 생각 되었다. 이 연구(硏究)를 위해 정상적(正常的)으로 관리(管理)되고 있든 비정상적(非正常的)으로 관리(管理)되고 있든 최근(最近)에 간벌(間伐)한 흔적이 없는 임분(林分)에서 165개(個)의 표본(標本)을 조사(調査)하여 평균수고(平均樹高), 평균직경(平均直徑) 우세목수고(優勢木樹高), ha당(當) 본수(本數)와 1평균목(平均木)의 간재적(幹材積)을 산출(算出) 하였다. 이 연구(硏究)에 특(特)히 세장도이론(細長度理論)을 새로 도입(導入) 하였다. 이 이론(理論)에 대(對)한 실험적(實驗的) 검토(檢討)는 마(馬)와 Wardle, Shantz, Harms & Colline의 밀도시험결과(密度試驗結果)를 인용(引用)하여 증명한 바 있다. 임목(林木)의 상대생장(相對生長)은 일반적(一般的)인 logistic cnrve를 인용(引用)하고 공식(公式)은 모두 $Y=a{\times}b$를 대입(代入) 하였다. 각측정인자간(各測定因子間)의 관계(關係)는 아래와 같았다. 1. 세장도별(細長度別) 수고(樹高)와 밀고(密度)와의 관계(關係)-표(表) 1과 그림2 2. 세장도별(細長度別) 직경(直徑)과 밀도(密度)와의 관계(關係)-표(表) 1과 그림3 3. 세장도별(細長度別) 수고(樹高)와 단목간재적(單木幹材積)과의 관계(關係)-표(表) 3과 그림4 4. $D^2H$와 단목(單木) 간재적(幹材積)-$Log_eV=0.9569\;Log_eD^2H-9.8431$ 5. 밀도(密度)와 간재적(幹材積)-$Log_eV=9.5026-1.6800\;Log_eD$ 6. 밀도(密度)와 간재적(幹材積)-$Log_eV_{ha}=9.4911-0.6784\;Log_eD$ 7. 세장도별(細長度別) 수고계급(首告階級)에 응대(應對)한 간재적(幹材積)-표(表) 5 8. 세장도별(細長度別) 수고계급(首告階級)에 응대(應對)한 Ha당(當) 본수(本數)-표(表) 6 9. 세장도별(細長度別) 수고계급(首告階級)에 응대(應對)한 Ha당(當) 간재적(幹材積)-표(表) 7 이상(以上)의 과정(過程)을 거쳐 일본잎갈나무 임분밀도관리도표(林分密度管理圖表)를 제작(製作)하였다(그림 9). 이 관리표(管理表)의 정확도(正確度)를 검정하기 위하여 실측치(實測値)와 추정치(推定値)와의 관계(關係)를 보니 표(表) 8의 내용과 같이 오차(誤差)가 낮은편이었다. 이 도표(圖表)는 일본잎갈나무 임분(林分)의 밀도관리(密度管理)의 지침(指針)이 되리라 생각 된다.