• Title/Summary/Keyword: B-C-N

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Corrosion Behavior of Boron-Carbon-Nitride Films Synthesized by Magnet Sputtering (스퍼터링법으로 합성한 BCN 박막의 내식성)

  • Byon E.;Son M. S.;Lee G. H.;Kwon S. C.
    • Journal of the Korean institute of surface engineering
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    • v.36 no.3
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    • pp.229-233
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    • 2003
  • Boron-Carbon-Nitrogen (B-C-N) system is an attractive ternary material since it has not only an extremely high hardness but also a number of other prominent characteristics such as chemical inertness, elevated melting point, and low thermal expansion. In this paper, the corrosion behavior of B-C-N thin films in aqueous solution was investigated B-C-N films with different composition were deposited on a platinum plate by magnetron sputtering in the thickness range of 150-280 nm. In order to understand effect of pH of solutions, $BC_{2.\;4}N$ samples were immerged in 1M HCl, 1M NaCl, and 1M NaOH solution at 298k, respectively. BCN samples with different carbon contents were exposed to 1M NaOH solutions to investigate effect of chemical composition on corrosion resistance. Corrosion rates of samples were measured by ellipsometry, From results, optical constant of $BC_{2,\;4}N$ films was found to be $N_2=2.110-0.295i$. The corrosion rates of $Bi_{1.\;0}C_{2.\;4}N_{1.\;0}$ films were NaOH>NaCl>HCl in orders. With increasing carbon content in B-C-N films, the corrosion resistance of B-C-N films was enhanced. The lowest corrosion rate was obtained for $B_{1.\;0}C_{4.\;4}N_{1.\;9}$ film.

C32-CONSTRUCTION ON Mn(κ)

  • Song, Youngkwon
    • Korean Journal of Mathematics
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    • v.12 no.1
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    • pp.23-32
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    • 2004
  • Let (B, $m_B$, ${\kappa}$) be a maximal commutative ${\kappa}$-subalgebra of a matrix algebra $M_n(\kappa)$. We will construct a maximal commutative ${\kappa}$-subalgebra (R, $m$, ${\kappa}$) of $M_n+3(\kappa)$ from the algebra B such that the algebra R has dimension greater than the dimension of B by 3. Moreover, we will show a $C_i$-construction doesn't imply a $C^3_2$-construction for $i=1,2$.

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Effects of neutron irradiation on superconducting critical temperatures of in situ processed MgB2 superconductors

  • Kim, C.J.;Park, S.D.;Jun, B.H.;Kim, B.G.;Choo, K.N.;Ri, H.C.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.9-13
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    • 2014
  • Effects of neutron irradiation on the superconducting properties of the undoped $MgB_2$ and the carbon(C)-doped $MgB_2$ bulk superconductors, prepared by an in situ reaction process using Mg and B powder, were investigated. The prepared $MgB_2$ samples were neutron-irradiated at the neutron fluence of $10^{16}-10^{18}n/cm^2$ in a Hanaro nuclear reactor of KAERI involving both fast and thermal neutron. The magnetic moment-temperature (M-T) and magnetization-magnetic field (M-H) curves before/after irradiation were obtained using magnetic property measurement system (MPMS). The superconducting critical temperature ($T_c$) and transition width were estimated from the M-T curves and critical current density ($J_c$) was estimated from the M-H curves using a Bean's critical model. The $T_cs$ of the undoped $MgB_2$ and C-doped $MgB_2$ before irradiation were 36.9-37.0 K and 36.6-36.8 K, respectively. The $T_cs$ decreased to 33.2 K and 31.6 K, respectively after irradiation at neutron fluence of $7.16{\times}10^{17}n/cm^2$, and decreased to 22.6 K and 24.0 K, respectively, at $3.13{\times}10^{18}n/cm^2$. The $J_c$ cross-over was observed at the high magnetic field of 5.2 T for the undoped $MgB_2$ irradiated at $7.16{\times}10^{17}n/cm^2$. The $T_c$ and $J_c$ variation after the neutron irradiation at various neutron fluences were explained in terms of the defect formation in the superconducting matrix by neutron irradiation.

Isolation and Properties of $\beta$-N-Acetyl-D-glucosaminidase B from Rat Uterus

  • Jung, Jin-Ha;Yang, Chul-Hak
    • Bulletin of the Korean Chemical Society
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    • v.4 no.3
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    • pp.139-143
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    • 1983
  • ${\beta}$-N-Acetyl-D-glucosaminidase B was highly purified with the following sequence of steps; DEAE-cellulose, CM-cellulose, and Sephadex G-200 gel filtration chromatograpies. The specific activity of the purified ${\beta}$ -N-acetyl-D-glucosaminidase B was 2.2 units/mg protein with 12.9 % yield and 196.2 fold purity. The purified ${\beta}$-N-acetyl-D-glucosaminidase B showed single band on polyacrylamide gel electrophoresis. The final preparation of ${\beta}$ -N-acetyl-D-glucosaminidase B was completely free friom arylsulfatase and ${\beta}$-glucuronidase. ${\beta}$ -N-Acetyl-D-glucosaminidase B had pH optimum of 4.5 in 0.5 M sodium citrate buffer. The molecular weight of ${\beta}$-N-acetyl-D-glucosaminidase B was 133,000 by Sephadex G-200 gel filtration. The Km value of ${\beta}$-N-acetyl-D-glucosaminidase B using p-nitrophenyl-N-acetyl-${\beta}$-D-glucosaminide as substrate was 1.0 mM and $V_{max}$ was 0.014 ${\mu}$ mole/min. ${\beta}$-N-Acetyl-D-glucosaminidase B was stable at $55^{circ}C$ for 70 minutes. The crude ${\beta}$ -N-acetyl-D-glucosamiinidase in 70 % ammonium sulfate retained 93 % activity after 7 months storage at -$55^{circ}C$. Bovine serum albumin, sodium chloride, and phosphate activated ${\beta}$ -N-Acetyl-D-glucosaminidase B. N-Acetyl-D-glucosamine, ${\alpha}$-methyl-D-mannoside, and acetate inhibited ${\beta}$ -N-acetyl-D-glucosaminidase B.

SOME FIXED-POINT RESULTS ON PARAMETRIC Nb-METRIC SPACES

  • Tas, Nihal;Ozgur, Nihal Yilmaz
    • Communications of the Korean Mathematical Society
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    • v.33 no.3
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    • pp.943-960
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    • 2018
  • Our aim is to introduce the notion of a parametric $N_b-metric$ and study some basic properties of parametric $N_b-metric$ spaces. We give some fixed-point results on a complete parametric $N_b-metric$ space. Some illustrative examples are given to show that our results are valid as the generalizations of some known fixed-point results. As an application of this new theory, we prove a fixed-circle theorem on a parametric $N_b-metric$ space.

THE KRONECKER FUNCTION RING OF THE RING D[X]N*

  • Chang, Gyu-Whan
    • Bulletin of the Korean Mathematical Society
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    • v.47 no.5
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    • pp.907-913
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    • 2010
  • Let D be an integrally closed domain with quotient field K, * be a star operation on D, X, Y be indeterminates over D, $N_*\;=\;\{f\;{\in}\;D[X]|\;(c_D(f))^*\;=\;D\}$ and $R\;=\;D[X]_{N_*}$. Let b be the b-operation on R, and let $*_c$ be the star operation on D defined by $I^{*_c}\;=\;(ID[X]_{N_*})^b\;{\cap}\;K$. Finally, let Kr(R, b) (resp., Kr(D, $*_c$)) be the Kronecker function ring of R (resp., D) with respect to Y (resp., X, Y). In this paper, we show that Kr(R, b) $\subseteq$ Kr(D, $*_c$) and Kr(R, b) is a kfr with respect to K(Y) and X in the notion of [2]. We also prove that Kr(R, b) = Kr(D, $*_c$) if and only if D is a $P{\ast}MD$. As a corollary, we have that if D is not a $P{\ast}MD$, then Kr(R, b) is an example of a kfr with respect to K(Y) and X but not a Kronecker function ring with respect to K(Y) and X.

The Solvent-Independent Structure of 6-(2-pyridyl)-3, 5-hexadiyn-1-ol (6-(2-pyridyl)-3, 5-hexadiyn-1-ol의 용매 비의존 분자구조)

  • 서일환;이진호
    • Korean Journal of Crystallography
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    • v.6 no.1
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    • pp.36-42
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    • 1995
  • Two types of single crystals of the title compound [6-(2-pyridyl)-3, 5-hexadiyn-ol, PyHxD] were obtained by solution of n-hexane/CH2C12 and n-hexane/Et2O, and their molecular conformations are proved identical in spite of different of space groups; C22H18N2O2 (I), Mr=343.70, Monoclinic, Pa, a=14.595(2), b=5.413(2), c=12.218(2)Å, β=96.86(1)°, V=958.3Å3, Z=2, Dx=1.19 Mgm-3, λ(MoKα)=0.71069Å, μ=0.072mm-1, F(000)=360.0, T=292K, R=0.104 for 756 unique observed reflections. An asymmetric unit contains a dimer connected by two N-H…O intermolecular hydrogen bonds. C11H9NO (II), Mr=171.85, Monoclinic, P21/a, a=14.611(2), b=5.423(6), c=12.191(2)Å, β=96.89(1)°, V=959.0Å3, Z=4, Dx=1.19 Mgm-3, λ(MoKα)=0.71069Å, μ=0.072mm-1, F(000)=360.0, T=293K, R=0.066 for 824 unique observed reflection. The structural asymmetric unit contains a molecule, but two N-H…O hydrogen bonds related by controsymmetry make the molecules form a dimer. In both structure, the dihedral angle between the planar pyridyl ring and the plane defined by C(10)-C(11)-O connected by linear diyne chain is approximately normal, and the molecules are stacked along b-axis with the unit repeat of b-axis.

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A NOTE ON DERIVATIONS OF A SULLIVAN MODEL

  • Kwashira, Rugare
    • Communications of the Korean Mathematical Society
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    • v.34 no.1
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    • pp.279-286
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    • 2019
  • Complex Grassmann manifolds $G_{n,k}$ are a generalization of complex projective spaces and have many important features some of which are captured by the $Pl{\ddot{u}}cker$ embedding $f:G_{n,k}{\rightarrow}{\mathbb{C}}P^{N-1}$ where $N=\(^n_k\)$. The problem of existence of cross sections of fibrations can be studied using the Gottlieb group. In a more generalized context one can use the relative evaluation subgroup of a map to describe the cohomology of smooth fiber bundles with fiber the (complex) Grassmann manifold $G_{n,k}$. Our interest lies in making use of techniques of rational homotopy theory to address problems and questions involving applications of Gottlieb groups in general. In this paper, we construct the Sullivan minimal model of the (complex) Grassmann manifold $G_{n,k}$ for $2{\leq}k<n$, and we compute the rational evaluation subgroup of the embedding $f:G_{n,k}{\rightarrow}{\mathbb{C}}P^{N-1}$. We show that, for the Sullivan model ${\phi}:A{\rightarrow}B$, where A and B are the Sullivan minimal models of ${\mathbb{C}}P^{N-1}$ and $G_{n,k}$ respectively, the evaluation subgroup $G_n(A,B;{\phi})$ of ${\phi}$ is generated by a single element and the relative evaluation subgroup $G^{rel}_n(A,B;{\phi})$ is zero. The triviality of the relative evaluation subgroup has its application in studying fibrations with fibre the (complex) Grassmann manifold.

Analysis of C/N Variation of Ku Band Satellite Beacon Receiver According to Rain Attenuation (강우 감쇠에 따른 Ku 대역 위성 비콘 수신기 C/N 변화 해석)

  • Park, Dae-Kil;Lee, Kyung-Soon;Koo, Kyung Heon
    • Journal of Advanced Navigation Technology
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    • v.22 no.5
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    • pp.415-419
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    • 2018
  • This paper predicts and measures the C/N ratio of a beacon signal transmitted from geostationary orbit satellite KorSat 5A ($113^{\circ}E$) at a ground station located in Kimpo. Based on the ground stations, we compared the rain attenuation of the zone K of ITU-R and the rain attenuation which analyzed the domestic weather information. In ITU-R, the Korean rainfall characteristics are classified into zone K, but forecasting the rainfall intensity and attenuation of three adjacent cities based on the cumulative rainfall data per minute from 2013 to 2017. The calculation of rainfall path and attenuation is based on ITU-R recommendations. The change of the C/N according to the rainfall amount was confirmed through the 2 week satellite beacon signal C/N measurement. The predicted critical C/N was decreased to 12 dB at $A_{0.3}$. During the experiment, it was confirmed that it decreased up to 8 dB according to the concentrated rainfall.