• 제목/요약/키워드: B$_2$O$_3$ flux

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Tb, Eu, EuTb가 치환된 가네트 단결정 막의 성장과 자기적 특성 (Growth and magnetic properties of Tb, Eu, EuTb-substituted garnet single crystal films)

  • 김근영;윤석규;정일섭;박승배;윤대호
    • 한국결정성장학회지
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    • 제14권5호
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    • pp.193-198
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    • 2004
  • $(TbBi)_3(FeAIGa)_5O_{12}(TbIG)$, $(EuBi)_3(FeAIGa)_5O_{12}(EuIG)$, $(EuTbBi)_3(FeAIGa)_5O_{12}(EuTbIG)$ 가네트 막을 $PbO-B_2O_3-Bi_2O_3$ 융제를 사용하여 $(GdCa)_3(GaMgZr)_5O_{12}(SGGG)$ 기판 위에 liquid phase epitaxy(LPE) 방법으로 성장시켰다. 성장된 TbIG, EuIG, EuTbIG 가네트 막의 포화자계값은 각각 150 Oe, 950 Oe, 170 Oe를 보였으며, magnetic force microscope(MFM) 분석을 측정 한 결과 TbIG 막에서는 단일 자구가 관찰되었으며, EuIG와 EuTbIG 막에서는 다 자구가 관찰되었다.

The flux pinning properties of BaSnO3-added GdBa2Cu3O7-δ films with varying growth conditions

  • Lee, J.K.;Oh, J.Y.;Lee, J.M.;Kang, W.N.;Kang, B.
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권3호
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    • pp.18-22
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    • 2017
  • Addition of $BaSnO_3$ (BSO) to $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) is reported to enhance the flux pinning property of GdBCO thick films. To investigate the effect of growth condition on the pinning properties, 700 nm-thick BSO-added GdBCO films deposited with varying temperatures and growth rates were prepared by using a pulsed laser deposition method. As the deposition temperature increases, the critical current density and the pinning force density show an improved field dependence up to $750^{\circ}C$ due to the increase in the formation of the a-axis growth and the BSO nanostructures. The films deposited at higher temperatures show degraded surfaces and as a result, degraded pinning behaviors. For the change in growth rate, the critical current density and the pinning force increase as the repetition rate increase at low magnetic fields, but this behavior is reversed in high magnetic fields. These results indicate that the film growth conditions significantly affect the formation of BSO nanostructures and the pinning properties of BSO-added GdBCO films.

자기 환원성 $Nb_2O_5$ 브리켓의 반응특성 연구 (Study on the Reaction Characteristics of Self-reducing $Nb_2O_5$ Briquettes)

  • 김민석;유병돈;위창현;윤덕재;최석우
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 춘계학술대회 논문집
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    • pp.333-336
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    • 2005
  • The reduction behavior of $Nb_2O_5$ in aluminum containing self-reducing briquettes(SRNB) was investigated. The time required for slag/metal equilibrium was estimated as about 20 minutes from the addition of SRNB on to the surface of molten steel. The maximum yield of Nb was expected with the slag composition of $60\%CaO-40\%Al_2O_3$. When $CaCO_3$ was used as a flux, the oxidation loss of Al by $CO_2$ should be compensated, and the chemical equivalent ratio of Al to $Nb_2O_5$ of about 1.43 was required to maximize the yield of Nb.

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동전해도금공장 Sludge로부터 동의 회수 (Recovery of Copper from Sludge of Copper Electro-Plating Plant)

  • Young-Gil Hwang;Youn-Soo Kim;Jae-Il Kim
    • 자원리싸이클링
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    • 제5권3호
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    • pp.31-36
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    • 1996
  • The metallic copper was recovered from sludge of the copper electro-plating plant by pyrometallurgical process. The reducing agent was Pyrolysized from waste tires and the flux was a mixture $Na_2CO_3$, $NaB_4O_7$, and glass. The green sludge contained 87.5% moisture and 12.5% solid with 56.5% Cu and 1.59% Fe. The sludge dried at $100^{\circ}C$ was analyized to be $Cu_4SO_4(OH)_6{\cdot}2H_2O$ and CuO by XRD analysis. The former was 84% and the latter 16%, However, the calcined sludge at $500^{\circ}C$ was 49% $Cu_2O(SO_4)$ and 51% CuO. The sludge could by smelted at $1100^{\circ}C$ for two hours with 6 to 8 moles carbon with respect to copper to produce metallic copper (>90%) with recovery of 9% above.

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Effect of additives on luminescence properties of long-persistence phosphor $SrAl_2O_4:Eu^{2+}$,$Dy^{3+}$

  • Han, Sang-Do;Singh, Krishan.C.;Gwak, Ji-Hye;Cho, Tai-Yeon;Kim, Jung-Duk;Han, Chi-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권2호
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    • pp.1512-1514
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    • 2007
  • Long afterglow $SrAl_2O_4:Eu^{2+}$,$Dy^{3+}$ is synthesized by a solid state reaction. The effect of flux $B_2O_3$ on the sintering dynamic process, the optimum concentrations of $Eu^{2+}$ and $Dy^{3+}$ for long lasting bright luminescence property and the effect of charge compensators like $Mg^{2+}$, $Zn^{2+}$, $Na^+$, $K^+$ on long persistence have been investigated.

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대면적 단결정 Gd1.5Ba2Cu3O7-y 벌크 초전도체의 초전도 특성 (Superconducting Properties of Large Single Grain Gd1.5Ba2Cu3O7-y Bulk Superconductors)

  • 김찬중;박승연;김광모;박순동;전병혁
    • 한국재료학회지
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    • 제22권11호
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    • pp.569-574
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    • 2012
  • Large single grain $Gd_{1.5}Ba_2Cu_3O_{7-y}$ (Gd1.5) bulk superconductors were fabricated by a top-seeded melt growth (TSMG) process using an $NdBa_2Cu_3O_{7-y}$ seed. The seeded Gd1.5 powder compacts with a diameter of 50 mm were subjected to the heating cycles of a TSMG process. After the TSMG process, the diameter of the single grain Gd1.5 compact was reduced to 43 mm owing to the volume contraction during the heat treatment. The superconducting transition temperature ($T_c$) of the top surface of the single grain Gd1.5 sample was as high as 93.5 K. The critical current densities ($J_cs$) at 77 K and 1T and 1.5 T were in ranges of 25,200-43,900 $A/cm^2$ and 10,000-23,000 $A/cm^2$, respectively. The maximum attractive force at 77 K of the sample field-cooled using an Nd-B-Fe permanent magnet (surface magnetic field of 0. 527 T) was 108.3 N; the maximum repulsive force of the zero field-cooled sample was 262 N. The magnetic flux density of the sample field-cooled at 77 K was 0.311T, which is approximately 85% of the applied magnetic field of 0.375 T. Microstructure investigation showed that many $Gd_2BaCuO_5$ (Gd211) particles of a few ${\mu}m$ in size, which are flux pinning sites of Gd123, were trapped within the $GdBa_2Cu_3O_{7-y}$ (Gd123) grain; unreacted $Ba_3Cu_5O_8$ liquid and Gd211 particles were present near the edge regions of the single grain Gd1.5 bulk compact.

초전도 벌크의 자기적 특성을 위한 간편한 시스템 (Magnetic Force Properties of Superconducting Bulk)

  • 이상헌
    • 한국전기전자재료학회논문지
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    • 제36권1호
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    • pp.70-73
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    • 2023
  • To improve superconductor properties, the size of the crystal grains of the superconductor should be adjusted, the amount of electricity flowing through the superconductor should be increased, and the superconductor should be designed to withstand external magnetic fields. It is necessary to control the microstructure so that many flux pinning centers are developed inside the superconductor so that defects are generated physically or chemically, and the micro secondary phase for trapped magnetic flux must be dispersed inside the superconductor. In order to measure the superconducting magnetic force of the superconducting bulk in a simplified manner, the superconducting magnetic force was analyzed using an Nd-Fe-B permanent magnet of 3.80 kG. In particular, by delaying the growth of partially melted Y2BaCuO5 particles, we devised a plan to refine Y2BaCuO5 particles to effectively improve superconducting magnetic force, and analyzed superconducting magnetic force in a single crystal YBa2Cu3O7-y superconducting bulk using a gauss meter. The melted superconducting bulk traps 80% or more of the applied magnetic field, and can be used as a bulk magnet of high magnetic field magnetization applicable to electric power equipment.

좁은 수평 환형 Crevice에서의 증발열전달촉진에 관한 연구 (Study on enhancement of evaporating heat transfer in narrow horizontal annular crevices)

  • 배상철;김종수
    • 대한기계학회논문집B
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    • 제20권4호
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    • pp.1481-1490
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    • 1996
  • This study is intend to improve flow pattern within evaporator, which is low quality and low mass flux, by installing narrow horizontal annular crevice so that enhance heat transfer coefficient. The motive, which made to study heat transfer enhancement by using narrow annular crevice, came from capillary phenomena and pumping force of generating vapor on refrigerant boiling. Tests were run about 5 models of turbulence promoter with CFC-12, in the range of evaporating temperature (15.deg. C), mass flux (50 to 100 kg/m$\^$2/s), heat flux (3.4 to 6.7 kW/m$\^$2/), quality (0.1 to O.5). It is observed that flow pattern within evaporator is changed closely to semi-annular flow or annular flow, of which refrigerant liquid is reached to the upper side of tube by using narrow annular crevice. When the narrow annular crevice is installed in the evaporator tube, local heat transfer coefficient is generally more improved than that of smooth tube. That fact is according to observed result of flow pattern. It is learned that narrow annular crevice has more efficiency at a low mass flux. At the TP-5, enhancement of heat transfer rate is about 170% compare to that of smooth tube on a low mass flux (50 kg/m$\^$2/s), and it is about 134% on a high mass flux (100 kg/M$\^$2/S), so that we know that it is on a very high condition.

단결정 $YBa_2Cu_3O_{7-y}$ 벌크 초전도체 제조를 위한 경제적 공정의 개발 (Development of a Cost-Effective Process for the Fabrication of Single Grain $YBa_2Cu_3O_{7-y}$ Bulk Superconductors)

  • 박순동;김광모;전병혁;한영희;김찬중
    • Progress in Superconductivity
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    • 제13권2호
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    • pp.133-138
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    • 2011
  • To reduce the processing cost of the single grain REBCO (RE: Rare-earth elements) bulk superconductors, a cost-effective process should be developed. One possible way of developing the cost-effective process is the use of low-cost precursor powders. In this study, the single grain YBCO superconductors were fabricated using a home made powder. $YBa_2Cu_3O_{7-y}$ (Y123) powders were synthesized at $850-900^{\circ}C$ in air by the powder calcination method with repeated crushing and heat treatment steps. The processing parameters for the fabrication of single grain Y123 bulk superconductors, $T_{max}$ (maximum temperature), $T_p$ (peritectic temperature) and a cooling rate through $T_p$ were optimized. To enhance the flux pinning capacity of the single grain Y123 samples, $Y_2BaCuO_5$ (Y211) particles were dispersed in the Y123 matrix by adding $Y_2O_3$ powder to the calcined Y123 powder. Applying the optimized processing condition, the single grain Y123 superconductors with $T_c=91\;K$ and $J_c=1.5{\times}10^4\;A/cm^2$ at 2 T were successfully fabricated using a home made powder. The levitation forces and trapped magnetic field at 77 K measured using a Nd-B-Fe permanent magnet of 5300 G were 47 N and 3000 G, respectively, which are comparable to those obtained for the samples fabricated using a commercial grade Y123 powders.