• Journal of Surface Science and Engineering
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• v.49 no.3
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• pp.238-244
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• 2016

Copper electrodeposition on AZ91 Mg alloy was studied in views of preferential deposition on ${\alpha}$- or ${\beta}$- phases and how to achieve uniform deposition over the entire surface on ${\alpha}$- and ${\beta}$-phases in a cyanide solution. The inhomogeneous microstructure of AZ91 Mg alloy, particularly ${\alpha}$- and ${\beta}$-phases, was found to result in non-uniform deposition of zincate layer, preferential deposition of zincate on ${\beta}$-phases, which leads to non-uniform growth of copper layer during the following electrodeposition process. The preferential depositions of zincate can be attributed to higher cathodic polarizations on the ${\beta}$-phases. Pin-hole defects in the copper electrodeposit were observed at the center of large size ${\beta}$-phase particles which is ascribed to gas bubbles formed at the ${\beta}$-phases. The activation of AZ91 Mg alloy in hydrofluoric acid solution was used to obtain uniform growth of zincate layer on both the ${\alpha}$- and ${\beta}$-phases. By choosing an optimum activation time, a uniform zincate layer was obtained on the AZ91 Mg alloy surface and thereby uniform growth of copper was obtained in a cyanide copper electroplating solution.

• Journal of Surface Science and Engineering
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• v.49 no.3
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• pp.231-237
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• 2016

This article reports a new chemical bath for preparing a mirror-like surface of AZ31 Mg alloy. In order to find an appropriate chemical polishing solution, four different acidic solutions of sulphuric acid, nitric acid, acetic acid and a specially designed mixture of nitric acid and acetic acid were investigated in view of the changes in surface appearance, roughness and dissolution rate of AZ31 Mg alloy. The surface scales on AZ31 Mg alloy were readily removed by all the acidic solutions, but a reflective surface was produced only by etching in the specially designed solution, and only after a specific etching time. The surface roughness increased with etching time in sulphuric acid, nitric acid, and acetic acid, but it lowered after a specific etching time in the specially designed mixture of nitric acid and acetic acid. Dissolution rate of the alloy in the specially designed mixture of nitric acid and acetic acid appeared to be more than twice than that in separate nitric acid or acetic acid. In this work, we recommend the mirror-like surface of AZ31 Mg alloy obtained by polishing for an optimum time in a mixture of nitric acid and acetic acid for following surface finishings, chemical conversion coating, electroplating, electrophoretic painting and anodizing treatment.

• Journal of Surface Science and Engineering
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• v.43 no.2
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• pp.73-79
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• 2010

A chromium-free conversion coating for AZ31 magnesium alloy has been obtained by using a permanganatephosphate solution, which has been developed with acid pickling. Examination have been carried out on the conversion coatings for morphology, composition and corrosion resistance. The morphology of the conversion-coated layer was observed using optical microscope and SEM. It was shown that the conversion coatings are relatively uniform and continuous, with thickness 1.8 to 2.7 ${\mu}m$. The chemical composition of conversion coating was mainly consisted of Mg, O, P, K, Al and Mn by EDS analysis. It was found that the corrosion resistance of the AZ31 magnesium alloy has been improved by the permanganate-phosphate conversion treatment from electrochemical polarization.

• Resources Recycling
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• v.3 no.1
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• pp.25-31
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• 1994

This paper was focused to optimize hot extrusion condition of Mg machined chips and scraps as fundamental basic research for the recycle of Mg alloy. We have been performed to extrude at $300~380^{\circ}C$ temperature range under the extrusion ratio of 25:1 after cold-pressing AZ91 Mg machined chips and scraps. AZ91 Mg ingots was used as reference materials. Microstructure observation showed that the extruded machined chips were perfectly bonded and extruded materials became fine grain size($20\mu\textrm{m}$) by recrystallization during hot extrusion. The specimens extruded from the machined chips, scraps and Mg ingot indicated tensile strength of 330MPa and the elongation of 10% at room temperature.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.05a
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• pp.73-77
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• 2005

In this work, the influences of tool temperature on the formability of AZ31 sheet material in warm deep drawing processes of square cup were investigated. Deep drawing tests under different tool temperatures for magnesium alloy sheet at elevated temperature $250^{\circ}C$, where AZ31 sheet shows a good formability, and FE analyses were carried out. The successfully formed part without any defects was obtained when temperature of tool was over $100^{\circ}C$ while the fracture was occurred at the corner of the square cup below $100^{\circ}C$. It is shown that lower temperature of tool than that of magnesium sheet causes the temperature drop of the material by heat transfer and thus Interrupts the dynamic recrystallization of it. Therefore, in order to obtain successful part of magnesium alloys, it is necessary that the tool temperature is limited to the same or slightly lower temperature than sheet material.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2008.05a
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• pp.374-377
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• 2008

Magnesium alloy sheets are usually formed at temperatures between $150^{\circ}C$and $300^{\circ}C$ because of their poor formability at room temperature. In the present study, the formability of AZ31B magnesium alloy sheets was investigated by the analytical and experimental approaches. First, tensile tests and the limit dome height test were carried out at elevated temperatures to get the mechanical properties and forming limit diagram, respectively. And then deep drawing of cross shaped die was tried to get the minimum corner radius and forming limit at specific temperature. Blank shape, punch velocity, minimum corner radius, fillet size, etc, were determined by finite element analysis physical try-outs. Especially, optimum punch and die temperature were suggested through the temperature-deformation analysis using Pam-stamp.

• Journal of the Korean Society for Heat Treatment
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• v.31 no.2
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• pp.56-62
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• 2018

Many researchers have studied on the precipitation control after solution treatment to improve the damping capacity without decreasing the strength. However, studies on the damping capacity and microstructure changes after deformation in the solid solution strengthening alloys were inadequate, such as the Al-Zn series magnesium alloys. Therefore, in order to investigate the effect of annealing condition on microstructure change and damping a capacity of AZ61 magnesium alloy. In this study, it was confirmed that the microstructure changes affect the damping capacity and hardness when annealed AZ61 alloy. AZ61 magnesium alloy was rolled at $400^{\circ}C$ with rolling reduction of 30%. These specimens were annealed at $350^{\circ}C$ to $450^{\circ}C$ for 30-180 minutes. After annealing, microstructure was observed by using optical microscopy, and damping capacity was measured by using internal friction measurement machine. Hardness was measured by Vickers hardness tester under a condition of 0.3 N. In this study, static recrystallization was observed regardless of the annealing conditions. In addition, uniform equiaxed grain structure was developed by annealing treatment. Hardness is decreased with increasing grain size. This is associated with Hall-Petch equation and static recrystallization. In case of damping capacity, bigger grain size show the larger damping capacity.

• Journal of the Korean Society for Heat Treatment
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• v.31 no.5
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• pp.231-236
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• 2018

The purpose of this study was to investigate the microstructural characteristics and hardness distribution of AZ91 magnesium alloy furnace-cooled to room temperature after solution treatment, and to compare the results with those of as-cast condition. The as-cast alloy showed a partially divorced eutectic ${\beta}(Mg_{17}Al_{12})$ phase and discontinuous precipitates (DPs) with a lamellar morphology, while only DPs were observed in the furnace-cooled alloy. The DPs in the furnace-cooled AZ91 alloy had various apparent interlamellar spacings, which would be ascribed to the different transformation temperatures during the furnace cooling. The average hardness for the furnace-cooled alloy is similar to that for the as-cast alloy. It is interesting to note that the hardness values of the furnace-cooled alloy were distributed over a narrower range than those of the as-cast alloy. This is likely to be caused by the relatively more homogeneous microstructure of the furnace-cooled alloy in comparison with the ascast one.

• Korean Journal of Metals and Materials
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• v.50 no.9
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• pp.619-627
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• 2012

One of the barriers limiting wide applications of magnesium alloys to various industries is their poor corrosion resistance. The corrosion properties of AZ91 magnesium alloy, which is the most popular magnesium casting alloy, are affected by microstructural and environmental factors. The corrosion properties of AZ91 magnesium alloy are affected by the corrosion properties of ${\alpha}-Mg$ and ${\beta}$ phases, the volume fraction and distribution of ${\beta}$ phase and area ratio of ${\alpha}-Mg/{\beta}$ phases. The corrosion properties of AZ91 magnesium alloy under various environments also change according to the passivity of films and types of corrosion products formed on its surface. The corrosion resistance of the magnesium alloys can be improved by microstructural control through the addition of alloying elements and optimization of the production process.

• Korean Journal of Metals and Materials
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• v.48 no.1
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• pp.85-89
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• 2010

The plastic deformation behavior of magnesium alloy is affected simultaneously by deformation temperature and strain rate under warm and/or hot working conditions. The soundness of deformation of AZ31-xCa (x=0. 0.7, 2.0 wt.%) extrudes during compression was strongly affected by processing variables including deformation temperature, strain rate. compression-loading direction, which was related to the activation of available deformation systems. The deformation behavior of AZ31-xCa extrudes was also affected by Ca content, which was related to the change of the sort and fraction of second phase. The complex effects of deformation temperature and strain rate on the deformation behavior of AZ31-xCa extrudes during compression under various conditions could be successfully described by Zener-Hollomon parameter.