• Title/Summary/Keyword: Available $SiO_2$

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The Influence of Soil Physico-Chemical Properties on Urease Activity in Paddy Soils (답토양(畓土壤)의 이화학적(理化學的) 특성(特性)과 Urease의 활성(活性))

  • Cho, Kang-Jin;Mun, Eul-Ho;Jung, Yeun-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.1
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    • pp.77-81
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    • 1984
  • Paddy soil samples were collected from the plow layers of 19 soil series distributed in Yeongnam district to determine the relationship between soil urease activity and other soil characteristics. The results obtained were summarized as follows: 1. Simple correlation analyses showed that the urease activity was positively related with available $P_2O_5(r=.844^{**})$, potassium activity ratio($r=0.762^{**}$), available $SiO_2(r=.580^{**})$ and $SiO_2$/O.M ratio($r=0.591^{**}$). 2. Among soil chemical properties which had positive linear correlations with soil urease activity, the content of available $P_2O_5$ in soil had the highest contribution to the multiple regression equation of soil urease activity. 3. The activity of soil urease was especially lower in sandy texture than in clayey paddy soils, and a tendency was observed that the heavier soil textures the higher activity of soil urease. 4. Relatively well drained soils had the higher activity of soil urease while the soils in "poorly drained" had remarkably lower activity of soil urease. 5. The soils in higher classes of paddy soil equitability group had higher activities of soil urease.

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Surface Oxidation of High Strength Automotive Steels during Continuous Annealing, and the Influence of Trace Elements of P,B, and Sb

  • Sohn, Il-Ryoung;Park, Joong-Chul;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.259-264
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    • 2010
  • In continuous hot dip galvanizing process, oxide formation on steel surface has an influence on Zn wetting. High strength automotive steel contains high amount of Si and Mn, where Si-Mn composite oxides such as $Mn_2SiO_4$ or $MnSiO_3$ covers the surface after annealing. Zn wetting depends on how the aluminothermia reaction can reduce the Mn-Si composite oxides and then form inhibition layer such as $Fe_2Al_5$ on the steel surface. The outward diffusion of metallic ions such as $Mn^{2+}$, $Si^{2+}$ in the steel matrix is very important factor for the formation of the surface oxides on the steel surface. The surface state and grain boundaries provide an important role for the diffusion and the surface oxide reactions. Some elements such as P, Sb, and B have a strong affinity for the interface precipitation, and it influence the diffusivity of metallic ions on grain boundaries. B oxide forms very rapildly on the steel surface during the annealing, and this promote complex oxides with $SiO_2$ or MnO. P has inter-reacted with other elements on the grain boundaries and influence the diffusion through on them. Small addition of Sb could suppress the decarburization from steel surface and retards the formation of internal and external selective oxides on the steel surface. Interface control by the trace elements such as Sb could be available to improve the Zn wettability during the hot dip galvanizing.

Electrical Properties of Ferroelectric Polymer on Inorganic Dielectric Layer for FRAM

  • Han, Hui-Seong;Kim, Kwi-Jung;Jeon, Ho-Seung;Park, Byung-Eun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.258-258
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    • 2008
  • Among several available high-k dielectrics the lanthanum zirconium oxide ($LaZrO_x$) system is very attractive as a buffer insulating layer. Because both lanthanum and zirconium atoms, the constituents of the $LaZrO_x$ thin film, have been considered to be thermally stable in contact with Si. The $LaZrO_x$ films were deposited by a sol-gel method. After the deposition, The $LaZrO_x$ films were crystallized at $750^{\circ}C$ for 30 minutes in $O_2$ ambient. PVDF-TrFE films were deposited on these $LaZrO_x$/Si structures using a sol-gel technique. The sol-gel solution was spin-coated on $LaZrO_x$/Si structures at 500 rpm for 5 sec and 2500 rpm for 15 sec. The deposited layer was dried at $165^{\circ}C$ for 30 min in air on a hot-plate. Then, we deposited Au electrode on PVDF-TrFE films using thermal evaporation.

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A New Annealing Method. (새로운 Annealing 방법)

  • Hong, Soon-Kwan;Park, Sun-Woo;Kim, Chul-Ju
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.367-369
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    • 1988
  • We suggest a new annealing method for stabilization of $Si-SiO_2$ interface state in MOS device using $NH_3$(10%) + $N_2$(90%) ambient gases. The annealing effect was examined through C-V characteristics, threshold voltage, effective mobility on channel, respectively. The experimental result show that the new method is available to improvement of MOS device characteristics.

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Surface Reaction Modeling for Plasma Etching of SiO2 Thin Film (실리콘 산화막의 플라즈마 식각에 대한 표면반응 모델링)

  • Im, YeonHo
    • Korean Chemical Engineering Research
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    • v.44 no.5
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    • pp.520-527
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    • 2006
  • A realistic surface model is presented for prediction of various surface phenomena such as polymer deposition, suppression and sputtering as a function of incidence ion energy in high density fluorocarbon plasmas. This model followed ion enhanced etching model using the "well-mixed" or continuous stirred tank reactor (CSTR) assumption to the surface reaction zone. In this work, we suggested ion enhanced polymer formation and decomposition mechanisms that can capture $SiO_2$ etching through a steady-state polymer film on $SiO_2$ under the suppression regime. These mechanisms were derived based on experimental data and molecular dynamic simulation results from literatures. The model coefficients are obtained from fits to available beam and plasma experimental data. In order to show validity of our model, we compared the model results to high density fluorocarbon plasma etching data.

Effect of Fly ash Application on the Yield of Rice and Silicate Availability in Paddy Soil (Fly ash 시용(施用)이 수도(水稻)의 수량(收量)과 논 토양(土壤)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響))

  • Kim, Yong-Woong;Yun, Chong-Hee;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.275-283
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    • 1994
  • The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

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Field Survey on Soil Chemical Properties as Influenced on Corn Yield (토양(土壤)의 화학성(化學性)이 옥수수 수량(收量)에 미치는 영향(影響))

  • Shin, Cheol-Woo;Kim, Jeong-Je;Hur, Beom-Lyang;Yoon, Jung-Hui
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.2
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    • pp.173-178
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    • 1984
  • Correlation study was conducted to establish the optimum test level of soil improvement for good growth of corn from the relationships between the corn yield and soil chemical properties in 16 farmers' demonstration fields. Significant positive correlations between the corn yield and soil chemical properties ; pH, available phosphorus, exchangeable potassium, calcium, magnesium, cation exchange capacity. available silica, and base saturation percentage were showed but organic matter and nitrogen content were not. The proper nutrient contents in soil for expecting corn yield, 1.000kg/10a could be estimated as pH 5.6, available phosphorus 327ppm, exchangeable potassium 0.39me/100g, exchangeable calcium 5.5me/100g, exchangeable magnesium 1.3me/100g, cation exchange capacity 11.5me/100g, available silica 116ppm, base saturation percentage 58 from the relationships between the corn yield and soil chemical properties. Exchangeable aluminium were negatively correlated with not only corn yield but also pH, available phosphorus, exchangeable potassium and exchangeable calcium.

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Investigations on Partial Discharge, Dielectric and Thermal Characteristics of Nano SiO2 Modified Sunflower Oil for Power Transformer Applications

  • Nagendran, S.;Chandrasekar, S.
    • Journal of Electrical Engineering and Technology
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    • v.13 no.3
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    • pp.1337-1345
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    • 2018
  • The reliability of power transmission and distribution depends up on the consistency of insulation in the high voltage power transformer. In recent times, considering the drawbacks of conventional mineral oils such as poor biodegradability and poor fire safety level, several research works are being carried out on natural ester based nanofluids. Earlier research works show that sunflower oil has similar dielectric characteristics compared with mineral oil. BIOTEMP oil which is now commercially available in the market for transformers is based on sunflower oil. Addition of nanofillers in the base oil improves the dielectric characteristics of liquid insulation. Only few results are available in the literature about the insulation characteristics of nano modified natural esters. Hence understanding the influence of addition of nanofillers in the dielectric properties of sunflower oil and collecting the database is important. Considering these facts, present work contributes to investigate the important characteristics such as partial discharge, lightning impulse, breakdown strength, tandelta, volume resistivity, viscosity and thermal characteristics of $SiO_2$ nano modified sunflower oil with different wt% concentration of nano filler material varied from 0.01wt% to 0.1wt%. From the obtained results, nano modified sunflower oil shows better performance than virgin sunflower oil and hence it may be a suitable candidate for power transformer applications.

Studies on the Estimation of K2O Requirement for rice through the Chemical Test Data of Paddy Top Soil (화학분석(化學分析)을 통(通)한 수도(水稻)의 가리적량(加里適量) 추정(推定)에 관한 연구(硏究))

  • Kim, Moon Kyu
    • Korean Journal of Agricultural Science
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    • v.2 no.1
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    • pp.61-100
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    • 1975
  • This study has been made to find out the possibilty of successfully using the following $K_2O$ recommended equation $K_2O\;kg/10a=(Ko/\sqrt{Ca+Mg}-Ks/\sqrt{Ca+Mg})sqrt{Ca+Mg}.\;47.\;B\;D$. where $Ko/sqrt{Ca+Mg}=0.03518+0.0007658\;Sio_2/O.M$. $K_Ssqrt{Ca+Mg}$=Exchangeable K me/100g/$\sqrt{Total\;soluble(Ca+Mg)me/100g\;in\;Soil}$ B. D. =Bulk density of top soil, when the dose of Nitrogen for rice is estimated from the following equation: $N\;kg/10a=(4.2+0.096\;SiO_2/O.M).F$ where $F=0.907+0.263x-0.013x^2$ $SiO_2/O.M=(available\;SiO_2=ppm)/(organic\;matter\;%)$in soil For this. two field experiments. one in sandy and the other in clay paddy soil. have been conducted using 3 levels of wollastonite (0, 500, 100kg/10a) as main treatments; 3 levels of $K_2O$ application were used as sub-plots. These were as follows : (1) 8kg of $K_2O$/10a regardless of the K activity-$K/\sqrt{Ca+Mg}$; (2) kg of $K_2O$/10a estimated from the above equation. and (3) same as (2) above plus additional 30% of $K_2O$. The dose of N kg/ 10a was determined from the above equation based on the value of $SiO_2$/O.M. ratio in each treatment. There were three replications. The leading variety of rice in Chung Chong Nam Do area. Akibare (introduced from Japan) was used. The data obtained. through soil and plant analysis and growth and yield observations. have been throughly examined to attain the following summarized conclusions. 1. The nitrogen dose. estimated from the above equation. was in excess for optimum growth of the rice variety Akibare; indicating the necessity of modification onthe value of "F" or the constants in the equation. The concept of using $SiO_2$/O.M. in the equation was shown to be applicable. 2. The dose of potash. estimated from the respective equation given above. also was in excess of the rice requirements indicating the necessity of minor change in the estimation of $Ko/\sqrt{Ca+Mg}$ value and some great modification in the calculation of $Ks/\sqrt{Ca+Mg}$ value for the equation; however the concept of using $K/\sqrt{Ca+Mg}$ as a basis of $K_2O$ recommendation was shown to be quite reasonable. 3. It was found. from the correlation study using the data of paddy yield and amount of $K_2O$ absorbed by rice plants that the substitution of the value of $Ks/\sqrt{Ca+Mg}$ in the equation for the vaule $Ks/\sqrt{Ca+Mg}=0.037+0.78K\;me/100g$ soil was much more applicable than using the value calculated from the data of soil and wollastonite analysis.

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Effects of Additives on the Characteristics of Sodium Borosilicate Thin Film Fabricated by AFD Method (첨가제가 AFD법에 의해 제조된 광소자용 Sodium Borosilicate 박막의 물성에 미치는 영향)

  • Chung, Hyung-Gon;Chun, Young-Yun;Mun, Jong-Ha;Chung, Suck-Jong;Lee, Hyung-Jong
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.693-698
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    • 1998
  • The effects of $AI_{2}$$O_{3}$ and the ratio of $Na_2O/B_2O_3$ on the phase separation and optical properties of sodium borosilicate glass film fabricated by AFD(Aerosol Flame Deposition) were investigated. When AI,O, of 6wt% was added to $66SiO_2-27B_2O_3-7Na_2O$ the clear glass film without any crystallization was produced under air-quenching condition after consolidation. As the amount of $AI_{2}$$O_{3}$ increased from 1.5 to 6.0 wt% the refractive index linearly increased from 1.4610 to 1.4701, and the difference of TE and TM mode causing by residual stress in film increased gradually. However, the difference of TE and TM mode to reveal birefringence could be minimized by annealing below the glass transition temperature after consolidation and air quenching. On the other hand. as the ratio of $Na_2O/B_2O_3$ increased the refractive index and birefringence of glass film tended to increase, but the measurement of their values were not available at over the critical ratio of $Na_2O/B_2O_3$, because of the cloudiness due to crystallization. The phase separation was greatly accelerated with increasing the ratio of $Na_2O/B_2O_3$.

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