• Title/Summary/Keyword: Atomic vapor

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Semiconductor laser-based absorption spectroscopy for monitoring physical vapor deposition process (증기증착 공정 감시를 위한 반도체 레이저 흡수 분광학)

  • 정의창;송규석;차형기
    • Journal of the Korean Vacuum Society
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    • v.13 no.2
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    • pp.59-64
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    • 2004
  • A study on the semiconductor laser-based atomic absorption spectroscopy was performed for monitoring physical vapor deposition process. Gadolinium metal was vaporized with a high evaporation rate by electron beam heating. Real-time atomic absorption spectra were measured by using tunable semiconductor laser beam at 770-794 nm (center wavelength of 780 nm) and its second harmonic at 388-396 nm. Atomic densities of metal vapor can be calculated from the absorption spectra measured. We plot the atomic densities as a function of the electron beam power and compare with the evaporation rates measured by quartz crystal monitor. We demonstrate that the semiconductor laser-based spectroscopic system developed in this study can be applied to monitor the physical vapor deposition process for other metals such as titanium.

Study on the velocity of gadolinium atomic vapor produced by electron beam heating (전자빔 가열로 발생시킨 Gd 원자증기의 속도에 관한 연구)

  • 정의창;권덕희;고광훈;김택수
    • Journal of the Korean Vacuum Society
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    • v.12 no.4
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    • pp.228-234
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    • 2003
  • The velocity of gadolinium(Gd) atomic vapor vaporized by an electron beam was measured by a microbalance. The velocity of about 900 ㎧ was obtained at an evaporation surface temperature of 2400-2500 K. The measured value was approximately 100 ㎧ faster than the maximum velocity of an ideal monatomic gas in an adiabatic expansion. This phenomenon can be explained that the internal energy of Gd atoms populated in higher excited levels at the high temperature should be convened to kinetic energy during adiabatic expansion. The calculated velocity agrees with the measured one when 100 excited energy levels are included in an enthalpy term for the velocity calculation. The characteristics of vapor flow as a function of heated surface temperature are also reported.

Semiempirical model for wet scrubbing of bubble rising in liquid pool of sodium-cooled fast reactor

  • Pradeep, Arjun;Sharma, Anil Kumar
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.849-853
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    • 2018
  • Mechanistic calculations for wet scrubbing of aerosol/vapor from gas bubble rising in liquid pool are essential to safety of sodium-cooled fast reactor. Hence, scrubbing of volatile fission product from mixed gas bubble rising in sodium pool is presented in this study. To understand this phenomenon, a theoretical model has been setup based on classical theories of aerosol/vapor removal from bubble rising through liquid pools. The model simulates pool scrubbing of sodium iodide aerosol and cesium vapor from a rising mixed gas bubble containing xenon as the inert species. The scrubbing of aerosol and vapor are modeled based on deposition mechanisms and Fick's law of diffusion, respectively. Studies were performed to determine the effect of various key parameters on wet scrubbing. It is observed that for higher vapor diffusion coefficient in gas bubble, the scrubbing efficiency is higher. For aerosols, the cut-off size above which the scrubbing efficiency becomes significant was also determined. The study evaluates the retention capability of liquid sodium used in sodium-cooled fast reactor for its safe operation.

Influence of Winding Patterns and Infiltration Parameters on Chemical Vapor Infiltration Behaviors of SiCf/SiC Composites (SiCf/SiC 복합체의 화학기상침착 거동에 미치는 권선 구조와 침착 변수의 영향)

  • Kim, Daejong;Ko, Myoungjin;Lee, Hyeon-Geun;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.453-458
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    • 2014
  • SiC and its composites have been considered for use as nuclear fuel cladding materials of pressurized light water reactors. In this study, a $SiC_f$/SiC composite as a constituent layer of SiC triplex fuel cladding was fabricated using a chemical vapor infiltration (CVI) process in which tubular SiC fiber preforms were prepared using a filament winding method. To enhance the matrix density of the composite layer, winding patterns, deposition temperature, and gas input ratio were controlled. Fiber arrangement and porosity were the main parameters influencing densification behaviors. Final density of the composites decreased as the SiC fiber volume fraction increased. The CVI process was optimized to densify the tubular preforms with high fiber volume fraction at a high $H_2$/MTS ratio of 20 at $1000^{\circ}C$; in this process, surface canning of the composites was effectively retarded.

Prenconcentration and Determination of Mercury (II) and Methylmercury in Waters by Immobilized 1,5-Diphenylcarbazone and Cold Vapor Atomic Absorption Spectrometry

  • Dadfarnia, Shayessteh;Salmanzadeh, Ali Mohammed;Haji Shabani, Ali Mohammed
    • Bulletin of the Korean Chemical Society
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    • v.23 no.12
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    • pp.1719-1723
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    • 2002
  • 1,5-diphenylcarbazone was immobilized on sodium dodecyl sulfate coated alumina. The alumina particle was effectively used for collection of mercury(II) and methylmercury cations at sub-ppb level. The adsorbed mercury was eluted with l mol $L^{-1}$ of hydrobromic acid solution. The mercury(II) was then directly measured by cold vapor atomic absorption spectrometry utilizing tin (II) chloride where as the total mercury was determined after the oxidation of methylmercury into the inorganic mercury. The methylmercury concentration was calculated by the difference between the value of total mercury and mercury (II). Mercury (II) and methylmercury cations were completely recovered from water with a preconcentration factor of 100 (for 1 L solution.) Relative standard deviation at Hg L ${\mu}gL^{-1}$ level 1.7%(n=8) and the limit of detection was 0.11 ${\mu}gL^{-1}$. The procedure was applied to spring water, well water and seawater and accuracy was assessed through recovery experiments.

Fabrication of High-purity Rb Vapor Cell for Electric Field Sensing

  • Jae-Keun Yoo;Deok-Young Lee;Sin Hyuk Yim;Hyun-Gue Hong;Sun Do Lim;Seung Kwan Kim;Young-Pyo Hong;No-Weon Kang;In-Ho Bae
    • Current Optics and Photonics
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    • v.7 no.2
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    • pp.207-212
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    • 2023
  • In this paper, we introduce our system for manufacturing a Rb vapor cell and describe its fabrication process in a sequence of removing impurities, cold trapping, and sealing off. Saturated absorption spectroscopy was performed to verify the quality of our cell by comparing it to that of a commercial one. By using the lab-fabricated Rb vapor cell, we observed electromagnetically induced transparency in a ladder-type system corresponding to the 5S1/2-5P3/2-28D5/2 transition of the 85Rb atom. A highly excited Rydberg atomic system was prepared using two counter-propagating external cavity diode lasers with wavelengths of 780 nm and 480 nm. We also observed the Autler-Townes splitting signal while a radio-frequency source around 100 GHz incidents into the Rydberg atomic medium.