• Title/Summary/Keyword: Atomic vapor

검색결과 461건 처리시간 0.023초

증기증착 공정 감시를 위한 반도체 레이저 흡수 분광학 (Semiconductor laser-based absorption spectroscopy for monitoring physical vapor deposition process)

  • 정의창;송규석;차형기
    • 한국진공학회지
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    • 제13권2호
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    • pp.59-64
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    • 2004
  • 반도체 레이저를 광원으로 사용하는 원자흡수분광 방법으로 금속증기의 증착 공정을 감시하는 연구를 수행하였다. 전자빔 가열 방식을 이용하여 gadolinium (Gd) 금속을 대량으로 증발시켰다. 파장 영역이 770-794 nm (중심파장 780 nm)인 반도체 레이저빔과 388-396 nm 영역의 제 2 고조파 빔을 진공용기에 입사시켜 증발되는 금속증기의 원자흡수 스펙트럼을 실시간으로 기록하였다. 흡수 스펙트럼을 분석하여 증기의 원자밀도를 구했다. 전자빔 출력을 변화시키면서 측정한 원자밀도를 수정 결정 모니터 장치를 사용하여 측정한 증착률과 비교하였다. 산업적으로 많이 사용되는 Ti 등의 증착 공정 감시에 이 실험에서 구현한 레이저 분광장치를 적용할 수 있다는 것을 제시하였다.

전자빔 가열로 발생시킨 Gd 원자증기의 속도에 관한 연구 (Study on the velocity of gadolinium atomic vapor produced by electron beam heating)

  • 정의창;권덕희;고광훈;김택수
    • 한국진공학회지
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    • 제12권4호
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    • pp.228-234
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    • 2003
  • 전자빔으로 증발시킨 gadolinium(Gd) 원자증기의 속도를 미량 저울(microbalance)을 사용하여 측정하였다. 증발 표면의 온도가 2400-2500 K인 조건에서 약 900 ㎧의 속도가 측정되었다. 이 값은 단열팽창을 하는 이상적 단원자의 최대 속도에 비해 약 100 ㎧ 더 빠른 속도에 해당된다. 이 특이 현상의 원인을 고온에서 여러 개의 들뜬 에너지 준위에 분포한 Gd 원자의 내부 에너지가 단열팽창 중에 운동 에너지로 전환되는 것으로 설명하였다. 100개의 들뜬 에너지 준위를 원자증기의 엔탈피에 포함시켜 속도를 계산한 값이 실험 결과와 비교적 일치함을 보였다. 가열된 표면 온도의 변화에 따른 원자증기의 유동 특성에 대해서도 보고한다.

Semiempirical model for wet scrubbing of bubble rising in liquid pool of sodium-cooled fast reactor

  • Pradeep, Arjun;Sharma, Anil Kumar
    • Nuclear Engineering and Technology
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    • 제50권6호
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    • pp.849-853
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    • 2018
  • Mechanistic calculations for wet scrubbing of aerosol/vapor from gas bubble rising in liquid pool are essential to safety of sodium-cooled fast reactor. Hence, scrubbing of volatile fission product from mixed gas bubble rising in sodium pool is presented in this study. To understand this phenomenon, a theoretical model has been setup based on classical theories of aerosol/vapor removal from bubble rising through liquid pools. The model simulates pool scrubbing of sodium iodide aerosol and cesium vapor from a rising mixed gas bubble containing xenon as the inert species. The scrubbing of aerosol and vapor are modeled based on deposition mechanisms and Fick's law of diffusion, respectively. Studies were performed to determine the effect of various key parameters on wet scrubbing. It is observed that for higher vapor diffusion coefficient in gas bubble, the scrubbing efficiency is higher. For aerosols, the cut-off size above which the scrubbing efficiency becomes significant was also determined. The study evaluates the retention capability of liquid sodium used in sodium-cooled fast reactor for its safe operation.

SiCf/SiC 복합체의 화학기상침착 거동에 미치는 권선 구조와 침착 변수의 영향 (Influence of Winding Patterns and Infiltration Parameters on Chemical Vapor Infiltration Behaviors of SiCf/SiC Composites)

  • 김대종;고명진;이현근;박지연;김원주
    • 한국세라믹학회지
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    • 제51권5호
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    • pp.453-458
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    • 2014
  • SiC and its composites have been considered for use as nuclear fuel cladding materials of pressurized light water reactors. In this study, a $SiC_f$/SiC composite as a constituent layer of SiC triplex fuel cladding was fabricated using a chemical vapor infiltration (CVI) process in which tubular SiC fiber preforms were prepared using a filament winding method. To enhance the matrix density of the composite layer, winding patterns, deposition temperature, and gas input ratio were controlled. Fiber arrangement and porosity were the main parameters influencing densification behaviors. Final density of the composites decreased as the SiC fiber volume fraction increased. The CVI process was optimized to densify the tubular preforms with high fiber volume fraction at a high $H_2$/MTS ratio of 20 at $1000^{\circ}C$; in this process, surface canning of the composites was effectively retarded.

Prenconcentration and Determination of Mercury (II) and Methylmercury in Waters by Immobilized 1,5-Diphenylcarbazone and Cold Vapor Atomic Absorption Spectrometry

  • Dadfarnia, Shayessteh;Salmanzadeh, Ali Mohammed;Haji Shabani, Ali Mohammed
    • Bulletin of the Korean Chemical Society
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    • 제23권12호
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    • pp.1719-1723
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    • 2002
  • 1,5-diphenylcarbazone was immobilized on sodium dodecyl sulfate coated alumina. The alumina particle was effectively used for collection of mercury(II) and methylmercury cations at sub-ppb level. The adsorbed mercury was eluted with l mol $L^{-1}$ of hydrobromic acid solution. The mercury(II) was then directly measured by cold vapor atomic absorption spectrometry utilizing tin (II) chloride where as the total mercury was determined after the oxidation of methylmercury into the inorganic mercury. The methylmercury concentration was calculated by the difference between the value of total mercury and mercury (II). Mercury (II) and methylmercury cations were completely recovered from water with a preconcentration factor of 100 (for 1 L solution.) Relative standard deviation at Hg L ${\mu}gL^{-1}$ level 1.7%(n=8) and the limit of detection was 0.11 ${\mu}gL^{-1}$. The procedure was applied to spring water, well water and seawater and accuracy was assessed through recovery experiments.

Fabrication of High-purity Rb Vapor Cell for Electric Field Sensing

  • Jae-Keun Yoo;Deok-Young Lee;Sin Hyuk Yim;Hyun-Gue Hong;Sun Do Lim;Seung Kwan Kim;Young-Pyo Hong;No-Weon Kang;In-Ho Bae
    • Current Optics and Photonics
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    • 제7권2호
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    • pp.207-212
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    • 2023
  • In this paper, we introduce our system for manufacturing a Rb vapor cell and describe its fabrication process in a sequence of removing impurities, cold trapping, and sealing off. Saturated absorption spectroscopy was performed to verify the quality of our cell by comparing it to that of a commercial one. By using the lab-fabricated Rb vapor cell, we observed electromagnetically induced transparency in a ladder-type system corresponding to the 5S1/2-5P3/2-28D5/2 transition of the 85Rb atom. A highly excited Rydberg atomic system was prepared using two counter-propagating external cavity diode lasers with wavelengths of 780 nm and 480 nm. We also observed the Autler-Townes splitting signal while a radio-frequency source around 100 GHz incidents into the Rydberg atomic medium.