• Title/Summary/Keyword: Atomic structure

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PROPERTIES OF ZR ALLOY CLADDING AFTER SIMULATED LOCA OXIDATION AND WATER QUENCHING

  • Kim, Hyun-Gil;Kim, Il-Hyun;Jung, Yang-Il;Park, Jeong-Yong;Jeong, Yong-Hwan
    • Nuclear Engineering and Technology
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    • v.42 no.2
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    • pp.193-202
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    • 2010
  • In order to study the cladding properties of zirconium after a loss-of-coolant accident (LOCA)-simulation oxidation and water quenching test, commercial Zircaloy-4 and two kinds of HANA claddings were oxidized at temperatures ranging from $900^{\circ}C$ to $1250^{\circ}C$ and exposed for 300 s, and then cooled to $700^{\circ}C$ before quenching. Microstructural observations were made to evaluate the matrix characteristics with the chemical compositions after the LOCA-simulation test. Ring compression testing was then performed to compare the ductile behaviour of the HANA and Zircaloy-4 claddings. An X-ray diffraction (XRD) analysis was carried out for temperatures ranging from room temperature to $1250^{\circ}C$ for the oxide layer to verify the oxide crystal structure at each oxidation temperature.

The inspection and maintenance of pressurizer internal structures by using the tele-operated robotic manipulator in nuclear power plants

  • Jeon, Poong-Woo;Jung, Seung-Ho;Seo, Yong-Chil;Choi, Chang-Hwan;Kim, Seung-Ho
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2307-2310
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    • 2005
  • A pressurizer is one of the major safety related equipment of nuclear power plants. In order to inspect and maintain the internal structures of a pressurizer, jumpers have to enter the pressurizer, in spite of the high dose exposure. Therefore, a tele-operated robotic manipulator has been developed, which consists of four parts with 2DOFs arms, a gripper, base frame, and control console. The task of this robotic manipulator is to extract the damaged electric heaters and inspect the internal structure of the pressurizer. The gripper hanging from the manipulator approaches the heaters and extracts the damaged heater by using a self-locking mechanism. In order to investigate the structural stability of the robotic manipulator, a stress analysis has been performed by using the ANSYS code. The results of this paper include the position control and vibration control of robotic gripper and the development of processing visual information for a vision sensor.

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Characteristics of TaN Film as to Cu Barrier by PAALD Method (PAALD 방법을 이용한 TaN 박막의 구리확산방지막 특성)

  • 부성은;정우철;배남진;권용범;박세종;이정희
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.2
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    • pp.5-8
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    • 2003
  • In this study, as Cu diffusion barrier, tantalum nitrides were successfully deposited on Si(100) substrate and $SiO_2$ by plasma assisted atomic layer deposition(PAALD) and thermal ALD, using pentakis (ethylmethlyamino) tantalum (PEMAT) and NH$_3$ as precursors. The TaN films were deposited at $250^{\circ}C$ by both method. The growth rates of TaN films were 0.8${\AA}$/cycle for PAALD and 0.75${\AA}$/cycle for thermal ALD. TaN films by PAALD showed good surface morphology and excellent step coverage for the trench with an aspect ratio of h/w -1.8:0.12 mm but TaN films by thermal ALD showed bad step coverage for the same trench. The density for PAALD TaN was 11g/cmand one for thermal ALD TaN was 8.3g/$cm^3$. TaN films had 3 atomic % carbon impurity and 4 atomic % oxygen impurity for PAALD and 12 atomic % carbon impurity and 9 atomic % oxygen impurity for thermal ALD. The barrier failure for Cu(200 nm)/TaN(10 nm)/$SiO_2$(85 nm)/ Si structure was shown at temperature above $700^{\circ}C$ by XRD, Cu etch pit analysis.

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Actinide Drawdown From LiCl-KCl Eutectic Salt via Galvanic/chemical Reactions Using Rare Earth Metals

  • Yoon, Dalsung;Paek, Seungwoo;Jang, Jun-Hyuk;Shim, Joonbo;Lee, Sung-Jai
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.373-382
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    • 2020
  • This study proposes a method of separating uranium (U) and minor actinides from rare earth (RE) elements in the LiCl-KCl salt system. Several RE metals were used to reduce UCl3 and MgCl2 from the eutectic LiCl-KCl salt systems. Five experiments were performed on drawdown U and plutonium (Pu) surrogate elements from RECl3-enriched LiCl-KCl salt systems at 773 K. Via the introduction of RE metals into the salt system, it was observed that the UCl3 concentration can be lowered below 100 ppm. In addition, UCl3 was reduced into a powdery form that easily settled at the bottom and was successfully collected by a salt distillation operation. When the RE metals come into contact with a metallic structure, a galvanic interaction occurs dominantly, seemingly accelerating the U recovery reaction. These results elucidate the development of an effective and simple process that selectively removes actinides from electrorefining salt, thus contributing to the minimization of the influx of actinides into the nuclear fuel waste stream.

Verification Test and Model Updating for a Nuclear Fuel Rod with Its Supporting Structure

  • H. S. Kang;K. N. Song;Kim, H. K.;K. H. Yoon;Y. H. Jung
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.73-82
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    • 2001
  • Pressurized water reactor(PWR) fuel rods. which are continuously supported by a spring system called a spacer grid(SG), are exposed to reactor coolant at a flow velocity of up to 6-8 m/s. It is known that the vibration of 3 fuel rod is generated by the coolant flow, a so-called flow-induced-vibration(FIV), and the relative motion induced by the FIV between the fuel rod and the SG can wear away the surface of the fuel rod, which occasionally leads to its fretting failure. It is, therefore, important to understand the vibration characteristics of the fuel rod and reflect that in its design. In this paper, vibration analyses of the fuel rod with two different SGs were performed using both analytical and experimental methods. Updating of the finite element(FE) model using the measured data was performed in order to enhance confidence in the FE model of fuel rods supported by an SG. It was found that the modal parameters are very sensitive to the spring constant of the SG.

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Microstructure of ZrC Coatings of TRISO Coated Particles by Codeposition of Free Carbon and Control of Stoichiometry (유리탄소의 동시증착에 의한 TRISO 피복입자의 ZrC 코팅층 미세구조와 화학양론비 제어)

  • Ko, Myung-Jin;Kim, Daejong;Park, Ji Yeon;Cho, Moon Sung;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.446-450
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    • 2013
  • TRISO coated particles with a ZrC barrier layer were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for a use in a very high temperature gas-cooled reactor (VHTR). The ZrC layer was deposited by the reaction between $ZrCl_4$ and $CH_4$ gases at $1500^{\circ}C$ in an $Ar+H_2$ mixture gas. The amount of free carbon codeposited with in ZrC was changed by controlling the dilution gas ratio. Near-stoichiometric ZrC phase was also deposited when an impeller was employed to a $ZrCl_4$ vaporizer which effectively inhibited the agglomeration of $ZrCl_4$ powders during the deposition process. A near-stoichiometric ZrC coating layer had smooth surface while ZrC containing the free carbon had rough surface with tumulose structure. Surface roughness of ZrC increased further as the amount of free carbon increased.

PAALD 방법을 이용한 TaN 박막의 구리확산방지막 특성

  • 부성은;정우철;배남진;권용범;박세종;이정희
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.14-19
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    • 2002
  • In this study, as Cu diffusion barrier, tantalum nitrides were successfully deposited on Si(100) substrate and SiO2 by plasma assisted atomic layer deposition(PAALD) and thermal ALD, using pentakis (ethylmethlyamino) tantalum (PEMAT) and $NH_3$ as precursors. The TaN films were deposited on $250^{\circ}$C by both method. The growth rates of TaN films were $0.8{\AA}$/cycle for PAALD and $0.75{\AA}$/cycle for thermal ALD. TaN films by PAALD showed good surface morphology and excellent step coverage for the trench with an aspect ratio of h/w - $1.8 : 0.12 \mu\textrm{m}$ but TaN films by thermal ALD showed bad step coverage for the same trench. The density for PAALD TaN was $11g/\textrm{cm}^3$ and one for thermal ALD TaN was $8.3g/\textrm{cm}^3$. TaN films had 3 atomic % carbon impurity and 4 atomic % oxygen impurity for PAALD and 12 atomic % carbon impurity and 9 atomic % oxygen impurity for thermal ALD. The barrier failure for Cu(200nm)/TaN(l0nm)/$SiO_2(85nm)$/Si structure was shown at temperature above $700^{\circ}$C by XRD, Cu etch pit analysis.

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Atomic Layer Deposition for Display Applications

  • Park, Jin-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.76.1-76.1
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    • 2013
  • Atomic Layer Deposition (ALD) has remarkably developed in semiconductor and nano-structure applications since early 1990. Now, the advantages of ALD process are well-known as controlling atomic-level-thickness, manipulating atomic-level-composition control, and depositing impurity-free films uniformly. These unique properties may accelerate ALD related industries and applications in various functional thin film markets. On the other hand, one of big markets, Display industry, just starts to look at the potential to adopt ALD functional films in emerging display applications, such as transparent and flexible displays. Unlike conventional ALD process strategies (good quality films and stable precursors at high deposition processes), recently major display industries have suggested the following requirements: large area equipment, reasonable throughput, low temperature process, and cost-effective functional precursors. In this talk, it will be mentioned some demands of display industries for applying ALD processes and/or functional films, in terms of emerging display technologies. In fact, the AMOLED (active matrix organic light emitting diode) Television markets are just starting at early 2013. There are a few possibilities and needs to be developing for AMOLED, Flexible and transparent Display markets. Moreover, some basic results will be shown to specify ALD display applications, including transparent conduction oxide, oxide semiconductor, passivation and barrier films.

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Nuclear Structure Studies with Low Temperature Technique (I)

  • Young Koh;Park, Won-Seok;Park, Chang-Kyu;Shin, Hee-Sung;Song, Tae-Yung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.669-674
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    • 1996
  • The theory of quantum mechanics states that for any system there are a set of discrete physical states, quantum states, which corresponds a particular energy level of the system. The lowest energy the system can have, corresponding to its ground state, is not necessarily zero, but depends only on the precise microscopic nature of the system under consideration. At the absolute zero of temperature all systems will be in their lowest energy state (zero point energy) and as the system is warmed from OK, the higher energy states become occupied. The probability of occupancy of the excited states relative to that of the ground state is proportional to the absolute temperature. Therefore we can obtain nuclear dipole and quadrupole moment very accurately at ultra low temperature (<15mk) by NMR and from the destruction of anisotropy. The former is called LTNO/NMR and the latter is called LTNO (Low Temperature Nuclear Orientation). In this paper we discuss and introduce only an experimental apparatus with results of cooling power test, a helium dilution refrigerator, which can reache 8mK, and an actual technique for the experiment, a theory and results will be presented in another papers.

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SHIELDED LASER ABLATION ICP-MS SYSTEM FOR THE CHARACTERIZATION OF HIGH BURNUP FUEL

  • Ha, Yeong-Keong;Han, Sun-Ho;Kim, Hyun-Gyum;Kim, Won-Ho;Jee, Kwang-Yong
    • Nuclear Engineering and Technology
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    • v.40 no.4
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    • pp.311-318
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    • 2008
  • In modem power reactors, nuclear fuels have recently reached 55,000 MWd/MtU from the initial average burnup of 35,000 MWd/MtU to reduce the fuel cycle cost and waste volume. At such high burnups, a fuel pellet produces fission products proportional to the burnup and creates a typical high burnup structure around the periphery region of the pellet, producing the so called 'rim effect'. This rim region of a highly burnt fuel is known to be ca. $200\;{\mu}m$ in width and is known to affect the fuel integrity. To characterize the local burnup in the rim region, solid sampling in the micro meter region by laser ablation is needed so that the distribution of isotopes can be determined by ICP-MS. For this procedure, special radiation shielding is required for personnel safety. In this study, we installed a radiation shielded laser ablation ICP-MS system, and a performance test of the developed system was conducted to evaluate the safe operation of instruments.