• Title/Summary/Keyword: Atomic parameters

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Spacer Grid Effects on Turbulent Flow in Rod Bundles (지지격자가 봉다발 난류유동에 미치는 영향)

  • Yang, Sun-Kyu;Chung, Moon-Ki
    • Nuclear Engineering and Technology
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    • v.28 no.1
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    • pp.56-71
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    • 1996
  • The local hydrulic characteristics in subchannels of 5$\times$5 nuclear fuel bundles with spacer grids were measured at upstream and downstream of the spacer grid for the investigation of the spacer grid effects on turbulent flow structure by using an LDV(Laser Doppler Velocimeter). The measured parameters are axial velocity and turbulent intensity, skewness factor, and flatness factor. Pressure drops were also measured to evaluate the loss coefficient for the spacer grid and the friction factor for rod bundles. From these data, it was found that the turbulent mixing and forced mixing occur up to $x/D^h=10$ and 20 from the spacer grid, respectively. The turbulence decay behind spacer grid behaves in the similar decay rate as turbulent flow through mesh grids or screens. Mixing factors useful in subchannel analysis code were correlated from the data and show the highest value near spacer grid and then have a stable values.

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Effects of Plasma Surface Treatments Using Dielectric Barrier Discharge to Improve Diamond Films

  • Kang, In-Je;Ko, Min-Guk;Rai, Suresh;Yang, Jong-Keun;Lee, Heon-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.552-552
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    • 2013
  • In our study we consider Al2O3 ceramic substrates for Plasma Surface Treatments in order to improve deposited diamond surface and increase diamond deposition rate by applying DBD (Dielectric Barrier Dischrge) system. Because Plasma Surface Treatments was used as a modification method of material surface properties like surface free energy, wettability, and adhesion. By applying Plasma Surface Treatments diamond films are deposited on the Al2O3 ceramic substrates. DC Arc Plasmatron with mathane and hydrogen gases is used. Deposited diamond films are investigated by SEM (Scanning Electron Microscopy), AFM (Atomic Force Microscopy) and XRD (X-ray Diffractometer). Then the C-H stretching of synthetic diamond films by FTIR (Fourier Transform Infrared Spectroscopy) is studied. As a result, nanocrystalline diamond films were identified by using SEM and diamond properties in XRD peaks at (111, $43.8{\Box}$, (220, $75.3{\Box}$ and (311, $90.4{\Box}$ were shown. Absorption peaks in FTIR spectrum, caused by CHx sp3 bond stretching of CVD diamond films, were identified as well. Finally, we improved such parameters as depostion rate ($2.3{\mu}m$/h), diamond surface uniformity, and impurities level by applying Plasma Surface Treatments. These experimental results show the importance of Plasma Surface Treatments for diamond deposition by a plasma source.

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Study on the Determination of Fatigue Damage Parameter for Rubber Component under Multiaxial Loading (다축하중이 작용하는 방진고무부품 피로손상 파라미터 결정에 관한 연구)

  • Moon, Seong-In;Woo, Chang-Su;Kim, Wan-Doo
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.194-200
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    • 2012
  • Rubber components have been widely used in automotive industry as anti-vibration components for many years. These subjected to fluctuating loads, often fail due to the nucleation and growth of defects or cracks. To prevent such failures, it is necessary to understand the fatigue failure mechanism for rubber materials and to evaluate the fatigue life for rubber components. The objective of this study is to develop the durability analysis process for vulcanized rubber components, which is applicable to predict fatigue life at initial product design step. The determination method of nonlinear material constants for FE analysis was proposed. In order to investigate the applicability of the commonly used damage parameters, fatigue tests and corresponding finite element analyses were carried out and strain energy density was proposed as the fatigue damage parameter for rubber components. The fatigue analysis for automotive rubber components was performed and the durability analysis process was reviewed.

Polarization of Rayleigh Scattered Lyα in Active Galactic Nuclei

  • Chang, Seok-Jun;Lee, Hee-Won;Yang, Yujin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.70.3-70.3
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    • 2016
  • Active galactic nuclei (AGNs) typically show a non-thermal continuum locally represented by a power-law and many prominent emission lines in the UV and optical regions. AGNs are classified by two types, where Type I AGNs exhibit both broad and narrow lines and only narrow lines are observed in Type 2 AGNs. The unification models of AGNs invoke the existence of a molecular torus just outside of the broad line region. In the presence of a high column HI region associated with the molecular torus, we propose that significant fraction of broad line photons near Lyman series can be scattered by atomic hydrogen in the torus. In particular, $Ly{\alpha}$ being the strongest emission line, strong linear polarization may develop around $Ly{\alpha}$ through Rayleigh scattering. We adopt a Monte Carlo technique to investigate the polarized transfer of $Ly{\alpha}$ in a thick HI region with the shape of a torus. We consider the range of HI column density N_HI = 1020-23 with fixed geometric parameters of the torus such as the inner and outer radii and the height. We present the polarized spectra and angular distribution of Rayleigh scattered radiation around $Ly{\alpha}$. We find that the $Ly{\alpha}$ core part is polarized in the direction perpendicular to the symmetry axis whereas in the far wing part it is polarized in the parallel direction. It is concluded that the unification of AGNs implies that $Ly{\alpha}$ can be uniquely polarized through Rayleigh scattering.

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Method for Determination of Maximum Allowable Pressure of Pressure Vessel Considering Detonation (폭굉을 고려한 압력용기 최대허용압력 결정방법의 제안)

  • Choi, Jinbok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.5
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    • pp.235-241
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    • 2018
  • The internal pressure is a critical parameter for designing a pressure vessel. The static pressure that a pressure vessel must withstand is usually determined according to the various codes and standards with simple formula or numerical simulations considering the geometric parameters such as diameter and thickness of a vessel. However, there is no specific codes or technical standards we can use practically for designing of pressure vessels which have to endure the detonation pressure. Detonation pressure is a kind of dynamic pressure which causes an impulsive pressure on the vessel wall in a extremely short time duration. In addition, it is known that the magnitude of reflected pressure at the vessel wall due to the explosion can be over twice the incident pressure. Therefore, if we only consider the reflected pressure, the design of the pressure vessel can be too conservative from the economical point of view. In this study, we suggest a practical method to evaluate the magnitude of maximum allowable pressure that the pressure vessel can withstand against the detonation inside a vessel. As an example to validate the proposed method, we consider the pressure vessel containing hydrogen gas.

A Dual Triangular Pyramidal Indentation Technique Based on FEA Solutions for Material Property Evaluation (유한요소해에 기초한 이중 삼각뿔 압입 물성평가법)

  • Kim, Min-Soo;Hyun, Hong-Chul;Lee, Jin-Haeng;Lee, Hyung-Yil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.1
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    • pp.17-28
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    • 2012
  • In this study, we suggest a method for material property evaluation by dual-triangular pyramidal indenters using the reverse analysis. First, we demonstrated that load-displacement curves of conical and triangular pyramidal indenters are different for the same material. For this reason, an independent research on the triangular pyramidal indenter is needed. From FE indentation analyses on various materials, we then investigated the relationships among material properties, indentation parameters and load-displacement curves. From this, we established property evaluation formula using dual-triangular pyramidal indenters having two different half-included-angles. The approach provides the values of elastic modulus, yield strength and strain-hardening exponent within an average error of 3% for various materials.

Synthesis and Oxygen Reduction Reaction Characteristics of Multi-Walled Carbon Nanotubes Supported PtxM(1-x) (M = Co, Cu, Ni) Alloy Catalysts for Polymer Electrolyte Membrane Fuel Cell (다중벽 탄소 나노 튜브에 담지한 PtxM(1-x)(M = Co, Cu, Ni) 합금촉매의 제조 및 고분자 전해질 연료전지에서 산소환원 특성)

  • Jung, Dong-Won;Park, Soon;Ahn, Chi-Yeong;Choi, Seong-Ho;Kim, Jun-Bom
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.667-673
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    • 2009
  • The electrocatalytic characteristics of oxygen reduction reaction of the $PtxM_{(1-x)}$ (M = Co, Cu, Ni) supported on multi-walled carbon nanotubes (MWNTs) have been evaluated in a Polymer Electrolyte Membrane Fuel Cell (PEMFC). The $Pt_xM_{(1-x)}$/MWNTs catalysts with a Pt : M atomic ratio of about 3 : 1 were synthesized and applied to the cathode of PEMFC. The crystalline structure and morphology images of the $Pt_xM_{(1-x)}$ particles were characterized by X-ray diffraction and transmission electron microscopy, respectively. The results showed that the crystalline structure of the Pt alloy particles in Pt/MWNTs and $Pt_xM_{(1-x)}$/MWNTs catalysts are seen as FCC, and synthesized $Pt_xM_{(1-x)}$ crystals have lattice parameters smaller than the pure Pt crystal. According to the electrochemical surface area (ESA) calculated with cyclic voltammetry analysis, $Pt_{0.77}Co_{0.23}$/MWNTs catalyst has higher ESA than the other catalysts. The evaluation of a unit cell test using Pt/MWNTs or $Pt_xM_{(1-x)}$/MWNTs as the cathode catalysts demonstrated higher cell performance than did a commercial Pt/C catalyst. Among the MWNTs-supported Pt and $Pt_xM_{(1-x)}$ (M = Co, Cu, Ni) catalysts, the $Pt_{0.77}Co_{0.23}$/MWNTs shows the highest performance with the cathode catalyst of PEMFC because they had the largest ESA.

Effects of Process Parameters on Formation of TiN Coating Layer in Small Holes by PACVD (PACVD 방법으로 TiN 코팅시 공정변수가 작은 동공 내부의 코팅층 형성에 미치는 영향)

  • Kim, Deok-Jae;Jo, Yeong-Rae;Baek, Jong-Mun;Gwak, Jong-Gu
    • Korean Journal of Materials Research
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    • v.11 no.6
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    • pp.441-447
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    • 2001
  • A study on the TiN coating layer in small holes on the Purpose of die-casting dies application has been performed with a PACVD process. For the hole having diameter of 4 mm. the uniform TiN coating layer in the hole to the depth of 20 mm was achieved using DC pulsed power source. To understand the forming mechanism of TiN coating layer, plasma diagnosis on Ti, $N_{2}^{+}$ and A $r^{+}$ emissions was carried out during plasma coaling process by optical emirssion spectroscopy. When the duty ratio was equal or over 50%, the Peaks of Ti,$ N_{2}^{+}$ and A $r^{+}$ emission were obviously observed. While duty ratio was equal or under 28.6%, no peaks for Ti, $N_{2}^{+}$ and A $r^$ were observed and the formation of TiN coating layer was rarely observed. For the coating in 4 mm hole diameter, the coating layer with bipolar process was two times deeper than that with unipolar process.

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Role of the Salt Bridge Between Arg176 and Glu126 in the Thermal Stability of the Bacillus amyloliquefaciens ${\alpha}$-Amylase (BAA)

  • Zonouzi, Roseata;Khajeh, Khosro;Monajjemi, Majid;Ghaemi, Naser
    • Journal of Microbiology and Biotechnology
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    • v.23 no.1
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    • pp.7-14
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    • 2013
  • In the Bacillus amyloliquefaciens ${\alpha}$-amylase (BAA), the loop (residues 176-185; region I) that is the part of the calcium-binding site (CaI, II) has two more amino acid residues than the ${\alpha}$-amylase from Bacillus licheniformis (BLA). Arg176 in this region makes an ionic interaction with Glu126 from region II (residues 118-130), but this interaction is lost in BLA owing to substitution of R176Q and E126V. The goal of the present work was to quantitatively estimate the effect of ionic interaction on the overall stability of the enzyme. To clarify the functional and structural significance of the corresponding salt bridge, Glu126 was deleted (${\Delta}$E126) and converted to Val (E126V), Asp (E126D), and Lys (E126K) by site-directed mutagenesis. Kinetic constants, thermodynamic parameters, and structural changes were examined for the wild-type and mutated forms using UV-visible, atomic absoption, and fluorescence emission spectroscopy. Wild-type exhibited higher $k_{cat}$ and $K_m$ but lower catalytic efficiency than the mutant enzymes. A decreased thermostability and an increased flexibility were also found in all of the mutant enzymes when compared with the wild-type. Additionally, the calcium content of the wild-type was more than ${\Delta}E126$. Thus, it may be suggested that ionic interaction could decrease the mobility of the discussed region, prevent the diffusion of cations, and improve the thermostability of the whole enzyme. Based on these observations, the contribution of loop destabilization may be compensated by the formation of a salt bridge that has been used as an evolutionary mechanism or structural adaptation by the mesophilic enzyme.

Study on ZnO Thin Film Irradiated by Ion Beam as an Alignment Layer (배향막 응용을 위한 이온 빔 조사된 ZnO 박막에 관한 연구)

  • Kang, Dong-Hoon;Kim, Byoung-Yong;Kim, Jong-Yeon;Kim, Young-Hwan;Kim, Jong-Hwan;Han, Jeong-Min;Ok, Chul-Ho;Lee, Sang-Keuk;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.430-430
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    • 2007
  • In this study, the nematic liquid crystal (NLC) alignment effects treated on the ZnO thin film layers using ion beam irradiation were successfully studied for the first time. The ZnO thin films were deposited on indium-tin-oxide (ITO) coated glass substrates by rf-sputter and The ZnO thin films were deposited at the three kinds of rf power. The used DuoPIGatron type ion beam system, which can be advantageous in a large area with high density plasma generation. The ion beam parameters were as follows: energy of 1800 eV, exposure time of 1 min and ion beam current of $4\;mA/cm^2$ at exposure angles of $15^{\circ}$, $30^{\circ}$, $45^{\circ}$, and $60^{\circ}$. The homogeneous and homeotropic LC aligning capabilities treated on the ZnO thin film surface with ion beam exposure of $45^{\circ}$ for 1 min can be achieved. The low pretilt angle for a NLC treated on the ZnO thin film surface with ion beam irradiation for all incident angles was measured. The good LC alignment treated on the ZnO thin film with ion beam exposure at rf power of 150 W can be measure. For identifying surfaces topography of the ZnO thin films, atomic force microscopy (AFM) was introduced. After ion beam irradiation, test samples were fabricated in an anti-parallel configuration with a cell gap of $60{\mu}m$.

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