• Journal of Korean Society for Atmospheric Environment
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• v.21 no.E3
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• pp.87-94
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• 2005

Wet scavenging by rain drops is a most important removal process of air pollutants. In order to study the scavenging mechanisms of aerosol particles, the characteristics of chemical components in the rain water were examined as a function of the amount of rainfall. Rain water were collected continuously and separated into the soluble and insoluble components. The elemental concentrations in both components were determined by a PIXE analysis. The physical and chemical characteristics of atmospheric aerosols during the rainfall events were measured simultaneously. The elemental concentrations in rain water decreased substantially just after rain started and then gradually declined in subsequential rain fall exceeding 1.0 mm. The large particles were scavenged more easily than the fine particles. Fe, Ti and Si in rain water were in high insoluble state. Contrarily, almost whole of S was dissolved in rain water.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.2
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• pp.294-305
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• 2018

Quantitative assessment on the impact from North Korean emissions to surface particulate matter(PM) concentration in the Seoul Metropolitan Area (SMA), South Korea is conducted using a 3-dimensional chemistry transport model. Transboundary transport of air pollutants and their precursors are important to understand regional air quality in East Asian countries. As North Korea locates in the middle of main transport pathways of Chinese pollutants, quantifiable estimation of its impact is essential for policy making in South Korean air quality management. In this study, the Community Multiscale Air Quality Modeling System is utilized to simulate regional air quality and its sensitivity, using the Comprehensive Regional Emissions inventory for Atmospheric Transport Experiment 2015 and the Clean Air Policy Support System 2013 emissions inventories for North and South Korea, respectively. Contributions were estimated by a brute force method, perturbing 50% of North and South Korean emissions. Simulations demonstrate that North Korean emissions contribute $3.89{\mu}g/m^3$ of annual surface PM concentrations in the SMA, which accounts 14.7% of the region's average. Impacts are dominant in nitrate and organic carbon (OC) concentrations, attributing almost 40% of SMA OC concentration during January and February. Clear seasonal variations are also found in North Korean emissions contribution to South Korea (and vice versa) due to seasonal characteristics of synoptic weather, especially by the change of seasonal flow patterns.

• Asian Journal of Atmospheric Environment
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• v.7 no.4
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• pp.177-190
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• 2013

Air pollution trends in Japan between 1970 and 2012 were analyzed, and the impact of air pollution countermeasures was evaluated. Concentrations of CO decreased from 1970 to 2012, and in 2012, the Japanese environmental quality standard (EQS) for CO was satisfied. Concentrations of $SO_2$ dropped markedly in the 1970s, owing to use of desulfurization technologies and low-sulfur heavy oil. Major reductions in the sulfur content of diesel fuel in the 1990s resulted in further decreases of $SO_2$ levels. In 2012, the EQS for $SO_2$ was satisfied at most air quality monitoring stations. Concentrations of $NO_2$ decreased from 1970 to 1985, but increased from 1985 to 1995. After 1995, $NO_2$ concentrations decreased, especially after 2006. In 2012, the EQS for $NO_2$ was satisfied at most air quality monitoring stations, except those alongside roads. The annual mean for the daily maximum concentrations of photochemical oxidants (OX) increased from 1980 to 2010, but after 2006, the $98^{th}$ percentile values of the OX concentrations decreased. In 2012, the EQS for OX was not satisfied at most air quality monitoring stations. Non-methane hydrocarbon (NMHC) concentrations generally decreased from 1976 to 2012. In 2011, NMHC concentrations near roads and in the general environment were nearly the same. The concentration of suspended particulate matter (SPM) generally decreased. In 2011, the EQS for SPM was satisfied at 69.2% of ambient air monitoring stations, and 72.9% of roadside air-monitoring stations. Impacts from mineral dust from continental Asia were especially pronounced in the western part of Japan in spring, and year-round variation was large. The concentration of $PM_{2.5}$ generally decreased, but the EQS for $PM_{2.5}$ is still not satisfied. The air pollution trends were closely synchronized with promulgation of regulations designed to limit pollutant emissions. Trans-boundary OX and $PM_{2.5}$ has become a big issue which contains global warming chemical species such as ozone and black carbon (so called SLCP: Short Lived Climate Pollutants). Cobeneficial reduction approach for these pollutants will be important to improve both in regional and global atmospheric environmental conditions.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.422-423
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• 1999

최근 저유황 연료유의 공급과 청정연료의 사용 등으로 인해 1차 오염물질은 점차 줄어드는 추세에 있는 반면, 늘어나는 자동차와 급속한 산업화로 산업시설에서 배출되는 질소산화물과 탄화수소류, 휘발성 유기화합물(VOC) 등이 복잡한 광화학 반응을 통해 2차 오염물질을 생성함으로 대기오염의 문제가 심각하다.(중략)

• Journal of Environmental Science International
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• v.22 no.9
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• pp.1213-1226
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• 2013

$PM_{10}$ concentration is related to the meteorological variables including to local and synoptic meteorology. In this study the $PM_{10}$ concentrations of Busan in 2007~2011 were analyzed and the days of yellow sand or rainfall which is more than 5 mm were excluded. The sections of $PM_{10}$ concentration were divided according to 10-quantiles, quartiles and 90-quantiles. The 90-quantiles of daily $PM_{10}$ concentration were selected as high concentration dates. In the high concentration dates the daily mean averaged cloudness, mean daily surface wind speed, daily mean surface pressure and PBL height were low and diurnal variation of surface pressure and daily maximum surface temperature were high. When the high $PM_{10}$ dates occurred, the west and south wind blew on the ground and the west wind blew strongly on the 850 hPa. So it seemed that long range transboundary air pollutants made effects on the high concentration dates. The cluster analysis using Hysplit model which is the backward trajectory was made on the high concentration dates. As a result, 3 clusters were extracted and on the short range transboundary cluster the daily mean relative humidity and cloudness were high and PBL height was low.

• Asian Journal of Atmospheric Environment
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• v.11 no.1
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• pp.33-36
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• 2017

China is suffering from severe air pollution especially fine $PM_{2.5}$ pollution. In 2015, the annual average $PM_{2.5}$ concentration of the 338 municipal cities was $50{\mu}g/m^3$, 78% cities at or above the prefectural level failed to comply with the $PM_{2.5}$ concentration standards. The $13^{th}$ Five-Year Plan for National Economic and Social Development set the goal that the annual average concentration of $PM_{2.5}$ in the municipal cities which failed to attain the ambient air quality standards shall be decreased by 18% by 2020 (CCCPC, 2016). In this study, an air pollution control scenario during the $13^{th}$ Five-Year Plan period was proposed and the $SO_2$, $NO_x$ and PM emission reductions in response to different measures in 31 provincial-level regions mainland China by 2020 were estimated. The air quality in the target year (2020) was simulated using the WRF-CMAQ model. The results showed that by 2020, the emissions of $SO_2$, $NO_x$ and primary PM in mainland China will be reduced by 4.19 million tons, 3.94 million tons and 4.41 million tons, a drop of 23%, 21% and 25% respectively compared with that in 2015, and the annual average concentration of $PM_{2.5}$ will decrease by 19%. Coal-fired power plant contributes the most pollutant emission reduction.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.1
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• pp.35-42
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• 1998

We compared absorption and adsorption rates of air pollutants by plants to eveluate the difference of absorption capacity of plant species and kinds of air pollutants, when foilage plants were exposed to $O_3$ and $SO_2$ singly and combiningly. Absorption and adsorption rates of three foliage plants exposed to $O_3$ and $SO_2$ singly and in combination varied a little according to plant species and kinds of air pollutants. But total absorption rate of Spathiphyllum patinii and Ficus benjamina was higher, and it was lower in Pachira aquatica. When exposed to $O_3$ and $SO_2$ at the same concentration, Pachira aquatica absorbed more $O_3$ than $SO_2$, in contrast to Ficus benjamina absorbing more $SO_2$. On the other hand, Spathiphyllum patinii absorbed as much $O_3$ as $SO_2$. Physiological activities were measured since absorption rates were affected by physiological characteristics of plants. Spathiphyllum patinii and Ficus benjamina showed higher photosynthetic and transpiration rates, and Pachira aquatica showed lower values. And diffusive and stomatal resistences of Pachira aquatica were higher than those of two other species. These results showed that absorption capacity was affected by the differences of physiological characteristics. Absorption capacity of air pollutants increased in plants, such as Spathiphyllum patinii and Ficus benjamina, which had high $SO_2$ absorption rate. We found that plants showing high $CO_2$ absorption rates absorb a lot of air pollutnats.

• Journal of Environmental Science International
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• v.10 no.2
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• pp.143-151
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• 2001

The atmospheric conditions and the transport mechanism of long-range transport of air pollutants from coastal area to inland area were investigated using regular meteorological data and air pollution data obtatined from the southeastern area of Korea. Daytime temperature over the inland area(Taegu) was higher than that over the coastal area(Pusan) and the temperature difference of about 5~6$^{\circ}C$ when the thermal low most fully developed and the sea level pressure over Taegu was lower than that over Pusan by about 4~5hPa at that time. Therefore this low pressure appeared to the thermally induced low. Air mass polluted from the coastal area during the morning period was transported inland area, at first by the sea breeze and by the large scale wind system toward the thermal low generated in the mountainous inland region. This was explained by the fact that the concentration of air pollutants over Taegu increased throughtout the late afternoon.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.4
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• pp.289-303
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• 2009

The chemical and meteorological effects on the concentration variations of ozone ($O_3$) were evaluated based on the intensive air quality measurement (5 pollutants and aromatic volatile organic compounds (AVOCs)) in and out-side an urban valley during spring and summer of 2006. The 5 pollutants measured in the study area include $O_3$, $NO_2$, NO, $PM_{10}$, and CO; the AVOCs include benzene (BEN), toluene (TOL), ethylbenzene (EB), m,p-xylene (MPX), and o-xylene (OX). For the purpose of this study, study areas were classified into two categories: valley area (VA) with a semi-closed topography covering a number of industrial complex, public building, and mountains and non-valley area (NVA) surrounding the suburban and residential areas. In general, the mean concentration levels of most pollutants (except for $PM_{10}$) in the VA were higher than those in the NVA. It was found that the average $O_3$ increase in the VA during spring might result from the combined effects such as the photochemical production from diverse anthropogenic sources and the $O_3$ accumulation due to geographical features (e.g., the semi-closed topography) and wind conditions (e.g., a low wind speed). In addition, the nocturnal $O_3$ increase in the VA during spring was primarily caused by local wind conditions (e.g., mountain and valley winds) with the low wind speed (approximately $1{\sim}2\;m\;s^{-1}$). On the other hand, the $O_3$ difference between the two areas during summer might be because of the photo-chemical production with the $O_3$ precursors (especially the AVOCs) rather than the contribution of wind conditions.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.6
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• pp.539-546
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• 2002

The physicochemical properties of solid wastes generated from seven highway service areas, four branch offices, and one construction site were analyzed in concert with air pollutants including heavy metals emitted from near-by small-scale incinerators. The amount of solid wastes generated from highway areas has been increasing with recent increases in the number of highways and passengers. Twelve incinerators examined in this study generally had capacity smaller than 100 kg/hr, most of which were equipped with cyclone for dust removal. It was seen that the concentrations of the gas-phase air pollutants (e.g., SO$_2$, NO$_{x}$, HCl and H$_2$S) were above the acceptable emission standards except one or two sites. CO concentrations at all incinerators were also higher due to incomplete combustion. In addition, particulate matters showed concentration six times higher at their maximum. The results of heavy metal analysis showed that the concentrations of Cu, Cd, and Ni satisfied the emission standards. whereas Pb at one site and Zn at five sites exceeded the standards. Cr measurement results indicated that 9 of 12 incinerators had higher values than the standard; especially one branch office showed nine times higher than normal concentration. In order to satisfy more stringent emission standards in the near future, it is necessary to install air pollution control system and to develop an intensified management plan.n.