• 임산에너지
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• 제23권1호
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• pp.19-25
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• 2004

본 연구의 목적은 현재 산림쇠퇴 징후가 나타나고 있는 반월공단지역에 식재되어 있는 잣나무와 리기다소나무의 생장저하 실태와 광합성 특성을 밝히는데 있다. 이를 위해 안산시 전망대공원에 피해구를, 경기도 광주시에 소재하고 있는 경희대학교 연습림에 대조구를 선정하여 인공식재된 약 10년생의 잣나무와 리기다소나무 2수종을 비교하였다. 잣나무 및 리기다소나무 2수종 모두 피해구에서 생장량이 감소하였으며, 침엽의 잔존율도 저하하였다. 또한 2수종 모두 피해구에서 대조구에 비하여 순광합성속도가 저하하였고, 광-광합성곡선의 초기기울기인 양자수율도 저하하였다. 클로로필 a+b, b의 함량도 피해구에서 감소하였으며, 이 결과는 침엽의 연령이 증가함에 따라서 집광운반능력이 낮아져 침엽의 잔존율이 낮아지는 결과를 초래하였다고 생각된다. 이상의 결과로부터 최근 대기오염이 심한 반월공단지역에서 생육하고 있는 잣나무 및 리기다소나무의 생장감소 원인은 침엽의 클로로필 함량이 광화학계의 활성을 저하시켜 광합성 능력이 감소되어 최종적으로 생장감소를 초래한 것으로 판단된다.

• 공업화학
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• 제9권1호
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• pp.115-120
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• 1998

메타세시스에 높은 활성을 나타내는 고분산 레늄촉매을 제조하기 위한 레늄카보닐 침착의 표면화학 및 활성점 생성에 관하여 연구하였다. 알루미나는 773K(PDA)와 1223K(DA)에서 각각 처리하여 담체로 사용하였고, 메타세시스 활성은 순수한 프로펜을 사용하여 상압하의 298K에서 조사하였다. PDA상의 레늄 산화가는 상당히 높았으나, DA에서는 저산화가의 레늄으로 담지되어 있었다. 제조한 Re/DA촉매를 고온에서 열분해시킨 다음 저온에서 산소로 처리하면 메타세시스 활성이 나타났고, 그 활성은 극히 낮은 담지율에서도 Re/PDA이나 통상의 $Re_2O_7/Al_2O_3$촉매에 비해 높은 활성을 보여, 레늄 카보닐을 출발물질로 하고 DA를 사용하는 것이 효과적이었다. 열분해하여 얻은 Re/DA촉매상의 레늄이온은 알루미나의 산소원자 2개와 결합하여 2가를 가지고, 산소처리에 의하여 4가만큼 증가한 6가의 레늄이온이 되며, 메타세시스는 그 6가이온에 의해 생성된 카르벤착체를 통하여 진행됨을 알았다.

• 한국해양공학회지
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• 제21권2호
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• pp.22-34
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• 2007

We present basic data for developing new research topics and closely examine the existing data on the development and organization of the Nakdong River Estuary Delta by analyzing various studies of the area, including ocean engineering, coastal engineering, ocean environmental engineering, geomorphological, and geological studies. We first defined the general concepts related to the estuary and delta and reviewed the historical development of the Nakdong River Estuary Delta over the past 100 years. We then examined the origin and core elements of the estuary deposits that constitute the delta. In addition, we scrutinized the main factors affecting the development of the delta and analyzed existing research on delta development mechanisms by core researchers. The construction of an estuary barrage is one of the main factors effecting estuarine circulation and has altered the physical oceanic environment, area of deposition, atmospheric environment, and vegetation community of the delta. These factors affect the estuary circulation in turn, altering the delta. Along the Nakdong River, an unsteady-state sandy barrier appears at approximately three times the distance of the wavelength of incident offshore waves, and this terrain forms approximately 10-15 years after reclamation in the interdistributary upper stream and transforms the shoreline. It is necessary to develop a technique to predict terrain change that reproduces the erosion and accumulation of estuarine deposits. To determine the parameters and variables necessary to reproduce this system, continuous on-site monitoring is necessary. The existing research did not fully examine the terrain changes in Nakdong River Estuary or the periodic developmental characteristics. To understand the future process of estuary delta development, it is necessary to establish an integrated management system.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.243.1-243.1
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• 2011

We demonstrate a facile and robust layer-by-layer (LbL) assembly method for the fabrication of nonvolatile resistive switching memory (NRSM) devices based on superparamagnetic nanocomposite multilayers, which allows the highly enhanced magnetic and resistive switching memory properties as well as the dense and homogeneous adsorption of nanoparticles, via nucleophilic substitution reaction (NSR) in nonpolar solvent. Superparamagnetic iron oxide nanoparticles (MP) of about size 12 nm (or 7 nm) synthesized with oleic acid (OA) in nonpolar solvent could be converted into 2-bromo-2-methylpropionic acid (BMPA)-stabilized iron oxide nanoparticles (BMPA-MP) by stabilizer exchange without change of solvent polarity. In addition, bromo groups of BMPA-MP could be connected with highly branched amine groups of poly (amidoamine) dendrimer (PAMA) in ethanol by NSR of between bromo and amine groups. Based on these results, nanocomposite multilayers using LbL assembly could be fabricated in nonpolar solvent by NSR of between BMPA-MP and PAMA without any additional phase transfer of MP for conventional LbL assembly. These resulting superparamagnetic multilayers displayed highly improved magnetic and resistive switching memory properties in comparison with those of multilayers based on water-dispersible MP. Furthermore, NRSM devices, which were fabricated by LbL assembly method under atmospheric conditions, exhibited the outstanding performances such as long-term stability, fast switching speed and high ON/OFF ratio comparable to that of conventional inorganic NRSM devices produced by vacuum deposition.

• 한국환경과학회지
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• 제15권5호
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• pp.387-396
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• 2006

The numerical modeling and comparison with observations are performed to find out the detailed structure of meteorology and the characteristic of related dispersion phenomena of the non-reactive air pollutant at Kyoungin region, South Korea, where several industrial complex including Siwha, Banwol and Namdong is located. MM5 (Fifth Generation NCAR/Penn State Mesoscale Model), 3-D Land/sea breeze model and 3-D diagnostic meteorological model have been utilized for the meteorological simulation for September, 2002 with each different spatial resolution, while 3-D Eulerian air dispersion model for the air quality study. We can see the simulated wind field shows the very local circulation quitely well compared with in-site observations in shoreline area with complex terrains, at which the circulation of Land/sea breeze has developed and merged with the mountain and valley breeze eventually. Also it is shown in the result of the dispersion model that the diurnal variation and absolute value of daily mean $SO_2$ concentrations have good agreement with observations, even though the instant concentration of $SO_2$ simulated overestimates around 1.5 times rather than that of observation due to neglecting the deposition process and roughly estimated emission rate. This results may indicate that it is important for the air quality study at shoreline region with the complex terrain to implement the high resolution meteorological model which is able to handle with the complicate local circulation.

• 한국습지학회지
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• 제14권4호
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• pp.657-665
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• 2012

각종 개발사업은 불투수층의 증가를 야기 시켜 자연적 물 순환 왜곡과 함께 비점오염물질의 유출을 증가시킨다. 개발로 인한 환경생태수리학적 영향을 저감하고 건전한 물 순환을 구축하기 위해서는 오염물질의 함량이 적은 유출유량에 대해서는 이용(use)을 고려해 볼 만하며, 오염물질의 함량이 높은 유량에 대해서는 조경공간에서 처리 후 저류, 침투 또는 증발산을 고려하여야 한다. 본 연구는 지붕빗물유출수의 상대적 오염도를 평가하여 이용가능성을 검토하고, 평균 EMC 산정을 위한 비용 효율적 적정 모니터링 기법을 제안하고자 수행되었다. 지붕유출수의 오염도는 도로와 주차장에 비해 오염물질별 3배에서 13배 정도 낮은 것으로 조사되었으며, 나뭇잎, 담배꽁초 등의 협잡물과 바람의 영향으로 인한 오염물질의 대기침적 및 옥상구조물 등이 주요 오염원인 것으로 나타났다. 비용 효율적 모니터링 기법 연구결과 평균 EMC를 보이는 시료는 유출 발생 후 약 15분 경인 것으로 나타났으며, 최소 8회 이상의 강우사상에 대한 모니터링이 수행되어야 평균 EMC를 산정할 수 있는 것으로 나타났다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.94-96
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• 2003

Since 1995, MOCT(Ministry of Construction and Transportation) and KOWACO(Korea Water Resources Corporation) have established the National Groundwater Monitoring Network in South Korea and also MOE(Ministry of Environment) has operated Groundwater Quality Monitoring network. Until 2001, 202 monitoring stations by MOCT and 780 monitoring wells by MOE have been constructed, measured groundwater level and analyzed water samples. Groundwater quality analysis has been conducted two times a year during last 6 years for all monitoring wells. The quality data has about 15 components including pH, COD, Count of Coliform group, and etc.. Trend analysis has been peformed for 6 components(Coliform, pH, COD, NO$_3$-N, Cl and EC) of water quality which are analyzed more than 7 times for total monitoring wells. Two test methods have been used ; Sen's test and Mann-Kendall test. These trend tests have been done at the 0.05 significance level. By the result of Sen's test, Count of Coliform group has either upward or downward trends at 4.3 percent of the monitoring points. pH does at 5.6 percent, COD does at 8.6 percent, Nitrate-Nitrogen does at 13.2 percent, Chloride does at 13.4 percent, and. EC does at 11.6 percent of the monitoring points. The exact causes of the groundwater quality trends are difficult to specify. Notable downward trends in nitrate at many monitoring points may be the result of reduction on some contamination sources. Potential causes include diminished agricultural areas, improvements in sewage treatment and a decrease in atmospheric deposition. Increase in chloride at many monitoring points may be the result of increased non-point source pollution such as road salting and runoff from sprawling paved developments and suburbs.

• 청정기술
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• 제5권2호
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• pp.63-68
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• 1999

The activities of Ni(20wt%)/$La_2O_3$, Ni(20wt%)/${\gamma}-Al_2O_3$, and Ni(20wt%)/$SiO_2$ catalyst for $CO_2$ reforming of $CH_4$ were investigated in a fixed bed flow reactor under atmospheric condition. Catalyst characterization using XRD, TEM, SEM, BET analysis were also conducted. The catalytic activity of Ni(20wt%)/$La_2O_3$ catalyst has relatively superior to that of Ni(20wt%)/${\gamma}-Al_2O_3$ and Ni(20wt%)/$SiO_2$ catalyst. The good activity of Ni(20wt%)/$La_2O_3$ catalyst seems to depend on reduced $Ni^{\circ}$ phases of NiO($\rightarrow$ Ni + O), $LaNiO_3$($\rightarrow$ $Ni+La_2O_3$), Ni crystalline phases, and decoration of Ni phases by lanthanum species is also an important factor. Ni(20wt%)/${\gamma}-Al_2O_3$ and Ni(20wt%)/$SiO_2$ catalyst due to surface acidity resulted in the deposition of wisker type and encapsulate carbon on the surface of catalyst, but Ni(20wt%)/$La_2O_3$ catalyst did not show carbon on the surface of catalyst up to 8.5hr reaction.

• 대기
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• 제29권5호
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• pp.689-698
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• 2019

Air pollution in urban areas has become a serious problem in the recent years. Especially, high concentrations of particulate matter (PM) cause negative effects on human health. Several studies suggest urban forest as a tool for improving air quality because of the capability of forests in reducing PM concentrations through deposition and adsorption using leaf area. For this reason, the National Institute of Forest Science plans to install in-situ observation stations for PM and biogenic volatile organic compounds (BVOCs) on a national scale to verify the net effect of forests on urban air pollution. To measure the quantitative change of PM concentrations due to the urban forest, stations should be located within and outside the forest area with respect to atmospheric circulation. In this study, we analyze the wind direction at the potential measurement sites to assess suitable locations for detecting the effect of urban forests on air quality in five cities (i.e. Gwangju, Daegu, Busan, Incheon, and Ilsan). This technical note suggests effective locations of in-situ measurements by considering main wind direction in the five cities of this study. A measurement station network created in the future based on the selected locations will allow quantitative measurements of PM concentration and BVOCs emitted from the urban forest and help provide a comprehensive understanding of the forest capabilities of reducing air pollution.

• Journal of Radiation Protection and Research
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• 제27권3호
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• pp.171-179
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• 2002

대기 중으로 방출된 방사성물질의 이동 확산 현상을 이해하기 위하여 3차원 장거리 확산 모델이 개발되었다. 모델은 수평방향으로 방출점으로부터 수천 키로 미터의 거리까지 공기중 농도와 지표면 침적을 계산하도록 설계되었다. 수직 난류운동은 혼합층 내와 혼합층 위로 분리하도록 고려하였다. 시험계산은 동북 아시아권의 영역을 고려하였고, 방출점은 중국의 동쪽 지점을 가정하였다. 계산된 농도분포는 바람장에 의해 방출점의 남동방향을 향해 주로 이동되었다. 개발된 모델은 원전 사고시 방사선 피해를 추정하기 위하여 이용될 것이며, 모델은 장거리 야외확산실험의 자료를 이용하여 비교 검증 연구를 통하여 보완될 것이다.