• Title/Summary/Keyword: Atmospheric composition

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Characterization of Individual Atmospheric Particles, Collected in Susan, Korea, Using Low-Z Electron Probe X-ray Microanalysis (Low-Z Electron Probe X-ray Microanalysis 분석법을 이용한 해안인근 지역의 대기입자 분석)

  • 김혜경;노철언
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.5
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    • pp.503-513
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    • 2003
  • A single particle analytical technique, called low-Z electron probe X-ray microanalysis (low-Z EPMA) was applied to characterize atmospheric particles collected in Busan, Korea, over a daytime period in Dec. 2001. The ability to quantitatively analyze the low-Z elements, such as C, N, and 0, in microscopic volume enables the low-Z EPMA to specify the chemical composition of individual atmospheric particle. Various types of atmospheric particles such as organics, carbon-rich, aluminosilicates, silicon oxide, calcium carbonate, iron oxide, sodium chloride, sodium nitrate, ammonium sulfate, and titanium oxide were identified. In the sample collected in Busan, sodium nitrate particles produced as a result of the reaction between sea salt and nitrogen oxides in the atmosphere were most abundantly encountered both in the coarse and fine fractions. On the contrary, original sea salt particles were rarely observed. The fact that most of the carbonaceous particles were distributed in the fine fraction implies that their origin is anthropogenic.

Environmental Geochemistry of Atmospheric Mercury: Its Backgriound Concentrations and Exchange Across the Air-Surface Interface (대기수은의 환경지화학: 배경농도측정 및 대기-지표면간의 교환작용)

  • 김기현
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.2
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    • pp.189-198
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    • 1996
  • Mercury (Hg) is ubiquitous throughout the earth's atmosphere. The uniqueness of its atmospheric geochemistry is well-known with the high environmental mobility and relatively long atmospheric residence time (c.a., 1 year) associated with its high chemical stability. Despite a growing recognition of the environmental significance of its global cycling, the prexisting Korean database for atmospheric Hg is extremely rare and confined to a number of concentration measurements conducted under relatively polluted urban atmospheric environments. To help activate the research on this suvject, an in-depth analysis on the current development in the measurements of atmospheric mercury and the associated fluxes has been made using the most using the most updated data ests reported worldwide. As a first step toward this purpose, the most reliable techniques commonly employed in the measurements of its concentration in the background atmosphere are introduced in combination with the flux measurement techniques over soil surface such as: dynamic enclosure (or field flux chamber) method and field micrometeorological method. Then the results derived using these measurement techniques are discussed and interpreted with an emphasis on its mobilization across the terrestrial biosphere and atmosphere interface. A unmber of factors including air/soil temperature, soil chemical composition, soil water content, and barometric pressure are found out to be influential to the rate and amount of such exchange processes. Although absolute magnitude of such exchange processes is insignificant relative to that of the major component like the oceanic environment, this exchange process is thought to be the the predominant natural pathway for both the mobilization and redistribution of atmospheric Hg on a local or regional scale.

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Soil Chemical Properties in Asian Dust Source region in Northern China (황사발생지역에서 토양입자의 화학적 특성)

  • Han, J.S.;Shin, Sun-A;Kong, B.J.;Park, M.S.;Park, S.U.;Kim, S.J.
    • Journal of Environmental Impact Assessment
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    • v.13 no.6
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    • pp.277-284
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    • 2004
  • The chemical composition and properties of soil were determined at selected sites, such as Loess plateau, Gobi and sand deserts in northern China, where most dust storms occur. Although the transport of this sort of dust storms to Korean peninsula is a well-documented phenomenon, there is not enough information about the very source regions. In this reason, this study tried to measure the chemical composition, including soil elements, anthropogenic elements and ions for soil samples so that certain properties of some major source regions of Asian Dust can be provided. Furthermore, the results are classified into four types of soil like Loess, Loess & sand, Gobi, and sand in order to identify the characteristics and difference among the types. $(X/Al)_{crust}$ values for each soil type were also calculated in this study and compared with those of other references including Asian Dust material(ADM). The results indicated that Ca contribution was higher than Al in all the soil types of this study including ADM and, compared with the values of urban area, contribution of anthropogenic elements such as Cr, Pb, Zn was quite low. However, it must be noted that there is such a variation in the result of soil composition, but it is also certain that the very source region soil composition resolved from this study could support the enhanced study on Asian Dust phenomenon in Korea.

A Study on the storage of Fresh Fruits and Vegetables (Part II) Effects of Intercellular atmosphere and Ethylene evolution by control of external pressure and gas composition in Apple Fruits. (청과물 저장에 관한 연구(제 2보) -사과 저장에 있어서 환경압력 및 기체조성이 사과조직내 기체조성과 Ethylene 생성에 미치는 영향-)

  • 손태화;최종욱;서온수
    • Microbiology and Biotechnology Letters
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    • v.1 no.1
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    • pp.25-30
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    • 1973
  • Experiments were carried out to clarify changes of intercellular gas composition, respiration and ethylene evolution by controlled external atmospheric pressure and external gas composition on apples. Jonathan apples, harvested 25, in September and Rolls apples, harvested 25, in October, 1971 and 1972 were used. Results obtained were as follows: 1. Intercellular gas volumes were proportionally changed by the given pressure, and the given pressure remarkably affected internal gas composition and volume of apples. As intercellular gas volumes were reached in their equilibrium within 5 min. after treatment, the internal atmospheric conditions became constant rapidly. 2. The increase of internal $CO_2$ production was co-related with an amount of internal $O_2$ consumption, therefore, the decreasing period of internal $O_2$ consumption was equalled to the period of climacteric rise in respiration. 3. The increasing of $CO_2$ production followed evolution of $C_2$H$_4$ and this phenomenon on SAP part. was subsequent to NAP part 4. In sub-atmospheric storage, CA effect was also obtained by control of low $O_2$ and high $CO_2$ concentration.

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Chemical Composition and Sources of Atmospheric Particulates Collected on the West Coast of Korea (서해안 대가 분진의 화학 조성 및 기원에 대한 연구 (1))

  • 최만식;조성록;이동수
    • Journal of Korean Society for Atmospheric Environment
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    • v.5 no.2
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    • pp.72-83
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    • 1989
  • Twenty-five atmospheric particulates were collected using a high volume aerosol sampler from Septermber to December, 1988 on a site located on the West coast of Korea and analysed for twelve elements (Na, Mg, Al, Mn, Fe, Cu, Co, Ni, Zn, Ag, Cd, and Pb) by AAS. The particles being mainly crustal minerals, large quantity of spherical fly ashes were also observed. In order to identify the origin of trace metals in atmospheric particulates, enrichment factor, interelemental correlation and factor analysis were performed. Based upon these analysis, the twelve elements can be classified into three groups; the elements dominantly present in soil particles (Al, Mn, Fe, Co, and Ni), those in sea salt aerosols (Na and Mg), and those in air pollution-derived particles (Cu, Cd, Pb, Ag and Zn).

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A Study on the Storage of Fresh Fruits and Vegetables (I) -Changes of the Internal Atmosphere in Storage Room and the Biochemical Changes of Apple Fruits by Controlled Ventilation- (청과물 저장에 관한 연구(제1보) -통기량 조절에 따른 저장실내 기체조성 및 생리화학적 변화에 대하여-)

  • Sohn, Tae-Hwa;Choi, Jong-Uck;Kim, Sung-Dal
    • Korean Journal of Food Science and Technology
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    • v.4 no.1
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    • pp.13-17
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    • 1972
  • This experiment was conducted to observe the changes of composition of atmosphere in storage room by controlled ventilation under normal and sub-atmospheric conditions, and the biochemical changes in apple texture under these conditions. The results were as follows; 1) By controlled ventilation, concentration of carbon dioxide in storage room was optionally regulated and constantly maintained. 2) Among compositions of internal atmosphere of apple, especially, concentration of ethylene was much decreased at apple stored under sub-atmospheric condition than that stored under normal atmospheric condition. 3) Acidity of apple stored under sub-atmospheric condition was much greater than that of apple stored under normal atmospheric condition. 4) Respiratory quotients of apple, which was stored under normal and sub-atmospheric conditions, were shown to be high. But decarboxylation of added pyruvate was found more active in slices prepared from apple stored under sub-atmospheric condition.

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Size-segregated Sources of Aerosol Estimated by Factor Analysis-For the Measurement using Drum Impactor at Gosan, Jeju Island in May 2002 (인자분석을 통한 대기 입자상 물질의 입경별 발생원 추정-Drum impactor를 이용한 2002년 5월 제주도 고산지역 측정을 중심으로)

  • Han, J.S.;Moon, K.J.;Kong, B.J.;Ryu, S.Y.;Kim, Y.J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.5
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    • pp.685-695
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    • 2004
  • Size-segregated measurements of aerosol composition are used to estimate the transport of natural and anthropogenic aerosols at Gosan site during May 2002. The results of measurement show that not only soil dust but also anthropogenic aerosols, including sulfur and enriched trace metals such as Pb, Zn, Cu, are transported to Gosan. This study combines the size- and time-resolved aerosol composition measurements with factor analysis in order to identify some source materials. As a result, coarse particles (2.5${\mu}m$~12${\mu}m$) are influenced by soil, sea-salt, coal, coal combustion, and nonferrous sources. But fine particles have different sources. The fine particles, which the diameter is from 0.56${\mu}m$ to 2.5${\mu}m$, are more affected by road dust, oil combustion, industry. municipal incineration, and ferrous metal sources. The very fine particles, from 0.09${\mu}m$ to 0.56${\mu}m$, mainly supplied by biomass burning, oil combustion, nonferrous and ferrous metal sources.

Microstructure and Tribological Properties along with Chemical Composition and Size of Initial Powder in Fe-based BMG Coating through APS (대기 플라즈마 용사공정을 이용한 Fe계 벌크 비정질 금속 코팅의 초기 분말의 화학조성과 크기에 대한 미세 조직 및 마모 특성)

  • Kim, Jung-Hwan;Yoon, Sang-Hoon;Na, Hyun-Taek;Lee, Chang-Hee
    • Journal of the Korean institute of surface engineering
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    • v.41 no.5
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    • pp.220-225
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    • 2008
  • In this study, two kinds of Fe-based bulk metallic glasses (BMG) powder were built-up through atmospheric plasma spray (APS) technique. The microstructure of two coatings was analyzed through X-ray diffraction, scanning electron microscopy and transmission electron microscopy. Crystallization and oxidation in coatings were affected by chemical composition and initial powder size. Then, both of them influenced the tribological property.

Methodology to Simultaneously Optimize the Inlet Ozone Concentration to Oxidize NO and Relative Humidity Composition for the $NO_x$ Degradation using Soil Bio-filter

  • Cho, Ki-Chul;Hwang, Kyung-Chul
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.E2
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    • pp.83-91
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    • 2008
  • This work investigated the methodology to simultaneously optimize the ozone and relative humidity composition for the $NO_x$ degradation using soil biofilter. Experiments were made as a function of inlet ozone concentration ($0{\sim}1,770\;ppb$) and relative humidity ($38{\sim}81%$). Factorial design ($2^2+3$) and response surface methodology by central composite designs were used to examine the role of two factors and optimal response condition on $NO_x$ degradation. It was found that a second-order response surface model can properly interpret the experimental data with an $R^2$-value of 0.9730 and F-value of 71.83, based on which the maximum $NO_x$ degradation was predicted up to 92.8% within our experimental conditions.