• Title/Summary/Keyword: Atmosphere Temperature

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Microstructure and dielectric properties with a contents Ca of (Sr.Ca)$TiO_3$-based grain boundary layer ceramics ((Sr.Ca)$TiO_3$계 입계층 세라믹의 Ca변화량에 따른 미세구조 및 유전특성)

  • 최운식;김충혁;이준웅
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.534-542
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    • 1994
  • Microstructures and dielectric properties of (Sr$_{1-x}$ .Ca$_{x}$)TiO$_{3}$+0.006Nb$_{2}$O$_{5}$ (0.05.leq.x.leq.0.2) ceramic were investigated. The specimens fired in a reducing atmosphere(N$_{2}$) were painted on the surface with CuO paste, and then annealed at 1100.deg. C for 2 hr. SEM and EDAX revealed that CuO penetrated rapidly into the bulk along the grain boundaries during the annealing. Grain size increased with increasing Ca content up to 15[mol%], but decreased with further addition. In the specimens with 10-15[mol%l of Ca, excellent dielectric properties were obtained as follows; dielectric constant <25000, dielectric loss(tan .delta[%]) <0.3[%] and capacitance change rate with temperature <.+-.[%], respectively. All the specimens in this study exhibited dielectric relaxation with frequency as a function of the temperature. The dispersive frequency was over 10$^{6}$ [Hz].z].

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$LiTaO_3$ single crystal growth by the halogen floating zone method I. Growth characteristics of LT single crystals (Halogen floating zone 법에 의한 $LiTaO_3$ 단결정 성장$I.LiTaO_3$단결정 성장특성)

  • 류정호;임창성;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.528-535
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    • 1997
  • $LiTaO_3$ single crystals of congruently melting composition were grown by the halogen lamp type floating zone system. Calcination and sintering parameters for the growth were established. Optimum crystal growth conditions were investigated by a controlling of growth rates, rotation speeds and atmospheres. Based on the melting aspect and the shape of molten zone, stable conditions could not be found in air or Na atmosphere. However the growth stability in Ar atmosphere was more regular than that in air or $N_2$. The grown crystals were characterized using Laue back reflection, Curie temperature, refractive index and transmittance. Curie temperature fluctuation in the section of the grown crystal part of top, body and tail was $1^{\circ}C$.

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Moist Air Density Calculation for Air Condition (공기 상태량에 대한 습공기 밀도 계산)

  • Kim, Jong-Woo
    • Transactions of the KSME C: Technology and Education
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    • v.2 no.2
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    • pp.105-111
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    • 2014
  • Generally the lower part of the Earth's atmosphere, which is 20km above the ground, is called "air." The composition of this area is almost consistent consisting of nitrogen, oxygen, and other gases. Air density refers to the mass per unit volume of earth atmosphere. Though air is made of the mixed gases in a constant composition, the water vapor is one of the very changeable components. The density of moist air is lower than the dry one at the same temperature and pressure. As the density varies according to the pressure and temperature, this paper attempts to explore the main factors in the air quantity calculation by examining first the density calculation process according to the air property, and second the relation between the actual and standard air flow.

Precision Validation of GPS Precipitable Water Vapor via Comparison with MWR Measurements (MWR 관측치와 비교를 통한 GPS 가강수량 정밀도 검증)

  • Ha, Jihyun;Park, Kwan-Dong;Chang, Ki-Ho;Yang, Ha-Young
    • Atmosphere
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    • v.17 no.3
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    • pp.291-298
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    • 2007
  • The precipitable water vapors (PWVs) obtained from Global Positioning System (GPS) and Microwave Radiometer (MWR) measurements have been compared for validation of precision of the GPS PWV at Daegwallyoung station for 21 days from Sep. 30 to Oct. 20, 2006. The GPS PWV is estimated using the delay of GPS signals due to the water vapor in the atmosphere with a local mean temperature equation, called HP model, and the MWR PWV by the combinational radiance observation of two channels (23.8 and 31.4 GHz). During the co-observation period, the MWR and GPS PWV show a similar trend, and the bias between the PWVs is 1.7 mm on average. When the bias is removed, the PWV of GPS gives good agreement with that of MWR, having about 1 mm for both the standard deviation and RMS error between the GPS and MWR PWV.

Gas-particle Partitioning of Organochlorine Pesticides in Atmosphere (대기 중 유기염소계 살충제의 가스-입자 분배)

  • Choi, Min-Kyu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.4
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    • pp.457-465
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    • 2007
  • This study was performed to estimate the gas-particle partitioning of organochlorine pesticides (OCPs) in atmosphere, the samples were collected by PUF high volume air sampler for two years from June, 2000 to June, 2002. The gas phase fraction of ${\alpha/\gamma}-HCH$, heptachlor epoxide, ${\alpha/\gamma}-chlordane$ and trans-nonachlor was over 90%. But the gas phase fraction of ${\beta}-HCH$, p,p'-DDE, endosulfan sulfate, p,p'-DDD and p,p'-DDT was range of 20% through 80%, which means the gas phase fraction of OCPs components described above is sensitive to temperature. The correlation between the gas phase fraction and molecular weight of each OCPs component was not found in this research. The slope of regression line between gas-particle partitioning coefficient(${\log}K_p$) and subcooled liquid vapor(${\log}{P^o}_L$), gal-particle partitioning coefficient(${\log}K_p$) and octanol-air partitioning coefficient(${\log}K_{oa}$) which show -0.54 and 0.43 was not steep. So the equilibrium state between gas and particle was not reached and in this state the particulate fraction was low.

Effects of Sintering Temperature and Atmosphere on Densification of Hypereutectic Al-Si Alloy Powders (Al-20Si-5.5Fe-1.2Mg-0.5Mn 합금분말의 치밀화에 미치는 소결온도와 분위기의 영향)

  • Lee, Jae-Wook;Park, Sang-Bin;Yang, Sang-Sun;Kim, Yong-Jin
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.196-203
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    • 2008
  • The densification behavior of Al-20Si-5.5Fe-1.2Mg-0.5Mn powders was investigated through micro-structure analysis of sintered specimens. The specimens sintered in vacuum or in high purity (99.999%) nitrogen showed porous near-surface microstructures. The densification of near-surface part was enhanced by means of ultra-high purity (99.9999%) nitrogen atmosphere. The relationship between slow densification and oxide surfaces of Al alloy powders was discussed. And the effects of Mg addition, nitrogen gas, and humidity on densification were discussed. In addition, the rapid growth of primary Si crystals above the critical temperature was reported.

Variation Pattern of Gaseous Organochlorine Pesticides Concentration in Atmosphere (대기 중에서 가스상 유기염소계 농약의 농도변화 패턴)

  • Choi, Min-Kyu;Chun, Man-Young
    • Environmental Analysis Health and Toxicology
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    • v.22 no.2 s.57
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    • pp.111-118
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    • 2007
  • This study was performed to measure gaseous Organochlorine Pesticides (OCPs : heptachlor epoxide, ${\alpha}/{\gamma}-chlordane$, trans-nonachlor, endosulfan, ${\gamma}-HCH$ and p, p'-DDE) concentration using PUF high volume sampler from June, 2000 to June, 2002 in the semi-rural atmosphere. Using monitoring data for two years, we tried to investigate the annual cycles of gaseous OCPs. We considered three functions to describe the annual cycle: Gaussian, Lorentzian and sinusoidal functions. These functions accounted for $54{\sim}91%$ of the variability in concentration for each gaseous OCPs, and the sinusoidal function gave the best fits. It was seen that the gaseous OCPs concentration increased during the warmer weather while decreased during colder weather. The variation of the gaseous OCPs concentration was closely similar to the variations of ambient temperature. The annual cycle of endosulfan was strongly higher than in comparison with other gaseous OCPs, while for ${\gamma}-HCH$, the cycle was weakly high and did not show apparent seasonal variation. The position of the annual maximum exists generally late July to early August. The period that showed levels more than a half maximum was from late June to early September.

Characteristics of thin-film type pressure sensors for high pressure (고압용 박막형 압력센서의 특성)

  • 서정환;최성규;정찬익;류지구;남효덕;정귀상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.737-740
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    • 2001
  • This paper describes the fabrication and characteristics of CrN thin-film type pessure sensors, which the sensing elements were deposited on SUS. 630 diaphragm by DC reactive magnetron sputtering in an argon-nitride atmosphere(Ar-(10%)N$_2$). The optimized condition of CrN thin-film sensing elements was thickness range of 3500${\AA}$ and annealing condition(300$^{\circ}C$, 3 hr) in Ar-10 %N$_2$deposition atmosphere. Under optimum conditions, the CrN thin-films for strain gauges is obtained a high resistivity, $\rho$=1147.65 ${\mu}$$\Omega$cm, a low temperature coefficient of resistance, TCR=-186 ppm/$^{\circ}C$ and a high temporal stability with a good longitudinal, 11.17. The output sensitivity of fabricated CrN thin-film type pressure sensors is 2.36 mV/V, 4∼20 mA and the maximum non-linearity is 0.4 %FS and hysteresis is less than 0.2 %FS.

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Study on the sintering Behavior of Mechanecally Alloyed 75W-25Cu Powder Using a Dilatometry Technique

  • Lee, Seong-;Hong, Moon-Hee;Kim, Eun-Pyo-;Houng-Sub;Noh, Joon-Woong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1992.05b
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    • pp.126-126
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    • 1992
  • Solid and liquid sintering behaviors of mechanically alloyed 75W-25Cu powders have been studied by using a dilatometry technique. The sintering was performed under hydrogen atmosphere of 1 atm with a heating rate of 3 $^{\circ}C$/min. The mechanically alloyed 75W-25Cu powders were prepared by high energy ball milling process under argon atmosphere of 1 atm with alloying times of 0 to 400 h. To compare with the sintering behaviors of mechanically alloyed powders, pure Cu and W powders were also sintered under the above conditions, As the mechanical alloying time increased from 0 to 400 h, the shrinkage behavior of the alloyed powders was enhanced during the sintering, and staring temperature of liquid sintering decreased from 1083 to 1068 $^{\circ}C$. The saturation temperature, above which the shrinkage was completed, of liquid phase sintering decreased from 1248 to 1148 $^{\circ}C$ with increasing mechanical alloying time from 200 to 400 h. The residual stress of the mechanically alloyed powder was measured by X-raydiffractometer. The microstructure of sintered spcimen was observed by optical and scanning electron microscope. From these results, variations of solid and liquid sintering behaviors with mechanical alloying time were discussed in terms of the amount of residual stress and the distribution of W and Cu powders in the mechanically alloyed powder.

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Dielectric Characteristics of $Ta_2O_5$ Thin Films Prepared by ECR-PECVD (ECR-플라즈마 화학 증착법에 의해 제조된 $Ta_2O_5$ 박막의 유전 특성)

  • 조복원;안성덕;이원종
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1330-1336
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    • 1994
  • Ta2O5 films were deposited on the p-Si(100) substrates by ECR-PECVD and annealed in O2 atmosphere. The thicknesses of Ta2O5/SiO2 layers were measured by an ellipsometer and a cross-sectional TEM. Annealing in O2 atmosphere enhanced the stoichiometry of the Ta2O5 film and reduced the impurity carbon content. Ta2O5 films were crystallized at the annealing temperatures above 75$0^{\circ}C$. The best leakage current characteristics and the maximum dielectric constant of Ta2O5/SiO2 film capacitor were observed in the specimen annealed at $700^{\circ}C$ and 75$0^{\circ}C$, respectively. The flat band voltage of the Al/Ta2O5/SiO2/p-Si MOS capacitor was varied in the range of -0.6~-1.6 V with the annealing temperature. The conduction mechanism in the Ta2O5 film, the variation of the effective oxide charge density with the annealing temperature, and the effective electric field distribution in the Ta2O5/SiO2 double layer were also discussed.

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