• Title/Summary/Keyword: Atmosphere Pressure

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The Patterns of Analogy Change and the Characteristics of Discussions in Collaborative Activity of Self-Generated Analogy (협력적 비유 생성 활동에서 나타나는 비유의 변화 유형과 토론의 특징)

  • Kwon, Hyeoksoon;Kim, Minhwan;Kim, Soohyun;Noh, Taehee
    • Journal of The Korean Association For Science Education
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    • v.37 no.3
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    • pp.407-416
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    • 2017
  • In this study, we investigated the processes of analogy change and the characteristics of discussions in collaborative activity of self-generated analogy. Twenty-four high school students in Seoul participated in this study. We implemented science instructions based on collaborative activity of self-generated analogy. We compared personal analogies, group analogies, and modified group analogies in order to analyze the processes of analogy change. We also analyzed the characteristics of group and classroom discussions in the science instructions. The analyses of the results indicated that the processes of analogy change were categorized into three patterns; adding shared attributes, recognizing unshared attributes, and revising mapping errors. They selected a group analogy from analogies of their group members by considering inclusiveness, originality, and familiarity. They perceived the activity of self-generated analogy as subjective and creative. Therefore, they felt little pressure of self-generated analogy and there were little conflicts in group discussions. On the other hand, various analogies were suggested in classroom discussions and the competitive atmosphere of classroom discussions led students to focus on unshared attributes. At the stage of modifying group analogies, they added unshared attributes as limitations of the group analogy and changed their group analogy not to have unshared attributes. There were no cases of generating a new analogy. Some suggestions to implement collaborative activity of self-generated analogy in science teaching effectively are discussed.

Hydrothermal Synthesis of Ultra-fine SrAl2O4:Eu Powders and Investigation of their Photoluminescent Characteristics (수열합성법에 의한 SrAl2O4:Eu 초미세 분말 합성공정 및 형광 특성)

  • 박우식;김선재;김정식
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.370-374
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    • 2004
  • Sr$_{l-x}$Ba$_{x}$Al$_2$O$_4$:Eu (x = 0, 0.1, 0.2, and 0.3 mol) phosphor was synthesized by the hydrothermal method and its properties of photoluminescence and long-afterglow were investigated. The mixtures of Sr(NO$_3$)$_2$, Al(NO$_3$)$_3$9$H_2O$, and Eu(NO$_3$)$_3$$.$6$H_2O$ salts dissolved in distilled water, after controlling their pH by NH$_4$OH solution, put into an Autoclave reactor with high temperature and pressure to react. Such synthesized SrAl$_2$O$_4$:Eu powders showed homogeneous and ultra-fine particles of sub-micron size. In order to have the photoluminescence characteristic, powders were heat treated at 1100 -140$0^{\circ}C$ for 2 h in Ar/H$_2$ reduction atmosphere. Photoluminescence spectra showed a excitation along the wide wavelength of 250 ∼ 450 nm, and broaden emission with maxima peak at 520 nm. Also, it showed a good long afterglow with decaying over 1000 sec after excitation illumination for 10 min. In addition, the microstructure and crystal structure of SrAl$_2$O$_4$:Eu powders were investigated by an SEM and XRD, respectively.

The Preparation of Bi-2223 Superconducting Powder and Tape by Emulsion Drying Method (에멀젼 건조법에 의한 Bi-2223 초전도 분말과 테이프 제조)

  • 장중철;이응상;이희균;홍계원
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.115-122
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    • 1997
  • The powder preparation by using emulsion drying method, one of the chemical powder fabrication methods has the advantages; easy to control the chemical stoichiometry and to fabricate homogeneously fine particles. In the present study, the initial morphology and size distribution of the powder fabricated by using emulsion dry-ing method were controlled and were improved the homogeneity. By carefully controlling the mixing ratio of oil phase and aqueous solution and surfactant of preventing emulsion separation, the Bi(Pb)-Sr-Ca-Cu-O su-perconducting powders were prepared. The properties of the superconducting powder fabricated by this method and the microstructures and superconducting properties of the pelletized samples were investigated. The microstructures and electric properties of the tapes prepared by oxide powder-in-tube method were in-vestigated. The fabricated powder was spherical with less than 1$\mu$m but most of them was agglomerated with 2~5$\mu$m in size. The critical temperature of the pelletized sample annealed at 84$0^{\circ}C$ for 72 hours in oxygen par-tial pressure of 1/13atm in Ar atmosphere was 108K. And the critical current of the first and second annealed tapes in air prepared by oxide powder-in-tube process were 0.4A and 1.5A, respectively.

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저온 공정 온도에서 $Al_2O_3$ 게이트 절연물질을 사용한 InGaZnO thin film transistors

  • 우창호;안철현;김영이;조형균
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.11-11
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    • 2010
  • Thin-film-transistors (TFTs) that can be deposited at low temperature have recently attracted lots of applications such as sensors, solar cell and displays, because of the great flexible electronics and transparent. Transparent and flexible transistors are being required that high mobility and large-area uniformity at low temperature [1]. But, unfortunately most of TFT structures are used to be $SiO_2$ as gate dielectric layer. The $SiO_2$ has disadvantaged that it is required to high driving voltage to achieve the same operating efficiency compared with other high-k materials and its thickness is thicker than high-k materials [2]. To solve this problem, we find lots of high-k materials as $HfO_2$, $ZrO_2$, $SiN_x$, $TiO_2$, $Al_2O_3$. Among the High-k materials, $Al_2O_3$ is one of the outstanding materials due to its properties are high dielectric constant ( ~9 ), relatively low leakage current, wide bandgap ( 8.7 eV ) and good device stability. For the realization of flexible displays, all processes should be performed at very low temperatures, but low temperature $Al_2O_3$ grown by sputtering showed deteriorated electrical performance. Further decrease in growth temperature induces a high density of charge traps in the gate oxide/channel. This study investigated the effect of growth temperatures of ALD grown $Al_2O_3$ layers on the TFT device performance. The ALD deposition showed high conformal and defect-free dielectric layers at low temperature compared with other deposition equipments [2]. After ITO was wet-chemically etched with HCl : $HNO_3$ = 3:1, $Al_2O_3$ layer was deposited by ALD at various growth temperatures or lift-off process. Amorphous InGaZnO channel layers were deposited by rf magnetron sputtering at a working pressure of 3 mTorr and $O_2$/Ar (1/29 sccm). The electrodes were formed with electron-beam evaporated Ti (30 nm) and Au (70 nm) bilayer. The TFT devices were heat-treated in a furnace at $300^{\circ}C$ and nitrogen atmosphere for 1 hour by rapid thermal treatment. The electrical properties of the oxide TFTs were measured using semiconductor parameter analyzer (4145B), and LCR meter.

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Conduction Band Model of the System ${\alpha}-Fe_2O_3$-CdO at Extrinsic Region (외성영역에서 ${\alpha}-Fe_2O_3$-CdO 계의 전도띠 모델)

  • Keu Hong Kim;Seok Ho Yun;Young Sik Kwon;Jae Shi Choi
    • Journal of the Korean Chemical Society
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    • v.31 no.5
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    • pp.406-412
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    • 1987
  • The electrical conductivities of ${\alpha}-Fe_2O_3$ containing 2.5 and 5.0mol% of cadmium were measured from 300 to $900^{\circ}C$ under oxygen pressures of 10$^{-7}$ to 10$^{-1}$ atmosphere. Plots of log ${\sigma}$ vs. 10$^3$/T show the extrinsic conductivity at oxygen pressure higher than $5{\times}10$^{-2}$atm. The transition points appear at about 550$^{\circ}$C and the activation energies are 1.34 eV for the intrinsic region and 0.50 eV for the extrinsic region on 5mol% Cd-doped ${\alpha}-Fe_2O_3$. The extrinsic conductivity disappears at oxygen partial pressures lower than $5{\times}10$^{-2}$ atm, and the intrinsic conductivity predominates. The electrical conductivities decrease with increasing mol% of cadmium doped. The predominant defect of ${\alpha}-Fe_2O_3$ doped with Cd is believed to be Fe${2+}$ interstitial for the intrinsic, however, oxygen vacancy predominates for the extrinsic region. The electrical conduction mechanisms are proposed and the conduction band model is suggested for the extrinsic region.

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A Study on the Annealing Effect of SnO Nanostructures with High Surface Area (높은 표면적을 갖는 SnO 나노구조물의 열처리 효과에 관한 연구)

  • Kim, Jong-Il;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.536-542
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    • 2018
  • Tin dioxide, $SnO_2$, is a well-known n-type semiconductor that shows change in resistance in the presence of gas molecules, such as $H_2$, CO, and $CO_2$. Considerable research has been done on $SnO_2$ semiconductors for gas sensor applications due to their noble property. The nanomaterials exhibit a high surface to volume ratio, which means it has an advantage in the sensing of gas molecules. In this study, SnO nanoplatelets were grown densely on Si substrates using a thermal CVD process. The SnO nanostructures grown by the vapor transport method were post annealed to a $SnO_2$ phase by thermal CVD in an oxygen atmosphere at $830^{\circ}C$ and $1030^{\circ}C$. The pressure of the furnace chamber was maintained at 4.2 Torr. The crystallographic properties of the post-annealed SnO nanostructures were investigated by Raman spectroscopy and XRD. The change in morphology was confirmed by scanning electron microscopy. As a result, the SnO nanostructures were transformed to a $SnO_2$ phase by a post-annealing process.

Development of Matrix for the Immobilization of High Level Radioactive Waste : Study on the Synthesis of Ce-pyrochlore (고준위 핵페기물의 고정화를 위한 메트릭스 개발 : Ce파이로클로어 합성 연구)

  • ;;;Yudintsev, S. V²
    • Economic and Environmental Geology
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    • v.35 no.2
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    • pp.97-102
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    • 2002
  • Ce-pyrochlore (CaCe $Ti_2 $O_7)was synthesized to study its properties and phase relations in CaO-Ce $O_2$-Ti $O_2$ system because Ce-pyrochlore was known as a promising material for the immobilization of radioactive actinide. The samples were prepared from the high purity starling materials under the pressure of 200~400 kg/$\textrm{cm}^2$ at room temperature, and annealed at 1000~ 150$0^{\circ}C$. The Synthesized samples were analysed and indentified with XRD and SEM/EDS methods. The optimal formation condition of Ce-pyrochlore was at 130$0^{\circ}C$ under $O_2$ atmosphere and the chemical composition of it wasCa$Ca_{1-x}Ti_{2-y}O_{7-x-2y}$(x=0.03-0.05, y=0.02~0.04) At temperature between 130$0^{\circ}C$ 140$0^{\circ}C$, Ce-pyrochlore underwent rapidly the incongruent decomposition to perovskite. Ce-perovskite, a partial solid solution between perovskite and loparite (C $e_{0.66}$Ti $O_3$), was observed as a major phase above 140$0^{\circ}C$.>.

Classification of Snowfalls over the Korean Peninsula Based on Developing Mechanism (발생기구에 근거한 한반도 강설의 유형 분류)

  • Cheong, Seong-Hoon;Byun, Kun-Young;Lee, Tae-Young
    • Atmosphere
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    • v.16 no.1
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    • pp.33-48
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    • 2006
  • A classification of snowfall type based on development mechanism is proposed using previous snowfall studies, operational experiences, etc. Five types are proposed: snowfall caused by 1) airmass transformation (AT type), 2) terrain effects in a situation of expanding Siberian High (TE type), 3) precipitation systems associated with extratropical cyclones (EC type), 4) indirect effects of extratropical cyclones passing over the sea to the south of the Korean peninsula (ECS type), and 5) combined effects of TE and ECS types (COM type). Snowfall events during 1981-2001 are classified according to the 5 types mentioned above. For this, 118 events, with at least one station with daily snowfall depth greater than 20 cm, are selected. For the classification, synoptic weather charts, satellite images, and precipitation data are used. For TE and COM types, local sea-level pressure chart is also used to confirm the presence of condition for TE type (this is done for events in 1990 and thereafter). The classification shows that 109 out of 118 events can be classified as one of the 5 types. In the remaining 8 events, heavy snowfall occurred only in Ullung Island. Its occurrence may be due to one or more of the following mechanism: airmass transformation, mesoscale cyclones and/or mesoscale convergence over the East Sea, etc. Each type shows different characteristics in location of snowfall and composition of precipitation (i.e., dry snow, rain, and mixed precipitation). The AT-type snowfall occurs mostly in the west coast, Jeju and Ullung Islands whereas the TE-type snowfall occurs in the East coast especially over the Young Dong area. The ECS-type snowfall occurs mostly over the southern part of the peninsula and some east cost area (sometimes, whole south Korea depending on the location of cyclones). The EC- and COM-type snowfalls occur in wider area, often whole south Korea. Precipitation composition also varies with the type. The AT-type has a snow ratio (SR) higher than the mean value. The TE- and EC-type have SR similar to the mean. The ECS- and COM-type have SR values smaller than the mean. Generally the SR values at high latitude and mountainous areas are higher than those at the other areas. The SR value informs the characteristics of the precipitation composition. An SR value larger than 10 means that all precipitation is composed of snow whereas a zero SR value means that all precipitation is composed of rain.

Intercomparison between Temperature and Humidity Sensors of Radiosonde by Different Manufacturers in the ESSAY (Experiment on Snow Storms At Yeongdong) Campaign (대설관측실험(Experiment on Snow Storms At Yeongdong: ESSAY) 기간 중 두 제조사 라디오존데 기온과 습도 센서 상호 비교)

  • Seo, Won-Seok;Eun, Seung-Hee;Kim, Byung-Gon;Seong, Dae-Kyeong;Lee, Gyu-Min;Jeon, Hye-Rim;Choi, Byoung-Cheol;Ko, A-reum;Chang, Ki-Ho;Yang, Seung-Gu
    • Atmosphere
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    • v.26 no.2
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    • pp.347-356
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    • 2016
  • Radiosonde is an observation equipment that measures pressure (geopotential height), temperature, relative humidity and wind by being launched up from the ground. Radiosonde data which serves as an important element of weather forecast and research often causes a bias in a model output due to accuracy and sensitivity between the different manufacturers. Although Korean Meteorological Administration (KMA) and several institutes have conducted routine and intensive radiosonde observations, very few studies have been done before on the characteristics of radiosonde performance. Analyzing radiosonde observation data without proper understanding of the unique nature of those sensors may lead to a significant bias in the analysis of results. To evaluate performance and reliability of radiosonde, we analyzed the differences between two sensors made by the different manufacturers, which have been used in the campaign of Experiment on Snow Storm At Yeongdong (ESSAY). We improved a couple of methods to launch the balloon being attached with the sensors. Further we examined cloud-layer impacts on temperature and humidity differences for the analysis of both sensors' performance among various weather conditions, and also compared daytime and nighttime profiles to understand temporal dependence of meteorological sensors. The overall results showed that there are small but consistent biases in both temperature and humidity between different manufactured sensors, which could eventually secure reliable precisions of both sensors, irrespective of accuracy. This study would contribute to an improved sounding of atmospheric vertical states through development and improvement of the meteorological sensors.

The Growth of $MgO:LiNbO_3$ Single Crystal by Czochralski Method and its Density Measurement (Czochralski법에 의한 $MgO:LiNbO_3$단결정 성장과 밀도 측정)

  • Kim, Il-Won;Park, Bong-Chan;Kim, Gap-Jin
    • Korean Journal of Crystallography
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    • v.4 no.2
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    • pp.74-85
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    • 1993
  • Single crystals of LiNbO3 have found extensive application in electro-optic and nonlinear optic devices. However, laser-induced refartive index inhomogeneities, which have been labeled opical damage impose limits on device optical damage in LiNbO3 is imporved if more than 4.5 rml% MgO is added to the melt The laser damage thrueshold increased as much as 100 times better then that of undoped crystals. The MgO doped cystal has thus been urterlsiv81y studied since then. In the study, Mgo:LiNbOs(MLA) single crystals dopsd with 0, 2.5, 5.0, 7.5, 10.0 mol% MgO have been grown by the czocrualski technique. The metls were prepared in the platinum crluible and 15∼20mm diameter crystals were grown with a length of 20∼30mm in a resitance heater. The growth rate was 2.5mm/hr, the rotation speed 15rpn. Before sawing MLN single crystals were annealed for 24 hours under atmosphere at a temperature of 1080℃. After sawing, we have found an annual ring cross section of MNA crystals only in the direction of perpendicilar to the c-axis. Nonuniform dispusion of MgO was pointed out that the cuties of the state of oxide were strongly affected by oxygen partial pressure in.

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