• 제목/요약/키워드: Atmosphere Gas

검색결과 1,127건 처리시간 0.022초

Synthesis of Ceria Nanosphere by Ultrasonic Spray Pyrolysis

  • Kim, Jong-Young;Kim, Ung-Soo;Cho, Woo-Seok
    • 한국세라믹학회지
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    • 제46권3호
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    • pp.249-252
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    • 2009
  • Nanocrystalline ceria particles were prepared by using the ultrasonic spray pyrolysis method. The prepared ceria particles were found to be spherical and non-agglomerated by the SEM and TEM analyses. It was found that carrier gas influences the size and morphology. It was found that the air stream of carrier gas results in porous agglomerated structure of ceria abrasives, whereas solid nano-sphere can be obtained in a more oxidizing atmosphere.

게이트 산화막에 대한 암모니아 어닐링의 효과 (The Effect of $NH_3$ Annealing for Gate Oxide)

  • 김영조;김철주
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 1992년도 춘계학술발표회
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    • pp.57-58
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    • 1992
  • The NH$_3$oxidation, which forms thermal oxide layer on silicon substrate with pure $O_2$gas added with small amounts of NH$_3$gas, has good interface sates due to activated gettering effect during oxidation. The superiority of interfae state in NH$_3$ oxidation method is not affected by preprocess but by gettering during oxidation. The dramatec reduction fo interface state is conformed with observing OSF when NH$_3$ oxide is annealed in NH$_3$ atmosphere.

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반타원형 균열을 가정한 파괴 및 피로역학에 의한 수소 압력용기의 예상 수명 계산과 두께와 내경이 미치는 영향 분석 (Calculation of Expected Life of Hydrogen Pressure Vessels by Fracture and Fatigue Mechanics assuming Semi-elliptical Cracks and Analysis of the Effect of Thickness and Radius)

  • 김정환;이화영;이민경;이재훈;유근준
    • 한국가스학회지
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    • 제25권6호
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    • pp.53-65
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    • 2021
  • 수소충전소의 빠른 확장 및 설치와 동시에 수소충전소의 고압수소 충전 압력용기에 대한 안전 검사가 매우 중요하게 이루어져야 한다. 이 중 ASME에 따르면 일정 압력 이상의 수소를 보관하는 용기에 대해서는 수소 취성 검사를 반드시 해야 한다. 수소취성 검사의 주된 시험방법으로 고압의 수소분위기에서 파괴시험 및 피로 파괴시험을 실시해야 하며, 이를 통해 수소 분위기에서 압력용기의 내구한계를 측정하고, 사용한계를 결정하도록 되어 있다. 세부적으로 stress intensity factor(K)로부터 한계균열깊이를 계산하고, da/dN(피로성장율)로부터 사용수명을 결정할 수 있다. API579-1/ ASME FFS-1 part 9에서 crack-like flaws의 모드에 따른 계산방법을 예시하고 있으나, 플레이트, 실린더 등 다양한 형태의 형상에 대하여 균열의 형상, 위치 등에 의하여 대략 55개 모드가 있고, 상당히 복잡한 수식으로 인하여 쉽게 접근을 못한다. 본 연구에서는 엑셀 및 VBA를 통하여 수치해석적으로 파괴역학계산하는 방법을 소개하고자 한다. 또한, 이를 적용하여 압력용기의 두께와 내경이 수명에 미치는 영향을 분석해 보았다.

플라즈마 침질탄화처리된 순철의 화합물층 특성 (The Characteristics of Compound Layers Formed during Plasma Nitrocarburising in Pure Iron)

  • 조효석;이상윤
    • 열처리공학회지
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    • 제13권3호
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    • pp.143-150
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    • 2000
  • Ferritic plasma nitrocarburising was performed on pure iron using a modified DC plasma unit. This investigation was carried out with various gas compositions which consisted of nitrogen, hydrogen and carbon monoxide gases, and various gas pressures for 3 hours at $570^{\circ}C$. After treatment, the different cooling rates(slow cooling and fast cooling) were used to investigate its effect on the structure of the compound layer. The ${\varepsilon}$ phase occupied the outer part of the compound layer and ${\gamma}^{\prime}$ phase existed between the ${\varepsilon}$ phase and the diffusion zone. The gas composition of the atmosphere influenced the constitution of the compound layer produced, i.e. high nitrogen contents were essential for the production of ${\varepsilon}$ phase compound layer. It was found that with increasing carbon content in the gas mixture the compound layer thickness increased up to 10%. In the gas pressure around 3 mbar, the compound layer characteristics were slightly effected by gas pressure. However, in the low gas pressure and high gas pressure, the compound layer characteristics were significantly changed. The constitution of the compound layer was altered by varying the cooling rate. A large amount of ${\gamma}^{\prime}$ phase was transformed from the ${\varepsilon}$ phase during slow cooling.

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P형 4H-SiC 기판에 형성된 ZnO 박막/나노선 가스 센서의 300℃에서 CO 가스 감지 특성 (CO Gas Sensing Characteristic of ZnO Thin Film/Nanowire Based on p-type 4H-SiC Substrate at 300℃)

  • 김익주;오병훈;이정호;구상모
    • 한국전기전자재료학회논문지
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    • 제25권2호
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    • pp.91-95
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    • 2012
  • ZnO thin films were deposited on p-type 4H-SiC substrate by pulsed laser deposition. ZnO nanowires were formed on p-type 4H-SiC substrate by furnace. Ti/Au electrodes were deposited on ZnO thin film/SiC and ZnO nanowire/SiC structures, respectively. Structural and crystallographical properties of the fabricated ZnO thin film/SiC and ZnO nanowire/SiC structures were investigated by field emission scanning electron microscope and X-ray diffraction. In this work, resistance and sensitivity of ZnO thin film/SiC gas sensor and ZnO nanowire/SiC gas sensor were measured at $300^{\circ}C$ with various CO gas concentrations (0%, 90%, 70%, and 50%). Resistance of gas sensor decreases at CO gas atmosphere. Sensitivity of ZnO nanowire/SiC gas sensor is twice as big as sensitivity of ZnO thin film/SiC gas sensor.

서울 대기 중 기체 및 입자상 다환방향족탄화수소 (PAHs)의 낮·밤 분포 특성 (Day and Night Distribution of Gas and Particle Phases Polycyclic Aromatic Hydrocarbons (PAHs) Concentrations in the Atmosphere of Seoul)

  • 임형배;김용표;이지이
    • 한국대기환경학회지
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    • 제32권4호
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    • pp.408-421
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    • 2016
  • Day and night sampling for gas and particle phases PAHs were carried out in Seoul to characterize gas and particle phases PAHs concentrations in day and night times. There was no significant difference between day and night time for particle phase PAHs concentrations and phase distribution of PAHs, while, gas phase PAHs concentrations in daytime were about 1/2 of nighttime concentrations in both summer and winter due to photochemical reaction of gas phase PAHs during daytime. A high fraction of cancer risk for PAHs was attributed to particle phase PAHs and the excess cancer risk in winter was higher than in summer. The excess cancer risk level of total(gas+particle) PAHs in summer was partially observed when both gas and particle phase PAHs concentrations were considered as risk assessment. Based on the diagnostic ratios and factor analysis of PAHs concentrations, combustion(coal and natural gas) and vehicular emission might be the most significant contributors of PAHs and major factors for determining of PAHs concentration were different between day and night times.

공기구동 기체이젝터의 성능특성에 관한 연구 (A Study on the Performance Characteristics of Air Driven Gas Ejector)

  • 홍영표;윤두호;김용모;윤석훈
    • Journal of Advanced Marine Engineering and Technology
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    • 제18권1호
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    • pp.51-59
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    • 1994
  • The gas jet pumps serve to preduce a vacuum or can be used as gas jet compressors. These are operated on the same principle as a steam jet vacuum pump : in the driving nozzle the pressure energy of the motive medium is converted into the kinetic energy. In the diffuser the driving jet mixes with the suction medium and the kinetic energy is reconverted into the pressure enegy. The application fields of gas jet ejectors are the evacuation of siphoning installations, the elevation of liquids, the production of vacuum filters, the vacuum supporting airlift system, the evacuation of the suction line of centrifugal pumps and the ventilation of the dangerous gases to the atmosphere. The performance of gas jet ejector is influenced strongly to velocity coefficient of motive nozzle, the distance between the motive outlet to the diffuser inlet and the dimensions of diffuser. This study is performed for the computer aided design of gas jet ejectors in future. Through the present experiments, it is known that the velocity coefficient of the motive air nozzle ranges from 0.91 to 0.95 and the maximum efficiency of gas jet ejector is 24.6%.

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$SF_6$ 대체가스 연구동향 (Trends on the Research for Alternatives of $SF_6$ Gas)

  • 이동희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 C
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    • pp.1403-1406
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    • 2002
  • Environmental impact of human activities has become a great concern in most of the countries world-wide, and for years. It has recently focused on potential climate changes due to the increase of green house gases content in the atmosphere. One of these gases is $SF_6$, which is an essential material in electrical applications having excellent dielectric and arc-quenching properties. Though the actual contribution of $SF_6$ to global warming is negligible at present, the control of $SF_6$ emissions seems to be nevertheless imperative. Actually, it is listed in the Kyoto protocol that emissions should not only be duly reported but also the electrical industry which is now the major user of this gas must be able to show that it is possible to use this gas and at the same time preserve the environment. For the development of environmentally-benign electric power equipment and systems, novel gases or gas mixtures are strongly required as the alternatives of $SF_6$ gas. Until now, most research work is focused on the $SF_6/N_2$ mixed gas which is suitable for application in the electrical apparatus with slightly non-uniform fields. Recently, $SF_6/CO_2$ mixed gas also is expected to be promising as a $SF_6$ alternative, especially in highly non-uniform fields and in a gas-impregnated film insulation system. Including these results, the author reviews the research trend or reducing the environmental impact of $SF_6$ gas in this paper.

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독성가스 시설의 정량적 위험성 평가를 이용한 비상대응시스템 구축 (Development of Emergency Response System for Toxic Gas Facilities Using Quantitative Risk Analysis)

  • 유진환;김민섭;고재욱
    • 한국가스학회지
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    • 제9권2호
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    • pp.43-49
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    • 2005
  • 현재 여러 가지 목적으로 사용되고 있는 독성가스는 누출사고 발생시 확산되는 특성이 있어 피해 범위가 매우 넓고, 인체에 치명적이라는 특징을 가지고 있다. 따라서, 위험성이 높은 독성가스 이용시설은 누출사고에 대비한 사고 대응 시스템을 구축하여 비상상황 발생시 즉각 대응이 가능하도록 하여야 한다. 이에 본 연구에서는 FTA기법을 이용한 사고 시나리오 선정 및 빈도 분석과 DNV사의 PHAST(Ver 6.2)를 이용하여 독성가스 누출에 의한 확산 사고영향 분석을 실시하였다. 그리고, 정량적 위험성 평가 결과들을 이용하여 독성가스시설의 비상대응시스템을 구축하였다.

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가스가마를 사용한 최적의 청자 소성방법 연구 (Optimal firing method of the Celadon using gas kiln)

  • 김상곤
    • 에너지공학
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    • 제28권2호
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    • pp.55-62
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    • 2019
  • 본 연구는 가스가마를 사용하여 청자를 소성 할 경우 최적의 소성조건을 구하고자 하였다. 특히 환원분위기와 산화 분위기 등의 소성분위기를 가마내의 CO 농도로 명확하게 정의하였다. $1250^{\circ}C$로 청자유약을 소성한 경우, 가마 안의 일산화탄소 양이 0~4,500PPM에서는 산화 4,500~25,000PPM에서는 중성, 25,000PPM 이상에서는 환원분위기가 됨을 관찰 할 수 있었다. 가스 가마 안의 소성분위기와 소성온도를 균일하게 하면서 가스소모량과 소성시간을 줄이기 위해서는 가마 안의 연돌을 일부 막은 후 댐퍼로 조절하면 된다. 이와 같은 조절방법으로 가스량은 40%, 소성시간은 1시간을 절약할 수 있다.